Abstract
Wellbore instability because of poor rheological properties, high fluid loss volume and shale swelling is the leading challenge faced by the petroleum sector. Therefore, the success of any drilling activity is fundamentally governed by the characteristics of the drilling mud. The main scope of this study is to observe an increase in the performance of water-based mud (WBM) after the addition of synthesized GO/TiO2 nanoparticles. In the first part, properties of WBM are analyzed after the addition of GO/TiO2 and anatase-TiO2 nanoparticles. Each particles as a separate entity is added in different three concentrations \(\left( {0.75, 1.5, 2.25 \;{\text{g}}} \right)\) in the WBM. In the second part, the influence of salt, polymer and synthesized nanoparticles on inhibiting the shale swelling is observed. For the first part, the results reveal that the rheological properties of all the six samples are in the API recommended window. However, plastic viscosity, yield point, gel strength (10 s/10 min), and transport index of the base mud substantially improves with the addition of GO/TiO2 nanoparticles than anatase-TiO2 nanoparticles. Furthermore, the GO supports TiO2 through oxygen-bearing functional groups, which eventually improves the adsorptivity of GO/TiO2 particles in the micro and nanopores and decreases the filtrate loss volume. Thin and compacted mud cake with lower permeability is obtain from GO/TiO2 nanoparticles. For the second part, full factorial design of experiment technique is implemented on the shale swelling behavior. The result of this segment indicates that GO/TiO2 nanoparticles are the most influential factor in reducing the shale swelling behavior. The shale surface becomes hydrophobic after its interaction with the GO/TiO2 nanoparticles. Moreover, these particles are responsible for developing strong interparticle hydrogen bonds between themselves, which prevents the fluid migration into the shale pellets. On the other hand, the impact of KCl and PAC on the shale swelling is relatively small. The polymer PAC is dehydrated in the presence of monovalent cations, which impacts their performance in minimizing the shale swelling.
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Introduction
Drilling is a fundamental and costly process in the oil and gas sector. The key element of any drilling activity is the preparation of the drilling mud, which is responsible for performing many functions over the course of the entire drilling activity (Wajheeuddin and Hossian 2018). The main characteristics of drilling mud is to remove and lift the drill cutting from the bottom of the borehole up to the surface, maintain the integrity of the wellbore, cool the drill bit and the drill pipes, and maintain adequate hydrostatic pressure inside the wellbore (Wajheeuddin and Hossian 2018; Lalji et al. 2023a). Among all the mud systems, water-based mud (WBM) is the most frequently used type of mud used in drilling operations. The WBM system is environmentally friendly, less costly, and is easy to formulate. However, differential sticking, shale instability, loss of circulation, caving and washouts are some common problems associated with WBM (Wajheeuddin and Hossian 2018; Lalji and Ali 2023; Lalji et al. 2023b). Therefore, numerous scholars are continuously working on improving the characteristics of WBM for the purpose of reducing the problems associated with this system.
Initially, the performance of WBM was improved with the addition of salt, most commonly known as potassium chloride (KCl). This additive was effective in maintaining the rheological behavior of WBM in the desired range, and also increased the shale stability (Mohamed Khodja et al. 2010). However, at higher concentration, KCl dephase the mud into two separate entities (Chang and Leong 2014). Consequently, the application of polymers in enhancing properties of drilling fluid gains substantial importance in the oil and gas sector. Various polymeric materials with their unique characteristics were used by numerous researchers in the WBM system to improve its characteristics. These polymeric materials include partially hydrolyzed polyacrylamide (PHPA), poly anionic cellulose (PAC), hydroxyethyl cellulose (HEC), and carboxymethyl cellulose (CEC) (Jefferis et al. 2015). However, their use is limited to a certain extent because of their expensive nature, incapability with anionic additives, and inability to work at elevated temperature conditions (Aftab et al. 2017). Therefore, the petroleum industry is exploring new alternatives, which have all the desired properties to enhance the performance of WBM and can also challenge the shortcoming associated with the polymers. Consequently, the use of nanomaterials in drilling fluid gains significant importance. This technology opens new and diverse doors in the field of drilling engineering especially in the area of drilling mud.
Several nanoparticles have been studied by numerous scholars and their positive impact on the properties of drilling fluid are documented in the literature (Hoelscher et al. 2012; Ravi Kumar 2019; Mortadha Alsaba et al. 2019). The most commonly used nanoparticles are silica (Boul et al. 2016), graphene oxide (Aramendiz and Imqam 2020a), iron oxide (Alvi et al. 2020), copper oxide (Ponmani et al. 2016), zinc oxide (Ponmani et al. 2016). However, limited attention is given to titanium dioxide (TiO2) nanoparticles as a drilling mud additive.
TiO2 nanoparticles play a prominent role in the areas of photo-catalysis, paints, cosmetics and many more (Reghunath et al. 2021). This metal oxide nanoparticle is capable of providing high chemical stability and substantial electrochemical properties (Reghunath et al. 2021). In addition, the non-toxic nature and commercially viable nature are some of other possible causes for its effectiveness. All these properties associated with TiO2 nanoparticles are mainly due to its crystal structure, large surface area, and noble metallic loading (Reghunath et al. 2021). In general, this nanoparticle exists in four major crystal systems, which includes anatase, rutile, brookite and TiO2-B (Reghunath et al. 2021). At nanoscale dimensions, anatase and brookite are the most stable crystal forms of TiO2 nanoparticles (Altomare et al. 2015). However, the large band gap in the anatase crystal system substantially affects its performance. To improve the characteristics of TiO2 nanoparticles, various support systems are provided. The most effective support system is provided with the help of the carbonaceous materials. Among all the carbonaceous material, graphene oxide gains significant attention due to its unique two-dimensional geometry, high conductivity and large surface area (Mahima Sharma 2018).
Graphene-based nanostructures have numerous applications due to their unique characteristics. These nanomaterials are currently used in energy-based zones of modern technology for the purpose of energy storage in the form of fuel cell, lithium batteries, super-capacitors, and photo-catalysts (Yusaf et al. 2022). Moreover, due to their high surface area, easy surface functionalization, and selective properties, these nanostructures are also used for gene and drug delivery in the field of medicine (Liu et al. 2014). Additionally, the recent advancement in graphene-based nanomaterials offer novel and advanced methods to deal with malignancy (You et al. 2015). Besides this, these structures are also now part of our personal computers, mobile phones and tablets, making them advanced and fast-processing (Yusaf et al. 2022). Furthermore, graphene nanostructures are also used in the food packing industry. These advanced nanomaterials contain antimicrobial mechanisms, which inhibit microbial growth and affect the physical metabolism developments (Romanchuk et al. 2013). Despite all these recent developments, the use of graphene-based nanostructures are limited in the field of drilling fluids.
In the current work, the performance of TiO2 and GO/TiO2 nanoparticles in drilling fluid was investigated. A series of rheological, filtration, and shale swelling tests were conducted and were examined. Based on the experimental results, the efficacy of GO/TiO2 nanoparticles in drilling fluid was observed. Moreover, the performance of GO/TiO2 nanoparticles in mitigating the shale swelling was also evaluated using 2n factorial analysis. In this investigation, the impact of KCl, PAC and GO/TiO2 nanoparticles was examined and the most influential additive for the shale swelling behavior was obtained. For the first time, this type of comparison between salt, polymer and nanoparticle was analyzed using the 2n factorial approach.
Previous studies on GO and TiO2 particles in drilling mud
Several applications of GO and TiO2 nanoparticles as drilling fluid additives have been reported in the literature. These particles are commonly added in drilling fluid to enhance the characteristics of the mud system. Some of the most recent work conducted by numerous scholars on these particles along with their findings are presented in Table 1.
Material and methods
Materials
The materials required for the synthesis of nanoparticles and for the formulation drilling mud were acquired from various sources. Table 2 shows the complete information related to the particles source.
Synthesis of GO/TiO 2 nanoparticle
The GO/TiO2 nanoparticle was synthesized using the hydrothermal thermal technique. For the synthesis of GO/TiO2 nanoparticle, GO was provided purchased from Xi’an Lyphar Biotech Co. Ltd. The complete characterization detail can be found out in our previous study (Lalji et al. 2023c). The oxygenated functional groups were also provided by the vendor. Initially, the graphene oxide was mixed with the deionized water and then exfoliated through sonication for one hour. Next, a paste prepared from the TiO2 precursor powder and ethanol was added drop wise to the GO solution and mixed vigorously. The mixture was ultra-sonicated for one hour before transferring it into a Teflon-lined autoclave. Moreover, before the transferring process, a small concentration of sodium hydroxide is added to the mixture for the purpose of maintaining the pH. Next, 100 mL of prepared solution was transferred into a Teflon-lined autoclave and heated at 200 °C for 8 h. A gray gel colored sample was collected, which was then washed with distilled water several times to remove any impurities. The final product was centrifuged at 4000 RPM for one hour and then was dried overnight to obtain GO/TiO2 nanoparticles. Figure 1 displayed the schematic for the synthesis of GO/TiO2 nanoparticles.
Characterization of Particles
Figure 2a shows the Fourier transform infrared analysis of a GO/TiO2 nanoparticle. The strong characterization peak obtained at 3425.09 cm−1 corresponds to the elongation of O–H bond in graphene oxide and its composites with titanium dioxide (Nethravathi and Rajamathi 2008). The peak at 2920.36 cm−1 corresponds to the asymmetric movements of the C–H. On the other hand, the small peak at 2887.92 cm−1 indicates symmetric movements of C–H bond. The presence of characterization peak at 1613.1 cm−1 indicates the skeletal vibrations of non-oxidized graphitic domains, which is mainly due to the stretching vibrations of C=C (Shen et al. 2011). The peak at 1312.52 cm−1 indicates the C–OH stretching vibration of the alkoxy functional group along with Ti–O modes. Finally, the broad peak obtained between 500–1000 cm−1 specifies the Ti–O–Ti stretching present in the nanoparticle (Yu et al. 2006). This characterization peak is mainly due to the chemical relations between the functional groups associated with graphene oxide and the surface hydroxyl groups present in TiO2 (Nguyen-Phan, et al. 2011). Figure 2b shows the XRD analysis of the GO/TiO2 nanoparticle. The 2-theta peaks at 25.1, 37.3, 49, 57.1, 63.68° show the presence of anatase-TiO2. The peak of graphene oxide at 24.6° was curtained by anatase-TiO2 peak at 25.1°. At lower concentration, the graphene oxide peak is usually overpowered by anatase-TiO2. The crystalline size of the nanoparticles was measured using Debye–Scherrer equation. During the study, the average crystalline size of the nanoparticles was 12.45 nm.
Formulation of water-base mud
The water-based mud was prepared using the solution method also known as the direct mixing method. This technique is most suitable for the formulation of a water-based mud system. Table 3 displays the composition of each sample prepared in this study. According to API recommended protocol, one barrel equivalent to 350 cc of mud was prepared using Hamilton beach stirrer. The mixing of the mud was continued until a stable mud sample with proper dispersed NPs was achieved. Both the tested particles were added in the base mud sample in various concentrations of 0.75, 1.5 and 2.25 g. The 2.25 g of nanoparticle corresponds to 0.65 wt. %. According to Parizad et al. in (2019), increasing the concentration of TiO2 particles beyond 0.75% is not economical and effective for the mud system (Amirhossein Parizad et al. 2019). Hence, during this study, experiments are designed on the bases of Parizad et al. threshold limit. In this way, a substantial quantity of resources and time were preserved.
The main aim was to investigate the performance enhancement in TiO2 NPs WBM after it has been supported by a carbonaceous material. Figure 3 shows the complete experimental procedure followed the course of study.
Mud weight
Density of drilling fluid is a critical factor during any drilling operation. This parameter is responsible for maintaining the desired hydrostatic pressure within the borehole, and at the same time prevents the unwanted flow within the wellbore (Ali et al. 2022). In the laboratory, this property is measured using an apparatus known as mud balance, which is an effective way of measuring the mud density (Ali et al. 2022). Drilling fluids will lower mud weight are usually are responsible for creating problem like caving and washouts. On the other hand, higher density muds are accountable for causing formation damage and loss circulation problems (Rafieefar 2021). During this study, the density of the base mud was 10 ppg, which remained unaffected by the addition of nanoparticles. In addition, no significant influence on the mud weight was recorded due to temperature (Ali et al. 2022).
Rheological characteristics
The rheological properties were investigated using the FANN 35 rheometer (MODEL-286). Rheological characteristics such as plastic viscosity (PV), yield point (YP), apparent viscosity (AV), gel strength (GS) and YP/PV (Transport Index) ratio were all measured at a room temperature of 30 °C. During the study, the shear rate was maintained in between the ranges of 600–100 s−1. The API recommended practices were thoroughly followed during the measurement of rheological properties (Institute 2017). Equations 1–3 were used to compute the rheological behavior of each fluid system. The parameters \({\uptheta }_{600} and {\uptheta }_{300}\) are dial reading obtained from FANN viscometer. For the GS 10 s testing, the sample was rotated at the 600 RPM, followed by a static period of 10 s. After 10 s, the sample was rotated at 3 RPM and the maximum change in the rheometer dial was recorded (Ali et al. 2022). Similar procedure was followed for GS 10 min; however, this time around the static period was observed for 10 min.
API filter press (low pressure low temperature)
The LPLT API Filter press was performed on each of the samples. All the filter press testing was conducted at an ambient condition of 30 °C and a differential pressure of 100 psi. The removal of mud filtrate from the mud system was recorded on every five minute interval till standard 30 min. Moreover, the filter cakes that were collected at the end of experimentation were also investigated for thickness, permeability and texture. During API filter press testing, the API protocols were meticulously followed. The uncertainty associated with the experimentation was kept within the acceptable boundary of \(2\%.\)
Liner dynamic swell-meter (LDSM)
During LDSM testing, shale cuttings were first dried in an oven for about 150 ℃ to remove any moisture content. Next, the dried samples were crushed and converted into the fine powder form using Mortar Grinder. The prepared powder was then passed through the sieve shaker, and the fine powder collected on the 0.212 mm sieve was used for further analysis. The 15 g of fine powder was then placed in a hydraulic compactor for about 30 min at a pressure of 6000 psi to form cylindrical shale pellets. These pellets were then placed into the LDSM where it interacts with the tested mud sample for approximately 24 h to monitor the changes in shale behavior. Once the equilibrium state was achieved in the LDSM testing, the swelling experiment was stopped, and the final swelling percentage was recorded. In general, a lower shale swelling percentage indicates toward the higher efficacy of the mud.
Full factorial design (FFD) of experiment
A comparison study was also conducted to evaluate the efficiency of GO/TiO2 nanoparticles over a salt and a polymeric material. During this investigation, the shale swelling was tested and the most influential additive out of GO/TiO2 nanoparticles, KCl and PAC was determined. During this study, FFD was implemented and the impact of additives (KCl, PAC and GO/TiO2) on shale swelling was investigated. Each factor is divided into 2 levels and based on the mathematical expression \({2}^{n}\) shale swelling tests were conducted. In this study, ‘8’ runs were evaluated. This tool provides an insight information of the system, thus making it an effective tool to investigate the performance of each variable (Aleksandar Jankovic and Goia 2021).
Result and discussion
Effect of particles on flow curve
Figure 4 depicts the rheogram showing the relationship between shear stress and shear rate of all the studied samples. At constant shear rate, the shear stress rises with an increase in particle concentration. Based on the rheogram, each non-Newtonian fluid demonstrates pseudo plastic or shear thinning characteristics. An upsurge in shear rate will cause a reduction in viscosity of the sample. This behavior is essential, as at static condition, high viscosity is required for the suspension of the drilled cutting and during dynamic condition, lower viscosity is vital, which assists in the removal of the drilled cutting on to the rig site (Ahmed et al. 2020). The lowest shear stress was observed in the base mud sample, which improves with the addition of NPs. The highest shear stresses were recorded in S5 and S6. Both of these samples contains the highest concentration of GO/TiO2 NPs. Shear stress in presence of 2.25 g of GO/TiO2 NPs was double that of the base mud.
In these samples, the sheets of GO/TiO2 were well dispersed throughout the water suspension. Subsequently, a hydrogen bond between GO/TiO2 NPs and PAC can be developed, which becomes substantially stronger as GO/TiO2 NPs concentration increases. This results in an increase in flow resistance and ultimately intensifies the viscosity and the shear stress.
Effect of particles on Rheological properties
Figure 5a–d shows the rheological properties of all the six studied samples. The parameters were recorded using the FANN 35 rheometer and were calculated using Eqs. (1–3). Figure 5a represents the plastic viscosity (PV) of each sample. Plastic viscosity is defined as the friction force arises between the solid particles and in between the individual fluid layer of the system (Elkatatny 2019). In general, fluids demonstrated high PV are difficult to pump, while lower PV exhibit incapability in the transportation of the drilled cutting (Bayat et al. 2018a). Hence, maintaining an optimum PV is crucial during any drilling activity. According to the American Petroleum Institute (API), the recommended value for PV for any drilling fluid should be in range of 8–35 cP (Biwott 2019). During the experimentation, PV of all the studied samples fall within the API suggested range as depicted in Fig. 5a. Moreover, an increase in PV was recorded when the quantity of the nanoparticles increases in the drilling mud. The base mud with composition shown in Table 3 shows the PV of 12 cP. With the introduction of the nanoparticles, PV increases and goes above the PV of the base mud. This result is in good agreement with Smoluchowski’s modification of Einstein equation (Aftab et al. 2016), which explains the relationship between the particle size and PV. The maximum PV (20 cP) was recorded in Sample 3 consists of 2.25 g of TiO2. Similar characteristics were also demonstrated by GO/TiO2 NPs. The modified TiO2 NPs also displayed a higher PV than the base mud sample. Different scholars had conducted research on GO and TiO2 NPs, but there is no case reported that investigated the combined impact of both these additives. Bayat et al. (2018a) conducted a study on TiO2 NPs. According to the study, the maximum PV attained after using TiO2 NPs was 10 cP at 0.01 wt. % that reached to 9 cP at the concentration of 1 wt. % (Bayat et al. 2018a). On the other hand, Rafieefar et al. (2021) reported the PV for the GO. According to the study, the maximum PV attained was 11 cP at 0.15 wt. % (Rafieefar 2021). A significant improvement in PV was observed when TiO2 NPs was supported with GO. By adding 0.75 g GO/TiO2 NPs to the base mud, the PV attained was 15 cP. With increasing the quantity of GO/TiO2 NPs up to 2.25 g, the PV was 17 cP. The enhancement of PV is mainly due to the dispersion of nanoparticles between the fluid layers, which eventually increases the fluid internal resistance and increases the plastic viscosity (Sundar et al. 2013). This investigation clearly shows the GO/TiO2 NPs is extremely effective than TiO2 and GO separately in maintain the PV, which eventually impacts the hydrostatic pressure of the mud in the wellbore and assist in safe drilling activity.
Figure 5b represents the yield point (YP) of all the studied mud samples. The YP represents the electrochemical forces, which creates friction during the fluid flow (Bayat et al. 2018a). According to API recommended practices, YP should not go below \(5 \;{\text{lb}}/100\;{\text{ft}}^{2}\) and should not exceed \(3xPV\) (Biwott 2019). The results showed that all the studied samples YP fall under the prescribed range of API. The YP for the TiO2 particle remained closer to the base mud. According to Parizad et al. in 2019, increasing the concentration of TiO2 particles beyond 0.75% is not economical and effective for the mud system (Amirhossein Parizad et al. 2019). This statement was in good agreement with the current work, as when TiO2 particle concentration starts to increase in the mud the YP decreases. Beg (2020) studied TiO2 particles as a separate entity (Mukarram Beg 2020). When this particle was added to the base mud, YP of 12 \({\text{lb}}/100\;{\text{ft}}^{2}\) was recorded at 25 °C. Similarly, Lalji et al. (2022) studied the influence of GO on salt-polymer mud and observed a 17 \({\text{lb}}/100\;{\text{ft}}^{2}\) at 0.4 wt. % (Lalji et al. 2022). However, when TiO2 particles was coated with GO, a substantial increase in YP was recorded. As the dimension of particles reduces an increase in YP was recorded (Rafieefar 2021). The smaller dimension particles improve the attractive forces between the positive and negative charges, which eventually increases the YP (Aftab et al. 2016). The GO/TiO2 particle declines the agglomeration among the drilling fluid particles and improves the YP, which eventually helps in the transportation of drilled cuttings to the ground surface better than GO and TiO2 as separate entities.
Furthermore, the cutting lifting efficiency of each studied sample was also examined using the YP/PV ratio, also commonly known as Transport Index (TI). According to APT 13A specification, this ratio should be in range of 0.7–1.5 for any drilling fluid (Elkatatny 2019). The magnitude of this ratio specifies the effectiveness of a drilling fluid in minimizing the cutting volume in the annulus, which ultimately avoids any differential sticking problems (Elkatatny 2019). Based on the findings, it can be witnessed from Fig. 5c that the inclusion of the GO/TiO2 particle improves the YP and PV of the drilling mud and improves the ratio according to APT 13A specification. For the base mud and TiO2 particles mud systems, this ratio falls well below the APT 13A specification. The lower magnitude of YP was the main reason behind its failure. In addition, at higher concentration, TiO2 particles forms clusters as shown by the SEM image in Fig. 5c. This further decreases the performance of the TiO2 particles mud, as the performance of nanoparticles was suppressed in the WBM.
Figure 5d shows the apparent viscosity (AV) of each of the six studied particles. According to API standards, a fluid should demonstrate at least 12– cP of AV (Dankwa et al. 2018). Beg (2020) studied the AV of TiO2 NPs. According to their finding, the base mud with TiO2 NPs demonstrated AV of 15 cP at 25 °C (Mukarram Beg 2020). Moreover, according to Lalji et al. (2021), when GO was used in WBM, the AV of the base mud remained fairly constant at 17 cP, and remained independent of GO concentration (Lalji et al. 2023c). In the current work, it can be observed that the AV of base mud was 15 cP, which substantially improves as the quantity of the nanoparticles increases. With the addition of NPs, the fluid becomes more viscous, which eventually elevates the AV. Moreover, the maximum AV was recorded in mud that contains the maximum concentration of GO/TiO2 particles. This clearly shows that when the TiO2 NPs was supported with GO, the thixotropic characteristics of drilling mud increases, which eventually increases the fluid performance in the wellbore.
Influence of particles on Gel strength (GS)
Figure 6a, b depicts the GS recorded at 10 s and 10 min intervals for all the studied mud samples. The GS of any mud provides information on the ability of the drilling fluid to suspend the drilled cuttings under static conditions (Lalji et al. 2023c). According to API recommended practices, a drilling fluid should exhibit GS 10 s in range of \(2 - 5 \;{\text{lb}}/100\;{\text{ft}}^{2}\) (Biwott 2019). Fluids that display lower GS as prescribed by API will suffer cutting transportation problems. On the other hand, higher GS fluids demand high pumping rates, nevertheless, sometimes it is effective to have higher GS in order to mitigate different drilling related problems. Beg (2020) studied the 10 s GS and 10 min GS of TiO2 NPs. According to their investigation, the base mud with TiO2 NPs demonstrated \(7 {\text{lb}}/100\;{\text{ft}}^{2}\) and 10 \({\text{lb}}/100\;{\text{ft}}^{2}\) of 10 s GS and 10 min GS, respectively (Beg 2020). The 10 s GS in Beg (2020) was above the API recommended practices, which clearly indicates a higher pump pressure requirement for this mud system. On the other hand, the study conducted by Lalji et al. (2021) shows that when GO was used in the base mud, the 10 s GS rose from 6 \({\text{lb}}/100\;{\text{ft}}^{2}\) at 0.1 wt. % to 8 \({\text{lb}}/100\;{\text{ft}}^{2}\) at 0.5 wt. %, going beyond the API protocols. Additionally, 10 min GS remained constant at 8 \({\text{lb}}/100\;{\text{ft}}^{2}\) (Lalji et al. 2023c). During the experimental investigation, the 10 s and 10 min GS of the base mud were 1 \({\text{lb}}/100\;{\text{ft}}^{2}\), which were lower than the API prescribed range. However, with the addition of particles it improves and goes in the desired range. Moreover, GO/TiO2 particles showed more efficacy by increasing GS higher than TiO2 particles as shown in Fig. 6a. However, both particles show flat rheology, which indicates no substantial changes in GS with time (Elkatatny 2019). Figure 6b shows the GS measured at a 10 min interval. According to API recommended practices, a drilling fluid should exhibit GS 10 min in range of \(2 - 35 \;{\text{lb}}/100\;{\text{ft}}^{2}\) (Biwott 2019). 10 min GS was substantially improved with the addition of TiO2 and synthesized GO/TiO2 particles. However, when the TiO2 particles are supported with GO, the efficacy of the particles increases, which improves the gelation and cutting suspension characteristics of the base mud. Moreover, all the six samples were capable enough to make the drilled cuttings suspended when experiencing static conditions.
Effect of particle on filtrate volume loss
The amount of water separated from the mud system is measured using API low pressure and low temperature filter press test. Drilling mud that demonstrates high fluid loss volume is undesirable as it gives rise to complications such as formation damage and wellbore instability (Deng et al. 2015). According to Beg (2020) study, the base mud with TiO2 NPs showed 30.2 mL of fluid loss before the hot rolling test (Mukarram Beg 2020). Moreover, a filtrate volume of 20 mL was recorded by Kai Wang et al. (2020), when their group used 0.1 wt. % GO (Kai Wang 2020), while when GO was used by Rafieefar et al. (2021), it provided 9.2 mL of fluid loss at 0.15 wt. % (Rafieefar 2021). In the current work, the base mud loses 48 mL of filtrate after 30 min of testing. This volume was substantial, and it shows that this type of WBM will not be feasible for drilling operations. However, as the NPs were added the filtrate loss started to get lower as shown in Fig. 7. The maximum fluid loss volume was 40 mL/30 min in Sample 1 (0.75 g of TiO2 particle). On the other hand, minimum fluid loss volume was recorded in Sample 6 (2.25 g of GO/TiO2 particle) 4.8 mL/30 min. This fluid loss volume was 7.5 times lower of what the TiO2 particles provided at similar concentration. Additionally, it was below the filtrate volume loss recorded by different scholars, when used these two particles as separate entities (Kai Wang 2020; Bayat and Shams 2019). The GO/TiO2 sheet with its high surface area and high adsorption capacity adhere to the filter paper and block the micro and nanopore spaces. A superior barrier on the face of the filter paper is generated that prevents the penetration of water molecules. The GO assists TiO2 in terms of more oxygen-bearing functional groups, which ultimately enhances the adsorptivity of GO/TiO2 particles due to high ionic/electro communications, which reduces the fluid loss volume (Wang et al. 2019).
Mud cake permeability, thickness and texture
One of the most critical properties of any drilling mud is to demonstrate minimum fluid loss volume. Wellbore instability, formation damage, and differential sticking are some of the most unwanted effects that arise with the filtrate loss from the mud. Therefore, an efficient mud system should demonstrate lower fluid loss volume along with the formation of fine, compacted mud cake and low permeability. According to the study conducted by Ikram et al. (2022), the mud cake thickness of commercial GO at 0.5 ppb was 1.13 mm (Ikram et al. 2022), which was lower than raw welding waste material and welding waste derived GO. Similarly, a study conducted on TiO2 NPs by Bayat and Shams (2019). According to their study, TiO2 NPs at 0.1 wt. % showed 0.17 cm and 1.00 mD of mud cake thickness and permeability of mud cake respectively (Bayat and Shams 2019). In the current work, the mud cake permeability and thickness of each sample in this study is shown in Fig. 8. The base mud with no concentration of NPs showed the maximum permeability of \(2.01 \times 10 ^{ - 4} \;{\text{mD}}\). On the other hand, when NPs were added, sample 1 showed the maximum permeability of \(1.05 \times 10 ^{ - 4} \;{\text{mD}}\). This sample contains the least concentration of TiO2 particles. The mud cake thickness of \(0.15 \;{\text{mm}}\) for this case was also higher than any other sample. However, as the concentration of TiO2 particles increases in the mud system, permeability and thickness of the mud cake decreases. On the other hand, the mud sealing capacity improves considerably with the addition of GO/TiO2 particles. When 2.25 g of GO/TiO2 particles was added in the base mud, w and \(t = 0.078\; {\text{mm}}\) was recorded. Almost \(12\;{\text{ times}}\) reduction in permeability and \(2x time\) reduction in thickness was observed when compared with samples having exactly the same concentration of TiO2. Moreover, it was also performing better than the GO and TiO2 results gather my Ikram et al. (2022) and Bayat and Shams (2019) respectively.
Figure 8 also displays the visuals of mud cake gathered after the filter press experiment. In the observation, it is apparent that as the quantity of the particle increases, the color of the mud cake becomes slightly dark. Moreover, the mud cake becomes dense, compacted and thin with an increase in the particle weight %. This clearly shows that the particles effectively block the permeation channels present on the filter paper and minimizes the water loss volume. The GO/TiO2 particle increases the filtrate viscosity, thus reducing the filtration rate of the mud. The hydrogen bonding present between the functional groups in GO was the main cause of strong filter cake over the surface of filter paper. Furthermore, as the concentration of particles increases, the GO/TiO2 particle creates a robust structure covering the micropores, and consequently, a decrease in fluid loss volume was recorded.
Performance of KCl, PAC and GO/TiO 2 in shale swelling mitigation.
The performance of the synthesized GO/TiO2 nanoparticles in terms of mitigating the shale swelling was compared with potassium chloride (KCl) and polyanionic cellulose (PAC). Full factorial design (FFD) of experiment methodology was implemented to study the efficacy of three additives in minimizing the shale swelling behavior. For the FFD, the concentration of particles in the WBM system was divided into two levels. Based on the mathematical expression of \({2}^{n}=8\) experimental runs were conducted. Figure 9a displays the importance of each particle in controlling the shale swelling through the Pareto chart. It can be observed that only GO/TiO2 nanoparticles exceed the significance line, which clearly indicates the efficacy of this particle in controlling the penetration of water into the shale pellet. On the other hand, PAC and KCl were ineffective in mitigating the shale swelling characteristics. The interaction of these two entities was the main cause of their failure. The PAC is sensitive in presence of the monovalent and divalent cations (Mohamed Khodja et al. 2010). The presence of K+ ions in the WBM system dehydrates the polymeric material leading to a decrease in fluid viscosity. Prior research has shown that low fluid viscosity high will be the filtration rate and lower shale swelling controlling behavior (Bülichen and Plank 2012). Therefore, the dehydration effect substantially reduces the performance of PAC.
The Pareto chart was further validated through an interaction plot as shown in Fig. 9b. All the three particles displayed a negative trend. This movement indicates that as the weight percentage of particles increases, there are some notable reductions in the shale swelling behavior. The increase in particle concentration will decrease shale swelling. The effect of both the particles on the shale swelling followed the following trend \({\text{Shale swelling}}_{{{\text{KCl}}}} {\text{ > Shale swelling }}_{{{\text{PAC}}}} {\text{ > Shale swelling }}_{{{\text{GO/TiO}}_{{2}} }}\). Conversely, the quantity of the particles follows a reverse order \({\text{Concentration }}_{{{\text{GO/TiO}}_{{2}} }} {\text{ < Concentration }}_{{{\text{PAC}}}} {\text{ < Concentration }}_{{{\text{KCl}}}}\).
In addition, the interactive effects of the three particles with one another were also assessed using the 3D surface plots and contour plots as shown in Fig. 9c and d. The most effective interaction was observed between the nanoparticles and the polymeric material followed by nanoparticles with salt. The long chain of PAC interacted with GO/TiO2 sheets to plug the pore spaces present in the shale pellet. Similar behavior was also observed in KCl and GO/TiO2 sheets, which is also responsible for the minimization of fluid loss volume and maintaining the shale stability. However, the interaction between KCl and PAC was below par. As the concentration of both the particles increases in the mud system, a notable increase in fluid loss volume was recorded, which eventually decreases the shale stability. Sensitivity of PAC toward KCl was the main reason for their failure as a fluid loss control additive.
Figure 10 demonstrates the possible mechanism behind shale swelling mitigation through GO/TiO2 particles. The shale surface becomes hydrophobic after its interaction with the GO/TiO2 nanoparticle, thus preventing the penetration of water molecules into the shale nanoplatelets. In addition, the individual GO/TiO2 sheets can plug the micropores and significantly reduce the water movement. Moreover, a GO/TiO2 sheet has a strong tendency for creating an interparticle hydrogen bonding with its other sheets and other additives present in the system. Individual GO/TiO2 plates could attract toward one another and prevent the migration of water from the mud into the shale structure.
Conclusion
The current study was divided into two parts. In the first part, GO/TiO2 nanoparticles were synthesized using the hydrothermal method, which was then added in the WBM to improve its characteristics. The GO/TiO2-WBM properties were compared with anatase-TiO2-WBM. In the second part of the study, shale pellets were prepared in a hydraulic compactor, and interacted in LDSM with the WBM containing GO/TiO2 nanoparticles, salt and polymer. The purpose was to investigate the influence of these entities on shale swelling behavior. The pertinent conclusions were drawn from the study:-
-
1.
The presence of GO/TiO2 nanoparticles greatly improved the rheological properties of WBM. The impact of GO/TiO2 nanoparticles was far superior to the anatase-TiO2.
-
2.
The GO supports TiO2 through oxygen-bearing functional groups, which eventually improves the adsorptivity of GO/TiO2 particles in the micro and nanopores and reduces the filtrate loss volume. Almost 2.5 times reduction in fluid loss volume was noted in GO/TiO2 particles.
-
3.
The addition of GO/TiO2 nanoparticles influences the mud cake’s microstructure. Thin, compacted and lower permeability mud cake was obtained from GO/TiO2-WBM. The hydrogen bonding between the functional groups in GO was responsible for compactness of the filter cake
-
4.
Based on the FFD design of the experiment, the GO/TiO2 nanoparticles were the most influential particle in reducing the shale swelling and maintaining the wellbore integrity. These particles are responsible for developing a strong interparticle hydrogen bonding between its associated molecules, which prevents the fluid migration into shale pellets.
-
5.
The impact of KCl and PAC on the shale swelling was relatively minor. The polymer PAC was dehydrated in presence of monovalent cations, which impacts their performance in minimizing the shale swelling.
Based on the findings, it can be decided that the performance of TiO2 nanoparticles can substantially improve from graphene oxide support. Moreover, the GO/TiO2 nanoparticles can act as a potential rheological modifier and fluid loss control agent in WBM systems, as its characteristics are superior to salt and polymeric materials.
Abbreviations
- TiO2 :
-
Titanium dioxide
- WBM:
-
Water-based mud
- OBM:
-
Oil-based mud
- KCl:
-
Potassium chloride
- PAC:
-
Polyanionic cellulose
- FFD:
-
Full factorial design
- PV:
-
Plastic viscosity
- YP:
-
Yield point
- GS:
-
Gel strength
- AV:
-
Apparent viscosity
- LPLT:
-
Low pressure low temperature
- mD:
-
Milli-darcy
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Lalji, S.M., Haneef, J. & Hashmi, S. Application of graphene oxide/titanium dioxide nanoparticle on the rheological, filtration and shale swelling characteristics in water-based mud system: experimental and full factorial design study. Chem. Pap. 78, 5085–5101 (2024). https://doi.org/10.1007/s11696-024-03454-x
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DOI: https://doi.org/10.1007/s11696-024-03454-x