Abstract
Rhodacarborane [(9-NMe3-7,8-C2B9H10)RhCl2]2 exhibited moderate catalytic activity in the reaction of annulation of arylcarboxylic acids with alkynes, giving naphthalenes as the major products. Effects of the substituent at the carborane ligand, as well as the nature of organic substrates, on the catalytic activity and selectivity of the reaction were estimated. In particular, it was revealed that a replacement of the NMe3 group at the carborane ligand with the SMe2 one leads to a significantly decreased activity of the catalyst.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1922–1926, October, 2021.
This work was financially supported by the Russian Science Foundation (Project No. 17-73-30036).
NMR expriments were carried out using the scientific equipment at the Center for the Study of the Molecular Structure at the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences and financially supported by the Ministry of Science and Higher Education of the Russian Federation. D. A. Loginov is grateful to the Plekhanov Russian University of Economics for providing access to electronic databases of scientific literature.
This paper does not contain descriptions of studies on animals or humans.
The authors declare no competing interests.
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Molotkov, A.P., Timofeev, S.V. & Loginov, D.A. Trimethylammonium-containing rhodacarborane [(9-NMe3-7,8-C2B9H10)RhCl2]2 as a catalyst for the annulation of arylcarboxylic acids with alkynes. Russ Chem Bull 70, 1922–1926 (2021). https://doi.org/10.1007/s11172-021-3297-x
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DOI: https://doi.org/10.1007/s11172-021-3297-x