Abstract
Two new lanthanide complexes [Ln(2,3-DClBA)3(CH3CH2O)(H2O)]2n · n(4,4′-bipy) (Ln = Eu (1),Tb (2); 2,3-DClBA = 2,3-dichlorobenzate; 4,4′-bipy = 4,4′-bipyridine) have been synthesized by aqueous solution synthesis and characterized by elemental analysis and X-ray crystallography analysis. The results showed that complexes 1 and 2 are isostructural and are built of two-dimensional layered structures. Complex 1 belongs to triclinic system, space group P1̄, a = 9.7239(7) Å, b = 12.0736(13) Å, c = 14.6611(12) Å, α = 103.356(2)°, β = 93.0140(10)°, γ = 97.6200(10)°, V = 1653.7(3) Å3, Z =1, ρ = 1.735 g/cm3, μ = 18.453 mm−1, F(000) = 850, the final R = 0.0591 and wR = 0.0963 for all data. Complex 2 belongs to triclinic system, space group P1̄, a = 9.6990(7) Å, b = 12.0380(11) Å, c = 14.6060(12) Å, α = 103.274(2)°, β = 93.0930(10)°, γ = 97.4250(10)°, V = 1639.7(2) Å3, Z = 1, ρ = 1.764 g/cm3, μ = 2.694 mm−1, F(000) = 854, the final R = 0.0545 and wR = 0.0911 for all data.
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Acknowledgments
This work was supported by the National Natural Science Foundation of China (no. 21473049) and the Natural Science Foundation of Hebei Province (no. B2016205207). Science and technology program of Handan city (no. 1621202043-2) and Natural science program of Handan university (no. 16201).
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Ning, R., Jun-Chen, W., Wei-Jie, L. et al. Synthesis and Crystal Structures of Two New Lanthanide Coordination Polymers with 2,3-Dichlorobenzoic Acid and 4,4′-Bipyridine. Russ. J. Inorg. Chem. 64, 445–449 (2019). https://doi.org/10.1134/S0036023619040168
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DOI: https://doi.org/10.1134/S0036023619040168