Abstract
Use of alcohols blended with biodiesel as alternative fuel in diesel engine is an attractive solution for depletion and demand of fossil fuels in transportation and industrial applications. Calophyllum Inophyllum is a higher oil yielding species with high heating value and notably non-edible oil. One of the most important criteria used for assessing the quality of biodiesel blended fuel is ‘storage oxidation stability’. Deprived oxidation stability is the important technical obstacle associated with the biodiesel commercialization. This study investigated the oxidation stability of biodiesel blends at 100 % (B100) and 20 % (B20) volume concentrations with diesel through induction time determined by Rancimat instrument. Effects of pentanol addition with B20 biodiesel at 10 % (P10) and 15 % (P15) volume concentrations are also analyzed. FTIR spectroscopy characterizes the oxidation variability of all test fuels. It can be concluded that the biodiesel (B100) shows good oxidation stability (I.P = 8.47 h). Addition of pentanol (10 %) enhances the storage ability by 44.57 % than B20, whereas further addition of pentanol (15 %) declines by 19.48 % when compared to P10. More concentration of pentanol weakens the hydrophilic and hydrophobic clusters formed between pentanol/diesel/biodiesel compounds which have been characterized using infra red spectroscopic analysis.
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Shameer P. M. and Ramesh K., Experimental evaluation on performance, combustion behavior and influence of incylinder temperature on NOx emission in a D.I diesel engine using thermal imager for various alternate fuel blends, Energy (2016) http://dx.doi.org/10.1016/j.energy.2016.11.017.
Mohamed Shameer P., Ramesh K., Sakthivel R. and Purnachandran R., Effects of fuel injection parameters on emission characteristics of diesel engines operating on various biodiesel: A review, Renewable and Sustainable Energy Reviews, 67 (2017) 1267–1281 ISSN: 1364-0321. DOI: http://dx.doi.org/10.1016/j.rser.2016.09.117.
H. C. Ong, H. H. Masjuki, T. M. I. Mahlia, A. S. Silitonga, W. T. Chong and K. Y. Leong, Optimization of biodiesel production and engine performance from high free fatty acid Calophyllum inophyllum oil in CI diesel engine, Energ Convers Manage, 81 (2014) 30–40, http://dx.doi.org/10.1016/ j.enconman.2014.01.065.
H. C. Ong, H. H. Masjuki, T. M. I. Mahlia, A. S. Silitonga, W. T. Chong and T. Yusaf, Engine performance and emissions using Jatropha curcas, Ceiba pentandra and Calophyllum inophyllum biodiesel in a CI diesel engine, Energy, 69 (2014) 427–445, http://dx.doi.org/10.1016/j.energy.2014.03.035.
I. M. Monirul, H. H. Masjuki, M. A. Kalam, M. H. Mosarof, N. W. M. Zulkifli, Y. H. Teoh and H. G. How, Assessment of performance, emission and combustion characteristics of palm, jatropha and Calophyllum inophyllum biodiesel blends, Fuel, 181 (2016) 985–995, http://dx.doi.org/10.1016/ j.fuel.2016.05.010.
A. E. Atabani and A. da Silva Cesar, Calophyllum inophyllum L. -A prospective non-edible biodiesel feedstock. Study of biodiesel production, properties, fatty acid composition, blending and engine performance, Renew Sust. Energ. Rev., 37 (2014) 644–655, http://dx.doi.org/10.1016/j.rser.2014.05.037.
A. K. Agarwal, Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines, Energy Combustion, 33 (2007) 233–271, DOI: 10.1016/j.pecs.2006.08.003.
K. A. Heufer, J. Bugler and H. J. Curran, A comparison of longer alkane and alcohol ignition including new experimental results for n-pentanol and n-hexanol, Proceedings of the Combustion Institute, 34 (2013) 511–518, http://dx.doi.org/ 10.1016/j.proci.2012.05.103.
C.-F. Javier, J. M. Arnal, J. Gomez and M. P. Dorado, A comparison of performance of higher alcohols/diesel fuel blends in a diesel engine, Appl. Energ., 95 (2012) 267–275, DOI:10.1016/j.apenergy.2012.02.051.
L. Li, W. Jianxin, W. Zhi and X. Jianhua, Combustion and emission characteristics of diesel engine fueled with diesel/biodiesel/pentanol fuel blends, Fuel, 156 (2015) 211–218, http://dx.doi.org/10.1016/j.fuel.2015.04.048.
E. Ileri, Experimental study of 2-ethylhexyl nitrate effects on engine performance and exhaust emissions of a diesel engine fueled with n-butanol or 1-pentanol diesel-sunflower oil blends, Energ. Convers Manage, 118 (2016) 320–330, http://dx.doi.org/10.1016/j.enconman.2016.04.015.
L. Zhu, Y. Xiao, C. S. Cheung, C. Guan and Z. Huang, Combustion, gaseous and particulate emission of a diesel engine fueled with n-pentanol (C5 alcohol) blended with waste cooking oil biodiesel, Appl. Therm. Eng., 102 (2016) 73–79, http://dx.doi.org/10.1016/j.applthermaleng.2016.03.145.
A. Atmanli, Comparative analyses of diesel-waste oil biodiesel and propanol, n-butanol or 1-pentanol blends in a diesel engine, Fuel, 176 (2016) 209–215, http://dx.doi.org/10.1016/j.fuel.2016.02.076.
H. K. Imdadul, H. H. Masjuki, M. A. Kalam, N. W. M. Zulkifli, A. Alabdulkarem, M. Kamruzzaman and M. M. Rashed, A comparative study of C4 and C5 alcohol treated diesel-biodiesel blends in terms of diesel engine performance and exhaust emission, Fuel, 179 (2016) 281–288, http://dx. doi.org/10.1016/j.fuel.2016.04.003.
M. Mittelbach and S. Gangl, Long storage stability of biodiesel made from rapeseed and used frying oil, J. Am Oil Chem. Soc., 78 (2001) 573–577, DOI: 10.1007/s11746-001-0306-z.
R. O. Dunn, Oxidative stability of soybean oil fatty acid methyl esters by oil stability index (OSI), J. Am Oil Chem. Soc., 82 (2005) 381–387, DOI: 10.1007/s11746-005-1081-6.
S.-K. Loh, S.-M. Chew and Y.-M. Choo, Oxidative stability and storage behavior of fatty acid methyl esters derived from used palm oil, J. Am Oil Chem. Soc., 83 (2006) 947–952, DOI: 10.1007/s11746-006-5051-9.
M. B. Dantas, A. R. Albuquerque, L. E. B. Soledade, N. Queiroz, A. S. Maia, M. G. Santos, A. L. Souza, E. H. S. Cavalcanti, A. K. D. Barro and A. G. Souza, Biodiesel from soybean oil, castor oil and their blends, Oxidative stability by PDSC and rancimat, J. Therm Anal Calorim, 106 (2011) 607–611, DOI: 10.1007/s10973-011-1410-3.
M. L. A. Tavares, N. Queiroz, I. M. G. Santos, A. L. Souza, E. H. S. Cavalcanti, A. K. D. Barro, R. Rosenhaim, L. E. B. Soledade and A. G. Souza, Sunflower biodiesel, Use of PDSC in the evaluation of antioxidant efficiency, J. Therm Anal. Calorim., 106 (2011) 575–579, DOI: 10.1007/s10973-011-1357-4.
E. F. S. M. Ramalho, A. R. Albuquerque, A. L. Souza, A. K. Barro, A. S. Maia, I. M. G. Santos and A. G. Souza, Use of different techniques in the evaluation of the oxidative stability of poultry fat biodiesel, J. Therm. Anal. Calorim., 106 (2011) 787–791, DOI: 10.1007/s10973-011-1545-2.
J. Dweck, R. S. Leonardo and M. L. M. Valle, Evaluating antioxidants efficiency during storage of ethylic and methylic biodiesel by low pressurized DSC and Rancimat methods, J. Therm. Anal. Calorim., 113 (2013) 1317–1325, DOI: 10.1007/s10973-013-3028-0.
A. S. R. Maria, F. P. S. Francisco, J. N. M. Francisco and E. M. Selma, Evaluation of antioxidants on the thermooxidative stability of soybean biodiesel, J. Therm. Anal. Calorim., 112 (2013) 921–927, DOI 10.1007/s10973-012-2650-6.
M. L. Murta Valle, R. S. Leonardo and J. Dweck, Comparative study of biodiesel oxidation stability using Rancimat, PetroOXY and low P-DSC, J. Therm. Anal. Calorim., 116 (2014) 113–118, DOI: 10.1007/s10973-014-3706-6.
M. A. M. F. Melo, M. A. R. Melo, A. S. G. C. Pontes, A. F. F. Farias, M. B. Dantas, C. D. Calixto, A. G. Souza and J. R. C. Filho, Non-conventional oils for biodiesel production: a study of thermal and oxidative stability, J. Therm. Anal. Calorim., 117 (2014) 845–849, DOI: 10.1007/s10973-014-3825-0.
L. M. Pinto, A. L. de Souza, A. G. Souza, I. M. G. Santos and N. Queiroz, Comparative evaluation of the effect of antioxidants added into peanut (arachis hypogae l.) oil biodiesel by P-DSC and rancimat, J. Therm. Anal. Calorim., 120 (2015) 277–282, DOI 10.1007/s10973-014-4181-9.
A. T.-R. Daniela, C. R.-I. Issis, I. A. Ibarra and H. Pfeiffer, Biodiesel production from soybean and Jatropha oils using cesium impregnated sodium zirconate as a heterogeneous base catalyst, Renew Energ., 93 (2016) 323–331, http://dx.doi.org/10.1016/j.renene.2016.02.061.
D. Reyman, A. S. Bermejo, I. R. Uceda and M. R. Gamero, A new FTIR method to monitor transesterification in biodiesel production by ultrasonication, Environ. Chem. Lett., 12 (2014) 235–240, DOI 10.1007/s10311-013-0440-4.
C. G. Mothe, B. C. S. de Castro and M. G. Mothe, Characterization by TG/DTG/DSC and FTIR of frying and fish oil residues to obtain biodiesel, J. Therm. Anal. Calorim., 106 (2011) 811–817, DOI 10.1007/s10973-011-1795-z.
M. E. S. Mirghani, N. A. Kabbashi, Md. Z. Alam, I. Y. Qudsieh and M. F. R. Alkatib, Rapid method for the determination of moisture content in biodiesel using FTIR spectroscopy, J. Am. Oil Chem. Soc., 88 (2011) 1897–1904, DOI: 10.1007/s11746-011-1866-0.
P. Y. Furlan, P. Wetzel, S. Johnson, J. Wedin and A. Och, Investigating the oxidation of biodiesel from used vegetable oil by FTIR spectroscopy: Used vegetable oil biodiesel oxidation study by FTIR, Spectros Lett., 43 (2010) 580–585, http://dx.doi.org/10.1080/00387010.2010.510708.
S. S. Damasceno, N. A. Santos, I. M. G. Santos, A. L. Souza, A. G. Souza and N. Queiroz, Caffeic and ferulic acids: An investigation of the effect of antioxidants on the stability of soybean biodiesel during storage, Fuel, 107 (2013) 641–646, http://dx.doi.org/10.1016/j.fuel.2012.11.045.
D. M. Fernandes et al., Storage stability and corrosive character of stabilised biodiesel exposed to carbon and galvanised steels, Fuel, 107 (2013) 609–614, http://dx.doi.org/10.1016/j.fuel.2012.11.010.
M. Lapuerta, J. Rodríguez-Fernández, Á. Ramos and B. Álvarez, Effect of the test temperature and anti-oxidant addition on the oxidation stability of commercial biodiesel fuels, Fuel, 93 (2012) 391–396, http://dx.doi.org/10.1016/j.fuel. 2011.09.011.
M. Serrano, A. Bouaid, M. Martínez and J. Aracil, Oxidation stability of biodiesel from different feedstocks: Influence of commercial additives and purification step, Fuel, 113 (2013) 50–58, http://dx.doi.org/10.1016/j.fuel.2013.05.078.
R. Sarin, M. Sharma, S. Sinharay and R. K. Malhotra, Jatropha-Palm biodiesel blends: An optimum mix for Asia, Fuel, 86 (2007) 1365–1371, http://dx.doi.org/10.1016/j.fuel.2006.11.040.
D. M. Fernandes, D. S. Serqueira, F. M. Portela, R. M. N. Assunção, R. A. A. Munoz and M. G. H. Terrones, Preparation and characterization of methylic and ethylic biodiesel from cottonseed oil and effect of tert-butylhydroquinone on its oxidative stability, Fuel, 97 (2012) 658–661, http://dx.doi.org/10.1016/j.fuel.2012.01.067.
H. Tang, A. Wang, S. Salley and K. Y. S. Ng, The effect of natural and synthetic antioxidants on the oxidative stability of biodiesel, Journal of American Oil Chemist’s Society, 85 (2008) 373–382, doi:10.1007/s11746-008-1208-z.
A. Obadiah, R. Kannan, A. Ramasubbu and S. V. Kumar, Studies on the effect of antioxidants on the long-term storage and oxidation stability of Pongamia pinnata (L.) Pierre biodiesel, Fuel Processing Technology, 99 (2012) 56–63, http://dx.doi.org/10.1016/j.fuproc.2012.01.032.
M. Chakraborty and D. C. Baruah, Investigation of oxidation stability of Terminalia belerica biodiesel and its blends with petrodiesel, Fuel Processing Technology, 98 (2012) 51–58, http://dx.doi.org/10.1016/j.fuproc.2012.01.029.
S. S. Pantoja, L. R. V. da Conceição, C. E. F. da Costa, J. R. Zamian and F. G. N. da Rocha, Oxidative stability of biodiesels produced from vegetable oils having different degrees of unsaturation, Energy Conversion Management, 74 (2013) 293–298, DOI: 10.1016/j.enconman.2013.05.025.
Z. Yang, B. P. Hollebone, Z. Wang, C. Yang and M. Landriault, Factors affecting oxidation stability of commercially available biodiesel products, Fuel Processing Technology, 106 (2013) 366–375, http://dx.doi.org/10.1016/j.fuproc.2012. 09.001.
M. Lapuerta, R. Garcia-Contreras, J. Campos-Fernandez and M. P. Dorado, Stability,lubricity,viscosity,and coldflow properties of alcohol-diesel blends, Energy Fuels, 24 (2010) 4497–4502, DOI: 10.1021/ef100498u.
H. Abou-Rachid, K. E. Marrouni and S. Kaliaguine, DFT studies of the hydrogen abstraction from primary alcohols by O2 in relation with cetane number data, Journal of Molecular Structure: THEOCHEM., 631 (2003) 241–250, http://dx.doi. org/10.1016/S0166-1280(03)00257-4.
M. Gautam and D. W. Martin, Combustion characteristics of higher-alcohol /gasoline blends, Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy, 214 (2000) 5497–5511, doi: 10.1243/ 0957650001538047.
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Mohamed Shameer P. received his Post Graduate degree in Thermal Engineering from Anna University Chennai, Tamil Nadu, India in 2015. In 2009, he joined Mechanical Engineering and graduated as University Rank Holder in Anna University Chennai, Tamil Nadu, India. He is currently working as a Teaching Research Associate and doing his research (Ph.D. degree) in energy, oxidation stability and combustion at Government College of Technology, Coimbatore, Tamil Nadu, India.
Ramesh K. received his Ph.D. degree in Mechanical Engineering from Anna University Chennai, Tamil Nadu, India in 2013. He is currently working as Assistant Professor (Senior Grade) of Mechanical Engineering at Government College of Technology, Coimbatore, Tamil Nadu, India for a period of 11 years (2005-2016). He has 17 years of teaching experience. His research interests include energy, combustion, environmental pollution, vibration analysis and manufacturing processes.
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Peer, M.S., Kasimani, R., Rajamohan, S. et al. Experimental evaluation on oxidation stability of biodiesel/diesel blends with alcohol addition by rancimat instrument and FTIR spectroscopy. J Mech Sci Technol 31, 455–463 (2017). https://doi.org/10.1007/s12206-016-1248-5
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DOI: https://doi.org/10.1007/s12206-016-1248-5