Abstract
This study investigates Li+ ion-conducting biopolymer blend electrolytes-based on chitosan (CS) and potato starch (PS) with glycerol plasticization. The advanced techniques including FTIR, impedance, TNM, LSV, and CV were employed to characterize the compositional and electrochemical properties of the solid films. The FTIR analysis indicates significant influence of glycerol on polymer/salt interactions, evidenced by the shift of FTIR bands to lower wavenumbers, signifying an increase in free ions within the host polymer system. Impedance results indicate that plasticizer addition reduces the bulk resistance to an optimum value of 49 Ω. The calculated DC values demonstrate the suitability of the electrolyte for use in energy storage applications (ESAs) with the highest ionic conductivity of 2.01 × 10−4 S cm−1. The high values of both \({\epsilon }^{{\prime }}\) and \({\epsilon }^{{\prime }{\prime }}\) at lower frequencies are due to interfacial polarization and the accumulation of charges, respectively. The sample with the largest plasticizer content has shown the highest \({\epsilon }^{{\prime }}\) of 112.4 at 105 Hz. The shifting of tan δ peaks to the higher frequency side with the increase of plasticizer indicates an increase in the mobility of cations. The combination of tan δ plot and Argand plot was used to explore the dominant mechanism in ion conduction. The electrochemical studies were performed to detect the ability of the films to be used for EDLC applications. The TNM (tion=0.947) and LSV (decomposition voltage = 3.1 V) values favor the films for ESAs. The pattern of CV curves at various scan rates established the successful design of the EDLC device. The calculated capacitance from the area under CV curves is sufficiently high. The capacitance was influenced by scan rates and changed from 12.92 to 38.68 F/g.
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Introduction
Recently, there has been a notable focus on solid polymer electrolytes (SPEs) owing to their versatility and the simplicity of creating them as polymer films. In contrast, conventional synthetic polymers typically come from petroleum sources and are often non-degradable, posing environmental concerns. Consequently, a concerted effort has been made to develop biodegradable polymer electrolytes capable of maintaining high ionic conductivity (σ). These sustainable materials have the potential to replace non-degradable polymers in a variety of applications, offering a more eco-friendly alternative while still meeting the critical requirement of efficient ion conduction [1, 2]. Notably, industrial innovators and researchers have been particularly interested in exploring the electrochemical capabilities of polymer electrolytes (PE) in the context of various device applications, with a focus on fuel cells [3], batteries [4], and supercapacitors [5].
Polymer-based electrolytes are solvent-free setups in which the conduit for ionic conduction is formed by incorporating ionic salts into a polymer framework [6, 7]. Unfortunately, the inherent low σ of polymers limits their applicability, prompting the development of various research methodologies to enhance the ionic conduction and electrochemical properties of these polymer-based electrolytes. These approaches encompass methods like introducing nanofillers [8], incorporating plasticizers [9], employing blending processes [10], or utilizing co-polymerization [11] to improve their performance. Due to its ease of preparation and the dual role of forming new complexation sites between the polymer blend and the ionic dopant, ultimately leading to improved ionic conduction, the blend approach is a favorite among researchers [12,13,14]. Natural biopolymers, such as CS and PS, stand out for their cost-effectiveness, offering environmentally friendly alternatives with considerable economic advantages. Their abundance and versatility make them attractive choices for various applications, providing a sustainable and affordable solution in material science. Our previous study combined CS with PS and introduced doping with either KSCN or NH4SCN [15, 16]. Our investigations revealed that this polymer blend system, composed of both CS and PS, displayed substantially superior ionic conduction properties when contrasted with individual polymers and other polymer blends frequently utilized as electrolyte systems [17, 18]. This improvement can be attributed to hydroxyl (−OH) and amine (−NH2) groups in the polymer chain. These groups simplify the conduction pathway and, when combined with an ionic dopant, increase σ.
Polymer blending and incorporating nano-fillers are essential in elevating the structural, dielectric, and σ of polymer-based electrolyte systems. For blending, previous studies have demonstrated noteworthy advancements. For instance, the blending of polyvinyl alcohol/polyvinyl pyrrolidone (PVA/PVP) with Li+ incorporation exhibited improved conductivity properties, rendering it suitable for battery applications [19]. Another study explored carboxymethyl cellulose/polypyrrole (CMC/PPy) blends with varying PPy concentrations, showcasing their promise as cost-effective blends with excellent chemical and physical characteristics for energy storage devices [20]. Incorporating nano-fillers further enhances the performance of these electrolyte systems. In previous studies, gold nanoparticles (Au-NPs) and TiO2 nanoparticles were introduced into a (PVP/PVA/CMC) blend, creating novel nanocomposites with exceptional capacitive behavior [21, 22]. Another investigation successfully incorporated graphene nanoplatelets (GNP) and copper nanoparticles (Cu NPs) into polystyrene (PS), resulting in significantly improved charge/capacitive storage abilities for the prepared nanocomposites [23].
Including plasticizers is a straightforward but crucial method to enhance the conductivity of complexes produced by polymer blends and ionic dopants. Plasticizers such as glycerol [24], dimethylacetamide (DMA) [25], tetra (ethylene glycol) dimethyl ether (TDE) [26], propylene carbonate (PC) [27], and ethylene carbonate (EC) [28] are known nonvolatile organic solvents and low molecular weight polymers that have proven successful in external methods. In a previous study, Chai and Isa plasticized CMC doped with oleic acid with glycerol to increase its conductivity to 1.64 × 10−4 S/cm [29]. Similarly, YM Yusof, and M.F.Z. Kadir used glycerol as a plasticizer in blending methylcellulose (MC)-PS doped with LiClO4, achieving higher σ at 4.25 × 10−5 S/cm [30]. Another study by Shukur et al., focused on CS-starch blended biopolymer electrolytes, enhancing σ to 1.02 × 10−4 S/cm by adding EC and using NH4NO3 as the ionic dopant [31]. In a separate effort, DC Dragunski, and A Pawlicka used starch polymers with glycerol (30% of starch mass) as plasticizers, resulting in a conductivity value of 5.05 × 10−5 S/cm [32]. These findings demonstrate that plasticization is a highly promising approach for enhancing the σ of polymer complexes, with optimization achieving values ranging from approximately 10−4 to near 10−3 S/cm.
Despite extensive research in polymer electrolytes, there is a gap in a suitable model for describing the ionic conduction mechanism. This is primarily due to the focus on enhancing σ and the challenges associated with understanding ion conduction, especially with varying conductivity values. The demand for PE systems with exceptional σ is crucial for efficient charge carrier transport in electrochemical devices. These charge carriers include both anions and cations, with anions typically exhibiting lower charge transport capabilities due to their bulkier nature. To bridge this gap, numerous well-documented approaches have been employed to assess transport properties, such as FTIR deconvolution [9], Broadband Dielectric Response (BDR) [33], Rice and Roth models [34], Trukhan model [35], and Nyquist fitting [36], all of which contribute to our comprehension of the electrolyte’s conduction characteristics. Bandara and colleagues [33] extensively explored the BDR method and found that it’s only suitable for Nyquist plots featuring a combination of semicircles and spikes. On the other hand, the Rice and Roth method is particularly effective when dealing with Arrhenius-type behavior. Still, it can sometimes provide questionable results when assessing the transport properties of PEs [36]. When considering transport property parameters, the Trukhan method assigns substantial significance to the characteristics of loss tangent (tan δ) peaks, including their shape and intensity. These tan δ peaks are associated with relaxing dipoles and are typically found in regions of low σ [6].
This study aims to synthesize innovative biopolymer-based electrolyte systems, which have been unexplored so far, to enhance our understanding of the physicochemical properties and impedance response governing the role of glycerol as a plasticizer. The objective is to increase the conductivity and ion transport capability of a polymer blend electrolyte (PBE). Our research specifically explores the influence of glycerol addition on the molecular properties and phase transitions within the PBE. Additionally, we analyze ion transport and conductivity properties using electric equivalent circuit modeling, providing valuable insights into the field. Our approach enhances comprehension of relationships assessed through impedance spectroscopy in solid polymer electrolyte (SPE) systems. This contributes to designing polymer blends with CS and PS, utilizing environmentally friendly and cost-effective materials for improved properties. These blends hold promise for next-generation electrochemical devices. The research aims to develop a new biodegradable electrolyte from natural sources, particularly for electrolyte systems. The ultimate goal is to employ this newly synthesized eco-friendly electrolyte in energy storage devices, such as electric double-layer capacitors (EDLC), which the literature has not examined.
Methodology
Reagents
To prepare for CSPS, we employed a blend of biopolymers consisting of 40% soluble starch from potatoes (PS) [(C6 H10O5)n], and 60% CS, which is 60% deacetylated chitin with a molecular weight ranging from 310,000 to 375,000 Da and a viscosity of 800–2000 cP. As the source of ions, we selected lithium perchlorate (LiClO4) in its ACS reagent-grade form, characterized by a purity of 99% and a molecular weight of 106.39 g/mol. Glycerol, with a molecular weight of 92.09 g/mol, served as our chosen plasticizer, and we incorporated it at concentrations of 11%, 22%, 33%, 44%, and 55%. To formulate the solvent, we utilized a mixture of deionized water and 1% acetic acid (glacial, purity ≥ 99.7%, molecular weight: 60.05 g/mol). In the electrode preparation for electrical double-layer capacitors (EDLC), we employed a blend of carbon black (CB) and activated carbon (AC) sourced from Alfa Aesar. Furthermore, we used polyvinylidene fluoride (PVdF) and N-methyl pyrrolidone (NMP) from Merck as our binder and solvent, respectively. The PVdF employed was in an anhydrous form, boasting a purity level of 99.5% and a molecular weight of 99.13 g/mol.
Synthesis of CSPS film (CSPS-LiCl4-Gly)
The synthesis of CSPS was carried out using a simple solution casting method, following the procedure described below. Initially, 0.6 g of CS, constituting 60% by weight, was dissolved in a 70 mL solution of highly diluted acetic acid (1% concentration) with continuous stirring for a period of 24 h. At the same time, a similar solution was heated to 95 °C and stirred continuously for 1 h to dissolve 0.4 g of soluble starch (PS), accounting for 40% of the total weight. An essential aspect of this process was the precise combination of these proportions of CS and PS biopolymers in the presence of acetic acid as a solvent. According to the references [37, 38], this particular blend was found to be crucial for improving ion transport through the host matrix. In the dissolution process of the polymers (CS and PS) 1% acetic acid was added to distill water, which created a highly diluted (acetic acid + distill water) solvent to facilitate the dissolution process by reducing the PH of the solvent (PH = 5). In addition, the acetic acid solution aids in breaking the strong hydrogen bonds in CS, promoting its dissolution and enhancing its conductivity by increasing bond rotation and segmental motion of chain and side groups. Following this, the two solutions were merged, and 40 wt% of LiClO4 dopant salt was incorporated into the mixture, with continuous stirring sustained for 24 h. Afterward, different concentrations of glycerol were introduced into the mixture and stirred for an additional 20 h. Indeed, in the preceding work [37], the optimal blending ratio for two polymers was initially established, focusing on a high amorphous region. This ratio was then utilized, and varying weight percentages of salt were systematically added to the polymer blend to achieve the best ion-conducting system. Subsequent to these experiments, the PBE with a fixed amount of dopant salt, exhibiting the highest measured conductivity using an LCR meter, was carefully selected. In this investigation, relying on the aforementioned knowledge, the impact of glycerol on the ionic conductivity of polymer electrolytes was explored by altering its concentration in the prepared samples to further augment the system’s conductivity. Table 1 lists the characteristics of the synthesized films and their corresponding designations.
Samples were put into labeled Petri dishes and air-dried for 14 days in a room with a relative humidity of 15%. A desiccator with silica gel inside was also used to dry the samples completely. These films can be used for the characterization and fabrication of EDLC. A digital micrometer was used to measure the thickness of the film. The main stages of the solution casting process for preparing CSPS based films are shown graphically in Fig. 1.
Instrumentation and Characterization of CSPS
Examinations of Structure and Composition
FTIR spectroscopy was performed at room temperature conditions using the transmittance mode. This method involves amplifying and digitizing weak signals from the sample to display a well-defined signal on a screen. The analysis was performed using the “Spotlight 400 Perkin Elmer” spectrometer, which covered the wavenumber range from 400 to 4000 cm−1 with a resolution of 1 cm−1. Throughout the examination, specific peaks in the spectra were discerned and grouped into various functional groups (FGs) and vibrational modes.
Electrical Conductivity Characteristics
Electrochemical impedance spectroscopy (EIS) was used to inspect the electrochemical and σ properties of CSPS membranes in a frequency range of 100 Hz to 2 MHz. A compression spring mechanism ensured the connection between the sample holder and the electrolyte was tight. To avoid possible damage to the sample during the test, a potential amplitude of only 10 mV was chosen, and the LCR meter was connected to a computer for data acquisition. The following formula, as referenced in [39], was applied to calculate the electrical conductivity (σ):
The formula mentioned above involves the thickness (in cm), represented as (\(B\)) and (\(S\)) signifies the area (in cm2) of the membranes. To ascertain the bulk electrolyte resistance (\({R}_{b}\)), we examined the Nyquist plot, plotting the real part (Zr) against the imaginary part (Zi). The point at which the line intersected the x-axis, designated as Zr, held significance for our analysis. The calculation of the real (\({\epsilon }^{{\prime }}\)) and imaginary (\({\epsilon }^{{\prime }{\prime }}\))parts of permittivity (\({\epsilon }^{*}\)) and modulus (\({M}^{*}\)) was done using the resulting relations: the real (Zr) and imaginary (Zi) parts of the complex impedance (\({Z}^{*}\)) [10, 28],
It is possible to derive the following relationship from Eqs. (2), (3), and (4) [30, 37].
\({C}_{o}\) is the vacuum capacitance in this case and is calculated as \({\epsilon }_{o} A/t\), where \(t\) is the film thickness and \(A\) is the film area. The frequency of the applied field, \(f\), is equal to \(\omega =2\pi f\), which is the angular frequency.
Measurement of Potential Stability and Carrier Transfer
Linear sweep voltammetry (LSV) was used to establish the potential range that is safe for application, and transference number measurements (TNM) were used to determine which charge carrier dominates the membrane. In conducting both LSV and TNM investigations, we employed an identical cell configuration, which involved positioning the CSPS based film between two stainless steel (SS) electrodes. To secure and optimize electrode contact, a compressed spring mechanism was employed.
In the LSV experiments carried out in this research, we employed a Digi-IVY DY2300 potentiostat manufactured by the V & A instrument brand (Shanghai, China), which was equipped with DY2300 Series software. The LSV test was conducted within a 4 V potential range at a scan rate of 0.01 V per second.
To calculate the ionic transference number (tion) in the TNM study, we monitored the recorded current over time. The remaining value, denoted as (1 − tion), corresponds to the electronic transference number (telectron). Following Wagner’s polarization method, we applied a constant DC voltage of 0.2 V across the SS /CSPS film/ SS cell during this test. To measure the current, we used a UT803 True RMS multimeter connected to a computer for data acquisition. Also, the digital power supply was a V & A Instrument DP 3003 DC source. By determining the initial current (Ii) and the steady-state current (Is) during the measurement, we estimated both tion and telectron values using the following equations [15]:
Electrode Preparation and EDLC Assembling
Before the assembly of the EDLC, a specific preparation process was carried out on the AC electrodes. Initially, 3.25 g of activated carbon (AC) were dry-milled with 0.25 g of conductive CB. This milling procedure lasted 25 min within a SS jar containing 6 steel balls with a 10-millimeter diameter. A vertical planetary ball mill was used to rotate the jar at a speed of 500 rpm. Then, 15 milliliters of NMP solvent was used to dissolve the carbonaceous material collected in the previous step. A binder of 0.5 g of PVdF was then added to the mixture. This blend was continuously stirred for a duration of 5 h until it reached a dense and evenly distributed black slurry. To create uniform electrodes, this slurry electrode material was applied onto an aluminum foil (AF) using the doctor blading technique, as illustrated in Fig. 2. Afterward, a drying process was conducted for 24 h in a drying cabinet set at 60 degrees Celsius. Finally, the sheet of electrode material was cut into circular shapes with a diameter of 1.6 centimeters to fit perfectly into CR2032 coin cells. These electrode discs had a thickness of 0.025 centimeters and contained approximately 0.00243 g of activated carbon. The mass of the active material was determined by weighing the AF substrate both before and after the coating process.
To construct the EDLC device, the most optimal ion-conducting film, based on its σ and potential stability, was positioned between two previously prepared circular AC electrodes. In the assembly of the EDLC, spacers were utilized to establish flawless connections and eliminate any gaps within the device. Subsequently, the lower and upper caps of the CR2032 coin cell were utilized to encase the EDLC device. Figure 3 provides a visual representation of the key components involved in the fabrication of the EDLC device.
EDLC Performance Characterization
The same potentiostat that was utilized for the LSV technique was also employed for conducting cyclic voltammetry (CV) measurements in this study. The CV measurements were carried out within a voltage range of 0 to 1 V, employing various sweep rates, namely 20, 50, and 100 millivolts per second (mV S−1), in order to assess the performance of the manufactured EDLC device. The data acquired through these techniques provided sufficient information to evaluate the overall performance of the device and determine the necessary parameters. Specifically, from the CV test, one could calculate the specific capacitance (Cspc) using the formula described in the references [40, 41].
In these formulas, (\(z\)) represents the scan rate for the applied potential, which spans from 0 (V1) to 1 V (V2), and (\(m\)) corresponds to the mass of the activated carbon (AC). The area of the cyclic voltammetry (CV) curve is extracted using Origin Lab 9.1 software.
Results and Discussion
FTIR Study
Fourier-Transform Infrared Spectroscopy (FTIR) is a highly valuable tool in the research and development of PEs due to its impressive sensitivity and non-destructive nature. This technique employs infrared (IR) radiation to stimulate the vibrations of chemical bonds, allowing for the detection of distinct spectral patterns associated with them. In our study, we conducted FTIR spectroscopy on all CSPS films, as portrayed in Fig. 4. We anticipated that complex interactions would occur between CS and PS, both rich in FGs, and the ionic components of the LiClO4 dopant salt, as well as glycerol with its multiple reactive hydroxyl groups. Our assessment involved observing alterations in the intensity and position of specific spectral bands and the emergence or disappearance of certain additional peaks to gain insights into these interactions [42]. The power of adding a dopant salt and increasing the glycerol content is readily apparent in Fig. 4, particularly in peak position shifts and variations in intensity. For instance, the axial O–H and stretching C–H bands are present in both the pure CS and PS spectra at wavenumbers of 3259.40 and 2924.31 cm−1, respectively [25].
However, with the inclusion of 40% by weight of the dopant salt and 11% by weight of the plasticizer, a distinct shift in the positions of these peaks is observed, moving to 3352.1 cm−1 and 2929.17 cm−1, accompanied by an increase in their intensities. The increased intensity of the O–H (hydroxyl) band compared to other bands can be attributed to the presence of strong hydrogen bonding within and between molecules. Furthermore, increasing the concentration of the plasticizer reinforces the dominance of this particular band. This effect is particularly pronounced because glycerol, which is used as the plasticizer, contains a substantial number of hydroxyl FGs. These hydroxyl groups readily engage in hydrogen bonding interactions, making the O–H band more prominent in the spectrum. In the LiClO4 spectra, the primary fingerprint peak associated with the linear anion vibration group (O−–Li+(M–O)) undergoes a noticeable change as the glycerol content increases. Specifically, this peak shifts to higher wavenumbers, transitioning from 615.11 to 619.97 cm−1, and experiences a significant decrease in intensity. This shift and reduction in the intensity of the O−–Li+(M–O) band has been observed previously in polymer blends containing metal salt systems when the glycerol concentration is increased [43]. Several groups of specific bands, including those containing N-H, O-H, C-H, and C = N functionalities in the range of approximately 1330.50–1640.61 cm−1, show notable changes in terms of their intensities and peak positions due to the addition of glycerol.
Furthermore, the α 1–4 skeletal glycoside bands, which are characteristic peaks of pure polyvinyl alcohol (PS), exhibit a shift in their positions. For instance, the peak that was initially observed at 1008.48 cm^(− 1) for the CPLCG1 sample (Fig. 4b) has shifted to 1023.05 cm^(-1) for the CPLCG5 sample (Fig. 4f). These alterations in the positions and intensities of specific bands serve as compelling evidence of interactions between the FGs of CS and PS and other electrolyte components, including the ions from LiClO4 salt and the glycerol plasticizer. This complexation process creates additional space, facilitating bond rotation and movement of chain segments. As a result, it opens up alternative kinetic pathways within the CSPS host blend, allowing for improved transfer and enhanced mobility of cations, specifically lithium ions (Li+) [42]. One potential conduction mechanism identified in this context is the Grothhus phenomenon, known as structure diffusion (Fig. 5). This mechanism involves the movement of Li+ ions between complex sites within the biopolymer blend. When an electric field is applied, dissociated Li+ ions traverse from one coordination point in the CSPS host to the next through a hopping process, driven by their weak electrostatic interactions with the coordination sites of the host medium [44]. At very high concentrations of glycerol (55 wt%), as depicted in Fig. 4f, the FTIR pattern closely resembles that of pure glycerol, exhibiting maximal hydroxyl peak strength. This corresponds to the multiple hydroxyl components in glycerol’s structure, which in turn creates alternative pathways for the movement of mobile ions [16]. The strong interconnection between the components of the electrolyte results in a more pliable and less ordered structure.
FTIR deconvolution is a valuable tool in the context of conductivity analysis, offering several advantageous qualities such as improved peak resolution, noise reduction, and the ability to investigate interconnections among deconvolution parameters. This method is particularly useful when assessing conductivity [42]. When employing FTIR deconvolution, it becomes possible to determine the ion fraction responsible for conducting electricity. As noted by Ramelli et al., the deconvolution of FTIR spectra allows for the isolation and manipulation of existing peaks, including adjustments to both their intensity and wavenumber [45]. The appearance of a peak within the 600 to 650 cm−1 range, attributed to ClO4, is a commonly employed indicator for investigating ion-ion interactions in PE when incorporating LiClO4 salt [43, 44]. The ClO4 bands display two discernible peaks spanning the 610 to 630 cm−1 range, implying the potential existence of up to two different ClO4 anion configurations within this material. Research conducted by Abarna et al. has previously proposed an association between Li+ ions and the ClO4 band in the 610–630 cm−1 range. Furthermore, lower frequencies below 610 cm−1, have shown the presence of CIP ClO4− anions, while approximately 610–630 cm−1 is indicative of free ClO4 anions [44]. The deconvoluted FTIR spectra of the prepared electrolyte are shown in Fig. 6a–d. From Fig. 6, the peaks of the contact-ion pairs are less pronounced than the peaks of the free ClO4 ions. This observation underscores the role of glycerol plasticizer in facilitating the dissolution of LiClO4 salt within the CS:PS matrix, and this interaction becomes apparent when these two components are combined.
The equations presented in reference [46] were employed to gauge the presence of free ions and contact ion pairs by analyzing the FTIR band areas [16, 36]:
In Table 2, the percentages of free ions (\(\text{F}\text{I}\)) and contact ion pairs (\(\text{C}\text{I}\text{P}\)) are indicated based on the respective areas, where \({A}_{f}\) represents the area of \(\text{F}\text{I}\), and \({A}_{c}\) represents the area of \(\text{C}\text{I}\text{P}\).
The elevation in σ can also be linked to the greater abundance of separated Li+ ions originating from LiClO4 salts. A connection between conductivity and the ratio of unbound ions has been confirmed in accordance with the research conducted by Aniskari and collaborators [47].
Electrochemical Investigations
Impedance Study
The impedance technique is a highly effective tool in materials science and electrochemistry, offering researchers valuable insights into the electrical characteristics of materials. Through the application of this method, it becomes feasible to recognize and distinguish among various electrical phenomena occurring at different frequencies. More precisely, the impedance technique offers the capability to identify the relaxation frequency and differentiate between the low-frequency tail and the high-frequency semicircular region, each associated with distinct bulk characteristics of the material being studied. Additionally, when employing EIS, it allows for the determination of the frequency-dependent real and imaginary components of impedance, which are referred to as Zr and Zi, respectively. In the field of materials research, the impedance technique proves to be indispensable for evaluating the DC conductivity [48]. This method involves subjecting an electrochemical sample holder to an alternating current (AC) field at various frequencies, thereby allowing for the calculation of EIS values. By doing so, researchers gain valuable insights into the electrical behavior of these films.
It can be noted from Fig. 7a–e that the inclined line observed in the plot is a result of the charge transfer resistance and capacitance associated with the electric double layer (EDL) formed at the interfaces of electrolyte and electrode, while the semicircle signifies the \({R}_{b}\) of the electrolyte membrane [49, 50]. This indicates the partially resistive and capacitive characteristics of the sample. Notably, as the concentration of glycerol increases in the prepared samples, the impedance plots exhibit a pronounced spike with a shrunk semicircle portion, indicating their highly capacitive nature. The nearly complete disappearance of semicircle in the largest plasticized samples indicates that ionic transport is facilitated by freely mobile ions, resulting in reduced electrolyte resistance and improved conductivity. To more precisely assess the influence of glycerol on the DC conductivity of the films, Table 3 provides a thorough summary of the collected data with their respective \({R}_{b}\) values. A clear enhancement in conductivity value can be noticed reaching the optimum value of 2.01 × 10−4 S/cm for the CPLCG5 sample. The outcomes underscore the significance of glycerol as a plasticizer in enhancing salt dissociation, attributed to its reactive polar hydroxyl groups and substantial \(\epsilon {\prime }\) (42.5) [51]. These properties contribute to reducing ion association and ultimately increasing the number of ion carriers. The incorporation of glycerol additionally enhances the flexibility of the film, facilitating polymer chain segmental motion [50]. The lowered energy barrier for polymer chain movement enabling a greater degree of rotation. This, in turn, facilitates easier ionic transport, leading to improved conductivity [52].
A useful approach in interpreting impedance data is comparing an imagined impedance component with its counterpart using electric equivalent circuit (EEC) modeling [52]. This comparison aids in understanding how the material’s electrical properties vary with frequency. The impedance graph typically includes a high-frequency segment, which aligns with a parallel combination of capacitor, usually known as constant phase element (CPE) or a leaky capacitor and resistor, as shown in the inset of Fig. 7, and a spike, which represented by another capacitor in series. The values of the EEC elements and fitting parameters are detailed in Table 4. The CPE values exhibit an increase with higher glycerol content, reaching the maximum magnitude for the largest glycerol content sample. The increased capacitance value is attributed to the greater availability of ions for electrode polarization with an increase in ion concentrations in the electrolyte [53]. The slanted inclination of the spike in the Nyquist plots may be attributed to ion migration and nonhomogeneity at the electrolyte/electrode interface [50]. The EEC fitting trend demonstrates a close match between practical and fitting data. The mathematical expressions for determining the impedance of the CPE element (\({Z }_{CPE})\), \({Z}_{r}\) and \({Z}_{i}\) associated with the EEC model for the sample displaying both a semicircle and spike shape are as follows [54]:
where
In this context, the \({n}_{1}\)parameter signifies the distortion of the arc shape from the ideal semicircle, indicating the deviation of the arc from the vertical axis. On the other and,\({n}_{2}\) highlights the slope of the spike in the low-frequency region, representing the deviation of the spike from the horizontal axis
Plasticizers are chemical compounds often added to polymer matrices to increase their flexibility and reduce their stiffness. In the context of electrolytes, these polymers are typically solid or semi-solid materials. By incorporating plasticizers, the PE becomes more flexibility, which allows the electrolyte to conform better to the outlines of the electrodes within a supercapacitor or electrochemical cell. This ensures enhanced interaction at the electrolyte and electrode interfaces, ultimately reducing the cell’s internal resistance. Plasticizers can improve ionic mobility within the PE by creating spaces or channels between polymer chains. These spaces provide pathways for ions to move more freely, thus increasing the overall σ of the electrolyte. This improved ion mobility results in better charge and discharge rates for the electrochemical device, making it more efficient. Plasticizers can impact on different parameters like viscosity, thermal stability, and mechanical strength. Engineers and researchers can select plasticizers that best match the requirements of the particular electrochemical device they are designing.
The comparison of DC σ values across various studies highlights the remarkable performance of the plasticized composite SPE films developed in this research. In the current study, it is evident that the film with the lowest \({R}_{b}\) value exhibits the highest DC σ. Specifically, the maximum DC σ achieved in the research is an impressive 2.01 × 10−4 S cm−1. This remarkable result was obtained with a glycerol concentration of 55 wt% in the CS:PS: LiClO4 electrolyte system at room temperature (RT), as detailed in Table 3. To provide context, a comparison with previous works in the field is noteworthy. For instance, YK.H. Teoh et al. reported a DC σ of 1.55 × 10−6 S cm−1 for the Corn starch: LiClO4:Glycerol system at room temperature [55], and YM Yusof et al. reported a value of 4.25 × 10−5 S cm−1 for the Methylcellulose(MC): PS: LiClO4:Glycerol system [30]. Notably, the DC σ achieved in the current research surpasses the values reported in these previous works, indicating the effectiveness of the developed CSPS films. Moreover, other studies have reported similar or comparable DC σ values in biopolymer electrolyte systems. For instance, CW Liew et al. achieved a DC σ of 1.47 × 10−4 S cm−1 for a PE system of Corn starch: LiPF6 with BmImPF6 plasticizer which was applied to a primary supercapacitor [56]. Similarly, KH Teoh et al. reported a DC σ of 1.23 × 10−4 S cm−1 for a biopolymer electrolyte system of Corn starch:LiClO4 and applied it to a primary barium titanate [57]. In conclusion, the DC σ achieved in the present research stands out as a noteworthy achievement, surpassing several previous studies in the field and demonstrating the potential of the developed CSPS films for various electrochemical applications.
Electrical Conductivity Study
Figure 8 displays the AC conductivity as a function of frequency at room temperature, providing fascinating insights into the characteristics of materials with differing levels of plasticizer content. This AC conductivity plot illustrates three distinct regions, each with its own characteristics and significance. The initial region, observed at low frequencies, is associated with the phenomenon known as electrode polarization. This region’s behavior varies with the addition of plasticizers. Electrode polarization emerges due to the buildup of charges at the interface between the electrode and the electrolyte. The degree of this polarization is impacted by the existence and characteristics of plasticizers within the system. In fact, interfacial polarization and the accumulation of charges in the bulk region are distinct electrical phenomena encountered in materials. Interfacial polarization occurs at boundaries between different materials or phases, resulting in the alignment or reorientation of dipoles. This phenomenon is attributed to variations in electric susceptibility or conductivity at interfaces and contributes to the overall dielectric behavior of materials, particularly at interfaces such as those between dielectric materials and electrodes in capacitors. On the other hand, the accumulation of charges in the bulk region involves the presence of excess charges within the volume or bulk of a material. This accumulation can arise due to conductivity, applied electric fields, or external influences, impacting the material’s overall conductivity and electrical response. While interfacial polarization predominantly occurs at interfaces, the accumulation of charges in the bulk region primarily takes place within the body of the material, highlighting the different spatial locations and influences of these two phenomena on the electrical properties of materials.
The AC conductivity second section of the graph signifies the intermediate frequency plateau, where long-distance ion movement transpires through a hopping mechanism. It is within this frequency range that the direct current (DC) conductivity is extracted. This plateau-like behavior signifies relatively stable ion transport, and the conductivity measured in this region provides valuable information about the material’s ability to support ion conduction [58]. The third segment in the AC conductivity diagram is marked by frequency dispersion. This phenomenon is linked to a heightened likelihood of ions moving from one location to another through hopping. Improved conductivity values in this range indicate an increased hopping frequency. In the high-frequency spectrum, two processes are in action: correlated forward-backward-forward migration (where ions may return to their original position), and successful hopping when the hopping frequency (wh) surpasses a critical threshold (Wh). This transition denotes the stage at which ions effectively jump to new locations as a result of relaxation, leading to an enhancement in conductivity [59, 60].
Dielectric Spectroscopy Study
The observed trends in both the \(\epsilon {\prime }\) and \({\epsilon }^{{\prime }{\prime }}\) offer valuable insights into the electrical characteristics of the investigated SPEs. Understanding these frequency-dependent changes is crucial for optimizing and tailoring these materials for various applications, such as in batteries, capacitors, and other electrochemical devices. Figures 9 and 10 present a comprehensive view of the frequency-dependent behavior of all SPEs of CSPS blend. These plots reveal a consistent pattern observed across all the samples, characterized by a decrease in the \(\epsilon {\prime }\) and \({\epsilon }^{{\prime }{\prime }}\) as the frequency increases. In the low-frequency range, a notable feature is the high \(\epsilon {\prime }\) observed. This occurrence can be ascribed to the prevalence of electrode polarization phenomena. Electrode polarization occurs when charges a mass or ions become fixed at the junction between the electrode and the electrolyte. This accumulation or immobilization results in an elevated \(\epsilon {\prime }\) in the lower frequency range. With increasing frequency, the influence of electrode polarization gradually diminishes, leading to a corresponding decrease in the \(\epsilon {\prime }\). This trend is commonly observed in dielectric spectroscopy and reflects the transition from low-frequency phenomena related to charge accumulation to higher-frequency behavior characterized by more mobile ions within the electrolyte [61]. Both The frequency-dependent behavior of the \(\epsilon {\prime }\) and \({\epsilon }^{{\prime }{\prime }}\) in plasticized systems is illustrated in Figs. 9 and 10. Notably, among all the samples, the system containing 55wt% glycerol exhibits the highest \(\epsilon {\prime }\) as the values are tabulated in Table 5. The rise in the \(\epsilon {\prime }\) can be attributed to several factors, including a high concentration of charge carriers and the amorphous nature of the system. Both the \(\epsilon {\prime }\) and \({\epsilon }^{{\prime }{\prime }}\) exhibit a decreasing trend as the frequency increases. This decrease is particularly rapid at low frequencies, and saturation is observed at high frequencies, as indicated in the figures. This behavior can be attributed to the inability of dipoles within the material to respond quickly to the changing frequency of the applied electric field. The delay between the field frequency and dipole oscillation results in the observed decline in \(\epsilon {\prime }\) and \({\epsilon }^{{\prime }{\prime }}\) with increasing frequency.
The observed variations in dielectric behavior offer valuable insights into the underlying mechanisms. At low frequencies, the high \(\epsilon {\prime }\) primarily comes from interfacial polarization, while the significant increase in \({\epsilon }^{{\prime }{\prime }}\) is a consequence of the movement of free charges within the material. These charges respond to the applied electric field, contributing to the overall dielectric response. At higher frequencies, the \(\epsilon {\prime }\) remains relatively stable due to the presence of space charge effects near the electrodes, linked to the concentration of charge carriers in close proximity to the electrodes. Nevertheless, these carriers cannot keep up with the periodic reversal of the electric field, resulting in a consistent dielectric response. It is essential to emphasize that the \(\epsilon {\prime }\) behaves differently in polar and nonpolar materials. In polar polymers, \(\epsilon {\prime }\) generally demonstrates a higher value and can be affected by factors such as temperature and the inclusion of plasticizers. With the growing concentration of plasticizers in polar materials, there is generally a concurrent elevation in \(\epsilon {\prime }\). This uptick is linked to the enhanced alignment of dipoles and the increased mobility of charge carriers, particularly as the temperature climbs. This behavior is well-documented in the literature and plays a critical role in understanding and optimizing the dielectric properties of materials for various applications [62, 63].
Loss Tangent Study
Figure 11 presents a graphical representation of tan δ plotted against frequency at various plasticizer concentrations. This plot offers valuable insights into the relaxation processes occurring within the material. At lower frequencies, there is a synchronization of the phase between polarization and the electric field, leading to a minimal loss angle or phase deviation. To put it in simpler terms, polarization closely tracks the electric field, resulting in minimal energy dissipation within the dielectric and generating only minimal heat.
However, as the frequency of the applied field increases, polarization progressively lags behind the electric field. This phase shift results in energy dissipation within the dielectric, leading to the generation of heat. When the tan δ reaches its peak, it signifies a resonance condition, indicating that the relaxation time of polarization matches the period of the applied field [64]. Jiang et al. [65] argue that the rise in the tan δ observed as the applied field frequency increases is mainly due to resistive losses. Essentially, mobile charges within the electrolyte layer encounter difficulties in keeping up with electric fields of higher frequencies. Figure 11 further illustrates an increase in tan δ with frequency, reaching a peak value before declining. An interesting observation is that the peak frequency of the maximum tan δ shifts to higher values as the glycerol concentration increases. This shift is attributed to the influence of plasticizers, which lead to an upward displacement of the peak frequencies. This phenomenon suggests that the relaxation time becomes shorter with higher plasticizer concentrations. This behavior aligns with the formula σ = σoeEa/kTε′, where Ea represents the activation energy. Given that the \({\epsilon }^{{\prime }}\) of the electrolyte system is boosted by the presence of plasticizers, it logically pursues that an increase in plasticizer concentrations results in a higher \(\epsilon {\prime }\), subsequently shifting the frequency at which the maximum tan δ is observed to higher frequencies [66].
In Fig. 11, the peak in the tan δ plot refers to the existing relaxing dipoles in all the samples. This relaxation peak shifts toward the high-frequency region with increasing glycerol content, indicating a reduction in relaxation time and highlighting the appearance of rapid segmental relaxation. In fact, with increasing glycerol content, that sample is expected to record a higher value of \(\epsilon {\prime }\) due to two main factors. First, glycerol has a room temperature \(\epsilon {\prime }\) of around 41, which is much higher than that of pure CS and PS [which is around 5]. Second, glycerol has multiple OH FGs that can significantly interact with the FGs of the host polymer blend (CS:PS). This interaction results in intra and inter-chain molecular hydrogen-bond interruption, enlarging the chain spacing and elongating disordering. This process improves the degree of rotation along with expanded interchain spacing and more free volume, which is ultimately crucial for an increment in the mobility of cation. According to Debye relaxation process, all dipoles in the system relax with the same relation time, which is called a single relaxation time approximation (Debye behavior) and appears as a single sharp peak in the plot. The single-relaxation-time model of Debye assumes a simple exponential decay of the relaxation function and a single relaxation time for some processes, which typically strongly diverges from the experimental observations in complex systems such as polymers and polymer composites (non- Debye behavior). Here, we have a broad peak (dispersion), which is a sign of the non-Debye relaxation time of the system, which is more expected in the case of polymer-based electrolyte systems. The broadness of the tan δ peaks indicates the attendance of multiple non-Debye-type relaxation processes within the material [67]. These observations highlight the complex interplay between frequency, plasticizer concentration, and the material’s dielectric properties, shedding light on the intricate relaxation dynamics occurring within the electrolyte system.
The Electric modulus (\({M}^{*}\)) Study
The \({M}^{*}\) is a fundamental tool for comprehending the low-frequency bulk relaxation behavior of materials. It serves as a valuable approach to tackle common challenges such as electrode polarization (EP) and conduction effects that might otherwise obscure relaxation when studying dielectric permittivity [68, 69]. Complex impedance data, represented by Zr and Zi, are utilized to calculate M’ and M” components of the \({M}^{*}\) [69, 70], as described by Eqs. (8) and (9). In Fig. 12 it becomes evident that at lower frequencies, the M’ value approaches zero. The M’ spectra exhibit a distinctive pattern contrasted with the \({\epsilon }^{{\prime }}\) behavior. As demonstrated in Fig. 13 it showcases the M” spectra for all the tested samples, particularly at low frequencies, where a high \(\epsilon {\prime }\) value is observed. Recent research has underscored the importance of utilizing the \({M}^{*}\) framework to investigate electrical relaxation processes [71]. The traditional exponential Debye model lacks the ability to adequately characterize this relaxation, as evidenced by the asymmetric shape of M”. To gain a thorough insight into the electrical conductivity of polymer electrolytes, it is essential to grasp the involved relationship between the movement of ions and the motion of polymer segments [72,73,74]. It is noteworthy that an increase in glycerol concentration leads to the shifting of the relaxation peak towards higher frequencies, as depicted in Fig. 14. In the context of a solid electrolyte system involving plasticized CS:PS:LiClO4:glycerol, the relaxation dynamics exhibit characteristics of both viscoelastic relaxation and conductivity relaxation. To investigate the effects of varying plasticizer concentrations on these relaxation mechanisms within the polymer electrolyte, Argand diagram is plotted, as illustrated in Fig. 14.
Figure 14 displays a series of Argand plots corresponding to varying levels of plasticizer. In the figure and its inset, an incomplete half-semicircle is evident, which deviates from the Debye model (i.e., a single relaxation time). This suggests the existence of a range of relaxation times that need to be considered to fully interpret the data. In such scenarios, a greater number of ions and dipoles become engaged in dielectric relaxation. The extensive segmental movements of polymer chains, which involve breaking and reformating coordination bonds crucial for ion transport, contribute to this phenomenon. These movements simultaneously create the necessary free space for cation transport, aiding in the interpretation of the data [75]. Additionally, the incorporation of higher plasticizer concentrations induces a clear shift in the Argand curves, causing them to migrate toward the origin. This transformation can be ascribed to the augmented ionic mobility facilitated by the plasticizers, which, in turn, leads to a decrease in both Zr and Zi values, indicative of the amplified conductivity. When the Argand plots (M” vs. M’) exhibit a semicircular shape in the transition from CPLCG4 to CPLCG5, it becomes evident that the relaxation process is predominantly influenced by the dynamics of conductivity relaxation. This suggests a separation between the motion of ions and the motion of polymer segments [76]. In contrast, the Argand plots provide insight into a distinct viscoelastic relaxation behavior for CPLCG1-3, evident in an incomplete semicircle within the M″ vs. M′ plot. Thus, Argand plots serve a crucial role in differentiating the ion transport mechanism in quasi-SPEs, offering insights into the complex mechanisms governing their electrical characteristics.
Electrochemical Analysis
Transference Number Measurement (TNM)
TNM is a valuable methodology for characterizing the intricate process of ion transport within SPEs. This technique is essential in developing and fine-tuning SPEs for their diverse applications across electrochemical devices. To further assess the viability of CPLCG5, which boasts the highest level of conductivity among the tested electrolytes, TNM analysis was meticulously carried out. The aim was to discern whether this electrolyte holds promise for integration into energy devices. The TNM analysis took place under standard room temperature conditions, offering a comprehensive examination of how specific charge carriers, whether ions or electrons contribute to the overall behavior of the electrolyte.
The ensuing Fig. 15 encapsulates a wealth of information. Initially, there is a marked and abrupt drop in the initial current (Ii), followed by the attainment of a steady-state current (Iss) commencing at the 80th second and persisting thereafter. This initial current drop is attributed to the limited mobility of ions, where the character of the stainless-steel electrode impedes ion diffusion. During this phase, only electrons are permitted to partake in the transport mechanism. The notable surge in current at the outset is due to the joint involvement of ions and electrons. Initially, cations and anions migrate in opposite directions toward the electrode surface from the electrolyte’s bulk, forming a double-layer at the electrode-electrolyte interfaces. This process leads to polarization. The polarization of the cell ends when it reaches a stable state, with the subsequent current flow being solely attributable to electrons. This shift to electron-dominant transport is the basis for determining the electron transference number (telectron) using stainless-steel electrodes. As time progresses, the establishment of diffusion layers on the electrode interface becomes instrumental in generating a steady state of current. These diffusion layers give rise to a substantial resistance within a passive ionic layer. Consequently, ions are no longer significant contributors to the current flow within this region. Once ions have been effectively reduced, a consistent current flow ensues, driven exclusively by electrons.
It is well established that the cation conductivity in the polymer-based electrolyte is significantly higher compared to anions, resulting in a much higher transference number for cations. This observation implies that the achieved ion transference number in this study is predominantly influenced by the mobility of lithium (Li+) ions in the electrolyte. Concerning the role of anions, it is reasonable that they form strong electrostatic interactions or are covalently linked to the hydroxyl FGs in the host matrix medium. This may lead to the anions being less involved in ion transport or ion-electron polarization, especially if they are large-sized bulk anions. Transference numbers, quantified as the ion transference number (tion) and the electron transference number (telectron), were calculated for the CPLCG5 electrolyte employing specific equations. Remarkably, the CPLCG5 electrolyte achieved a notably high tion value of 0.947, strongly indicating the predominant role of ions within the system [77]. A similar observation has been corroborated by previous studies, notably by Shukur et al. [38], which suggests that a tion value approaching unity signifies ions as the principal carriers of charge in the system. This consistent observation has been reported by other researchers, such as Rama et al. [78] and Tang et al. [79]. In summary, TNM analysis offers an insightful glimpse into the dynamic behavior of charge carriers within CPLCG5, providing a foundation for assessing its suitability for integration into energy devices.
LSV Study
Determining the breakdown potential of CPLCG5 through LSV is of great significance when evaluating its suitability for incorporation into energy storage systems such as solar cells, batteries, and supercapacitors [48]. Knowing the potential at which the electrolyte may experience oxidation and initiate degradation is essential for ensuring the durability and continued efficiency of these devices. As depicted in Fig. 16, the electrolyte exhibits remarkable stability, with no discernible changes in current observed below a potential of 3.10 V. However, beyond this threshold, a sharp increase in current becomes evident. This increase is attributed to the disruption of interactions between polymer chains and between the polymer and salt components, ultimately leading to polymer degradation [52].
The findings presented in this study indicate that the present system exhibits a reasonably broad electrochemical potential window before experiencing degradation. This window is wider compared to many other aqueous electrolytes but does not reach the broader potential range typically associated with ionic liquid (IL) electrolytes, which typically span from 3.5 to 4 V [80]. For instance, in previous studies, ((PEO–PMMA)– LiClO4–3 wt% nanofiller) was reported to remain stable up to 3.05 V [81]. Similarly, S Rudhziah. reported that CMKC/CMCE SPE demonstrated stability below 2.0 V [82]. The findings from this research align with those of previous studies focusing on magnesium-based electrolytes and suggest that the CPLCG5 electrolyte possesses the requisite stability for incorporation into Energy Density Layer Capacitors (EDLCs). This promising result positions CPLCG5 as a viable candidate for various ESAs, given its favorable electrochemical potential window and potential for long-term reliability in demanding operational environments.
Cyclic Voltammetry
The cyclic voltammetry analysis of the assembled EDLC consisting of with activated carbon and CPLCG5 reveals scan-rate-dependent behavior. The absence of distinct peaks in the CV plot confirms the predominantly capacitive nature of the device. The observed capacitance values are in line with the expected trends, reflecting the varying response of the EDLC at different scan rates, and are indicative of its performance characteristics in terms of ion accumulation and resistance. It is a well-established fact that the behavior of a capacitor, in this case, an EDLC, is influenced by the scan rate used during CV experiments. Therefore, multiple scan rates, specifically 20, 50, and 100 mV/s, were employed to thoroughly examine its characteristics. In Fig. 17, the shape of the CV plot undergoes distinctive changes, ranging from rectangular to leaf-like shapes, without any conspicuous peaks. According to the findings of Jäckel et al. [83], the presence of peaks in a CV plot typically indicates the occurrence of Faradaic current, which is associated with processes like intercalation and deintercalation. Such processes are not expected to take place in a capacitor like an EDLC. At increased scan rates, the motion of mobile ions within the system takes place quickly. Moreover, because of factors like internal resistance and the porous characteristics of the carbon electrode material, the correlation between voltage and current becomes contingent on the pace of ion movement [40].
The capacitance values of the EDLC, as outlined in Table 6, provide valuable insights. Notably, the capacitance (Cspc) is more substantial at lower scan rates and decreases as the scan rate increases. This behavior is consistent with expectations: at lower scan rates, the CV response tends to exhibit relatively flat plateaus, indicating the accumulation of ions at the electrode-electrolyte interface and low ohmic resistance, as exemplified in Fig. 17 [84, 85]. Table 7 displays the findings of various polymer-based electrolytes containing different dopant salts utilized in EDLC devices. These results are contrasted with the outcomes of our study, focusing on potential stability, ion transference number, and specific capacitance. Fortunately, the electrolyte prepared in this study exhibits favorable performance, making it suitable for applications in energy storage devices like EDLC. Notably, its performance surpasses many other studies documented in the literature.
Conclusion
To sum up, concentrated on biopolymer blend electrolytes plasticized with glycerol, emphasizing Li+ ion conductivity and employing various techniques. FTIR analysis underscored the substantial impact of glycerol on polymer-salt interactions, with a shift in FTIR bands indicating an increase in free ions within the electrolyte films. EIS measurements revealed that the addition of glycerol reduced bulk resistance and enhanced conductivity simultaneously. The EEC model provided a comprehensive view of the entire electrolyte system, equating it to realistic circuit elements for better visualization. Calculated DC conductivity values confirmed the suitability of these films for ESAs with a maximum conductivity of 2.01 × 10−4 S cm−1. Furthermore, the high \({\epsilon }^{{\prime }}\) and \({\epsilon }^{{\prime }{\prime }}\) values at low frequencies suggested interfacial polarization and charge accumulation. The shifting of tanδ peaks to higher frequencies and their broadening indicated enhanced cation mobility with non-Debye behavior. The combination of the tan δ graph with the Argand plot revealed that ion conduction happens through both viscoelastic and conductivity relaxation, depending on the concentration of glycerol in the prepared electrolyte system. Electrochemical studies indicated the suitability of the film for EDLC application, supported by a favorable TNM value for ions and a decomposition voltage of 3.1 V. CV curves at different scan rates demonstrated a well-designed EDLC device, exhibiting no signs of redox peaks and high capacitance values ranging from 12.92 F/g to 38.68 F/g. Overall, our findings suggest that these biopolymer blend electrolytes have great promise as effective materials for energy storage and EDLC applications.
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Acknowledgements
The authors gratefully acknowledge all the support for this study from the Ministry of Higher Education and Scientific Research-Kurdish National Research Council (KNRC), Kurdistan Regional Government. The support from the University of Sulaimani, University of Humburg, University of Charmo, University of Cihan Sulaimaniya, University of Raparin and University of Malaya are greatly acknowledged. The authors express their gratitude to the Researchers Supporting Project Number (RSP2024R348), King Saud University, Riyadh, Saudi Arabia.
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Conceptualization, SB; Data curation, RT; Formal analysis, DM, SB and RT; Funding acquisition, BA; Investigation, RT, SA and PS; Methodology, SA, HJ, RT and AA; Project administration, SB and MF; Resources, BA and HJ ; Supervision, SB and MK; Validation, DM, SA, PS, WO, BA, AA and HJ ; Visualization, DM and RT; Writing—original draft, DM and SB; Writing—review & editing, RT, SA, WO, PS, HJ, and A
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Aziz, D.M., Abdulwahid, R.T., Hassan, S.A. et al. Development and Investigation of Electrochemical and Dielectric Properties of Eco-Friendly Lithium-Ion Conductor Biopolymer Electrolyte for Energy Storage Application. J Polym Environ 32, 3845–3868 (2024). https://doi.org/10.1007/s10924-024-03198-5
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DOI: https://doi.org/10.1007/s10924-024-03198-5