Abstract
Our recent studies on the synthesis of metallacarboranes based on the cationic species [(Carb)M]+ are summarized. The labile complexes [Carb’M(Solv)3]2+ (Carb’ = 9-SMe2- 7,8-C2B9H10; M = Rh or Ir) and [Carb’ Fe(C6H6)]+ were suggested to use as synthons. The new method was employed to synthesize a great variety of sandwich, half-sandwich, and tripledecker complexes.
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References
T. P. Gill, K. R. Mann, Inorg. Chem., 1980, 19, 3007.
G. E. Herberich, A. Gaffke, H. J. Eckenrath, Organometallics, 1998, 17, 5931.
A. Salzer, H. Werner, Angew. Chem., Int. Ed. Engl., 1972, 11, 930.
A. R. Kudinov, M. I. Rybinskaya, Yu. T. Struchkov, A. I. Yanovskii, P. V. Petrovskii, J. Organomet. Chem., 1987, 336, 187.
G. E. Herberich, U. Englert, F. Marken, P. Hofmann, Organometallics, 1993, 12, 4039.
D. S. Perekalin, J. Holub, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii, B. Stibr, A. R. Kudinov, Organometallics, 2005, 24, 4387.
A. R. Kudinov, R. H. Herber, P. Zanello, D. S. Perekalin, I. V. Glukhov, M. Corsini, S. Fedi, F. Laschi, Eur. J. Inorg. Chem., 2007, 4190.
R. H. Herber, A. R. Kudinov, P. Zanello, I. Nowik, D. S. Perekalin, V. I. Meshcheryakov, K. A. Lyssenko, M. Corsini, S. Fedi, Eur. J. Inorg. Chem., 2006, 1786.
C. White, P. M. Maitlis, J. Chem. Soc., A, 1971, 3322.
D. A. Herebian, C. S. Schmidt, W. S. Sheldrick, C. van Wüllen, Eur. J. Inorg. Chem., 1998, 1991.
C. M. Alvarez, R. J. Angelici, A. Sygula, R. Sygula, P. W. Rabideau, Organometallics, 2003, 22, 624.
G. E. Herberich, B. Hessner, G. Huttner, L. Zsolnai, Angew. Chem., Int. Ed. Engl., 1981, 20, 472.
A. R. Kudinov, D. A. Loginov, Z. A. Starikova, P. V. Petrovskii, J. Organomet. Chem., 2002, 649, 136.
D. A. Loginov, D. V. Muratov, P. V. Petrovskii, Z. A. Starikova, M. Corsini, F. Laschi, F. de B. Fabrizi, P. Zanello, A. R. Kudinov, Eur. J. Inorg. Chem., 2005, 1737.
X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy, K. Nestor, M. Thornton-Pett, S. Hermanek, T. Jelinek, B. Stibr, J. Chem. Soc., Dalton Trans., 1990, 681.
D. S. Perekalin, K. A. Lyssenko, P. V. Petrovskii, J. Holub, B. Stibr, A. R. Kudinov, J. Organomet. Chem., 2005, 690, 2775.
A. R. Kudinov, V. I. Meshcheryakov, P. V. Petrovskii, M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim., 1999, 1817 [Russ. Chem. Bull. (Engl. Transl.), 1999, 48, 1794].
A. R. Kudinov, D. S. Perekalin, P. V. Petrovskii, Izv. Akad. Nauk, Ser. Khim., 2001, 1269 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1334].
A. R. Kudinov, D. S. Perekalin, P. V. Petrovskii, K. A. Lyssenko, G. V. Grintselev-Knyazev, Z. A. Starikova, J. Organomet. Chem., 2002, 657, 115.
O. V. Gusev, L. N. Morozova, T. A. Peganova, P. V. Petrovskii, N. A. Ustynyuk, P. M. Maitlis, J. Organomet. Chem., 1994, 472, 359.
M. Corsini, S. Losi, E. Grigiotti, F. Rossi, P. Zanello, A. R. Kudinov, D. A. Loginov, M. M. Vinogradov, Z. A. Starikova, J. Solid State Electrochem., 2007, 11, 1643.
A. R. Kudinov, V. S. Kaganovich, M. I. Rybinskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 2635 [Bull. Acad. Sci. USSRDiv. Chem. Sci. (Engl. Transl.), 1986, 35, 2418].
V. S. Kaganovich, A. R. Kudinov, M. I. Rybinskaya, Metalloorg. Khim., 1988, 1, 294 [Organomet. Chem. USSR, (Engl. Transl.), 1988, 1, 162].
D. A. Loginov, D. V. Muratov, Z. A. Starikova, P. V. Petrovskii, A. R. Kudinov, J. Organomet. Chem., 2006, 691, 3646.
D. A. Loginov, D. V. Muratov, A. R. Kudinov, Izv. Akad. Nauk, Ser. Khim., 2008, 1 [Russ. Chem. Bull., Int. Ed., 2008, 57, 1].
A. R. Kudinov, D. A. Loginov, Z. A. Starikova, P. V. Petrovskii, M. Corsini, P. Zanello, Eur. J. Inorg. Chem., 2002, 3018.
D. A. Loginov, M. M. Vinogradov, D. S. Perekalin, Z. A. Starikova, K. A. Lysenko, P. V. Petrovskii, A. R. Kudinov, Izv. Akad. Nauk, Ser. Khim., 2006, 81 [Russ. Chem. Bull., Int. Ed., 2006, 55, 84].
A. R. Kudinov, D. V. Muratov, M. I. Rybinskaya, P. V. Petrovskii, A. V. Mironov, T. V. Timofeeva, Yu. L. Slovokhotov, Yu. T. Struchkov, J. Organomet. Chem., 1991, 414, 97.
D. A. Loginov, M. M. Vinogradov, L. S. Shul’pina, A. V. Vologzhanina, P. V. Petrovskii, A. R. Kudinov, Izv. Akad. Nauk, Ser. Khim., 2007, 2046 [Russ. Chem. Bull., Int. Ed., 2007, 56, 2118].
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 586–589, March, 2009.
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Kudinov, A.R., Loginov, D.A. Cationic metallacarborane species [(Carb)M]+: generation and synthetic application. Russ Chem Bull 58, 600–603 (2009). https://doi.org/10.1007/s11172-009-0062-y
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DOI: https://doi.org/10.1007/s11172-009-0062-y