Abstract
Four lanthanide coordination polymers, LaL3(H2O)2(1), LnL2(µ3-OH)(H2O)[Ln=Eu(2),Tb(3)] and ErL3·2H2O(4) were synthesized via hydrothermal reactions of lanthanide oxide with 4-pyridin-4-ylbenzonic acid(HL), and characterized by means of elemental analyses, infrared(IR) spectrometer, powder X-ray diffraction(PXRD), thermogravimetric analyses(TGA) and single-crystal XRD. The results reveal that complex 1 possesses a linear chain structure, complexes 2 and 3 possess isostructural ladder-like chains, while complex 4 possesses a 2D layer with 4-connected sql topology. Furthermore, the luminescence properties and UV-Vis spectra of complexes 2 and 3 were investigated.
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Supported by the National Natural Science Foundation of China(Nos.91122028, 21221001, 50872133) and the National Basic Research Program of China(Nos.2014CB932101, 2011CB932504).
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Fang, W., Yang, G. A series of lanthanide coordination polymers constructed from 4-pyridin-4-ylbenzoate. Chem. Res. Chin. Univ. 31, 187–191 (2015). https://doi.org/10.1007/s40242-015-4316-y
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DOI: https://doi.org/10.1007/s40242-015-4316-y