Abstract
Within the Mediterranean realm, the Rhodopes represent a nappe stack of oceanic and continental fragments assembled along the Eurasian continental margin during the Alpine orogeny. The timing of the high-pressure (HP) metamorphism has long been ambiguous, lacking detailed geochronological and geochemical control on subduction-exhumation and nappe stacking processes. Here we apply the Lu–Hf and Sm–Nd chronometers to a suite of representative eclogite samples covering two different key units of the Rhodopean nappe stack: (1) the Kimi Complex (Upper Allochthon) and (2) the Middle Allochthon. In addition to geochronology, we also determined whole rock Hf and Nd isotope compositions as well as major and trace element concentrations in order to constrain the nature of the eclogite protoliths. Two HP metamorphic events were revealed by Lu–Hf geochronology: (1) a Lower Cretaceous event in the Upper Allochthon (126.0 ± 1.7 Ma) and (2) an Eocene event in the Middle Allochthon (44.6 ± 0.7 Ma; 43.5 ± 0.4 Ma; 42.8 ± 0.5 Ma), at conditions of ca. 700°C/20–25 kbar. Our new data provide direct evidence for multiple subduction events in the Rhodopes. Exhumation and subsequent thrusting of the Middle Allochthon on the Lower Allochthon can be narrowed down to the time span between 42 and 34 Ma. In a broader tectonic context, the Eocene ages for the HP metamorphism support the view that the Rhodopes represent a large-scale tectonic window, exposing the deepest nappe units of the Hellenides.
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Introduction
The convergence between Africa and the Eurasian continent since the Jurassic led to the closure of the Tethyan realm in a protracted succession of subduction and collision events involving several microplates (Stampfli and Borel 2002; van Hinsbergen et al. 2005). In this context, rock units of both oceanic and continental affinity were subducted and metamorphosed at high-pressure (HP) and even ultra-high pressure (UHP) conditions (e.g., Gebauer et al. 1997; Mposkos and Kostopoulos 2001), and subsequently they were exhumed and incorporated into the evolving Alpine orogen. Constraining the exact timing of these events as well as characterization of the protoliths involved is crucial for reconstructing the geodynamic evolution of the Eastern Mediterranean realm. The Rhodopes, which are exposed in southern Bulgaria and northern Greece (Figs. 1, 2), are a key locality to understand the succession of HP events in the eastern Mediterranean as they represent the link between the Hellenic-Dinaric thrust belt and the Eurasian continental margin.
In the Rhodopes, evidence for the presence of deeply subducted oceanic and continental fragments reaching up to UHP conditions has been discovered in eclogites, metapelites and mélange-zone rocks (Mposkos and Kostopoulos 2001; Perraki et al. 2006; Cornelius 2008; Schmidt et al. 2010; Janák et al. 2011). However, only limited geochronological and geochemical data for the eclogite-facies rocks are available so far, and the results are inconsistent. Based on zircon dating, Liati (2005) postulated four episodes of HP to UHP metamorphism whereas Krenn et al. (2010) argue that UHP metamorphism was confined to ca. 180 Ma, followed by decompression.
In the last two decades, direct dating of HP metamorphic events in Alpine or older metamorphic rocks has been improved by the application of the Lu–Hf (and Sm–Nd) geochronometers to metamorphic garnet (e.g., Vance and O’Nions 1990; Duchêne et al. 1997; Amato et al. 1999; Scherer et al. 1997, 2000; Blichert-Toft and Frei 2001; Thöni 2002; Lapen et al. 2003; Lagos et al. 2007; Herwartz et al. 2008, 2011; Smit et al. 2010). The major advantages of this approach are (1) high Lu/Hf (and Sm/Nd) ratios in garnet, (2) the additional information from initial Hf–Nd isotope compositions about the nature of the protolith and (3) the fact that garnet ages can be tied to specific P–T conditions. New analytical approaches (e.g., Lagos et al. 2007) also allow the selective digestion of garnet, thus minimizing the effects of inclusions that are in isotopic disequilibrium with the host garnet.
In this study, we present Lu–Hf and Sm–Nd isotope data for whole rocks and omphacite/garnet mineral separates for four eclogite samples from two different tectonic units of the Bulgarian Rhodopes. These data are complemented by element profiles of garnet obtained by LA-ICP-MS and electron microprobe, whole rock major and trace element analyses and are furthermore combined with petrological observations and phase diagram calculations. The results lead to a fundamental tectonic re-interpretation of the Rhodopes as the most internal portion of the Hellenides rather than an independent older orogen.
Geological overview
The Rhodopes are tectonically sandwiched between the Hellenic-Dinaric thrust belt in the south-west and the Eurasian continental margin, including the Balkanides, to the north (Fig. 1). To the south, the Rhodopes extend into Greece and are partially covered by the Aegean Sea. The present study focuses on the Bulgarian part of the Rhodopes, which is built of several metamorphic thrust units that were re-structured by intense extension in the Eocene and Miocene (e.g., Burg et al. 1996; Kilias et al. 1999; Krohe and Mposkos 2002; Bonev et al. 2006; Pleuger et al. 2011). The extensive nomenclature for individual, local units so far lacks a consistent classification scheme. Here, we follow the approach of Janák et al. (2011), referring to four large superunits: the Lower, Middle, Upper and Uppermost Allochthon (Figs. 1, 2). The nomenclature introduced by Janák et al. (2011) also allows a direct tectonic correlation between the Rhodopes in the strict sense and the Serbo-Macedonian Massif further south-west. A short description of the respective units along with the most important available geochronological data is given in Table 1.
The Lower Allochthon is exposed south of the Nestos Shear Zone (“Rhodope Metamorphic Core Complex” or “Pangaion–Pirin Complex”; Dinter and Royden 1993; Dinter 1998; Georgiev et al. 2010; Jahn-Awe et al. 2010) as well as in three metamorphic core complexes (Arda–Byala Reka/Kechros–Kesebir/Kardamos) that form extensive domes in the eastern part of the Rhodopes (Figs. 1, 2). The Lower Allochthon is composed of Variscan basement (e.g., Wawrzenitz and Mposkos 1997; Peytcheva et al. 2004; Ovtcharova et al. 2004; Turpaud and Reischmann 2010) and a metasedimentary sequence, reaching greenschist- to amphibolite-facies metamorphism in the Pangaion–Pirin complex and migmatization in the Arda, Byala Reka/Kechros and Kesebir/Kardamos complexes. Migmatization in the Arda dome took place at 37.8 ± 1.5 Ma (Cherneva et al. 2002).
The Middle Allochthon corresponds to the Sidironero-Mesta Unit in the broad sense and includes the Madan, Arda 2, Starcevo, Borovica and Asenica Units in the Central Rhodopes (Table 1; Figs. 1, 2). The Middle Allochthon is equivalent to the “Rhodope Terrane” of Turpaud and Reischmann (2010) and Jahn-Awe et al. (2010) and is a mixed unit of continental and oceanic affinity, including orthogneisses derived from Jurassic to Early Cretaceous arc granitoids, and intruded by Eocene granitoids (U–Pb on zircons; Ovtcharova et al. 2004; Turpaud and Reischmann 2010; Jahn-Awe et al. 2010). The metamorphic grade reached up to eclogite facies (e.g., Kolčeva et al. 1986; Liati and Mposkos 1990; Liati and Seidel 1996). Furthermore, mineral relics and mineral compositions indicating UHP metamorphic conditions have been reported from several different localities from the base of the Middle Allochthon (microdiamond inclusions in garnet of metapelites; Mposkos and Kostopoulos 2001; Perraki et al. 2006; Schmidt et al. 2010). The timing for thrusting of the Middle on the Lower Allochthon along the top-to-the-south-west Nestos Shear Zone was recently confined by Jahn-Awe et al. (2010) to 55–32 Ma. An Eocene activity of the Nestos Shear Zone is also constrained by ca. 42–38-Ma-old pegmatite veins affected by mylonitization along the Nestos Shear Zone (Liati 2005; Bosse et al. 2009).
The Upper Allochthon is composed of the Kardžali Unit and the Kimi Complex in the Eastern Rhodopes and the Vertiskos/Ograzhden Unit in the Serbo-Macedonian Massif, which is regarded as the western continuation of the Rhodopes (Table 1; Figs. 1, 2; Burg et al. 1996; Ricou et al. 1998; Himmerkus et al. 2009a, b). The Upper Allochthon is a composite unit made up of metapelites, gneisses, amphibolites, marbles and boudins of eclogites and ultramafic rocks. The latter have previously been interpreted as melting residues and cumulates emplaced at the base of a thickened crust (Baziotis et al. 2008). A metamorphic grade of eclogite facies up to UHP conditions has been documented for the Kimi Complex (Mposkos and Kostopoulos 2001). Recently, microdiamond inclusions in zircons were also reported from the mélange zone at the base of the Upper Allochthon by Cornelius (2008). So far, the timing of UHP metamorphism in the Upper Allochthon could only be constrained between 200 and 41 Ma and is still a matter of debate for the Kimi Complex. Most recently an Early Jurassic age (~180 Ma) was suggested by Krenn et al. (2010).
The Uppermost Allochthon consists of the Circum-Rhodope Belt as well as the Mandrica and Alexandropolis greenschists. These units consist of low-grade metamorphic sedimentary and volcanic rocks, partly of oceanic affinity and were thrust northwards over the Eurasian margin in the Late Jurassic to Early Cretaceous (Bonev and Stampfli 2003).
Sample localities
Three eclogite samples (Rh-83, Rh-89 and Rh-197) were taken from key localities in the Middle Allochthon and one sample (Rh-210) from the Upper Allochthon (GPS coordinates see Table 2). Rh-83 and Rh-197 were sampled near to each other, within the same sub-unit (Starcevo Unit of the Middle Allochthon; see Fig. 2).
Sample Rh-83 is of particular importance, in that it is a sapphirine-bearing kyanite eclogite. It has been collected in a small creek bed ~300 m north-east of the town of Ardino, located at the top of the Ardino Mélange (Fig. 2). This mélange forms the basal part of the Starcevo Unit (Middle Allochthon) and is characterized by ortho- and para-gneisses, marbles, amphibolites and minor ultramafic rocks and eclogites. On top of the mélange towards east follow mixed gneisses of the Starcevo Unit proper. As sample Rh-83 was part of a stream boulder, it is not clear whether its original tectonic position was in the uppermost part of the mélange or upstream in the hanging-wall of the mélange within the mixed gneisses of the Starcevo Unit that also contain eclogites.
Eclogite Rh-197 has been collected ~700 m to the north-east of Sransko village (south-west of Ardino; Fig. 2). It originates from lenses of amphibolite and eclogite enclosed in migmatitic gneisses of the Starcevo Unit.
Eclogite sample Rh-89 originates from the so-called Čepelare Shear Zone (Fig. 2; Burg et al. 1990; Bosse et al. 2009; Gerdjikov et al. 2010), a mixed zone at the base of the Arda 2 Unit (Middle Allochthon). The sample has been collected ~1 km south-east of Beden village. At this locality, fine-grained eclogites and surrounding garnet-amphibolites form a 25-m-long and 10-m-thick boudin embedded in gneiss.
Eclogite sample Rh-210 originates from the Kardžali Unit, which is part of the Upper Allochthon (see Table 1). The sample has been collected ~3 km WNW of Drangovo village (Fig. 2). The sample originates from an eclogite boudin hosted by garnet-micaschists. More eclogite outcrops can be found towards north-north-east and south-south-west in a thin band on top of a west-north-west-dipping extensional shear zone.
Analytical techniques
Sample preparation, separation and digestion
Four eclogite samples (Rh-83, Rh-89, Rh-197 and Rh-210) were analysed for their whole rock major and trace element concentrations as well as for Lu–Hf and Sm–Nd isotope compositions. The results along with GPS coordinates of sample localities are listed in Tables 2 and 3.
After removing the weathering crusts with a rock saw, the samples (total weight ca. 2–3 kg) were crushed in a steel mortar. A representative aliquot was then ground in an agate mill and the powder was subsequently used for bulk rock analyses. For trace element analyses, the sample powder was digested in a 1:1 mixture of HNO3-HF in Parr bombs for 3 days to ensure complete sample digestion and was subsequently dried down with one mL of perchloric acid. A second aliquot of the crushed sample was sieved, and the fractions >63 μm were purified with a Frantz magnet separator. In order to prevent a selective separation of either garnet rim or core, the settings were adjusted to remove non-magnetic minerals only. Subsequently, three to five garnet separates per sample were hand-picked under a binocular lens. Both visibly inclusion-free and inclusion-bearing garnet fractions were separated in order to avoid biasing the results towards either garnet rims or cores. For sample Rh-210, an additional omphacite fraction was separated. Nine to 120 mg of mineral fractions were used for Lu–Hf and Sm–Nd measurements (see Table 3). Prior to digestion, the whole rock powders and mineral separates were spiked with mixed 176Lu-180Hf and 149Sm-150Nd tracers. The digestion procedures employed for whole rocks (bomb digestion) and mineral separates (tabletop digestion) were described in detail by Lagos et al. (2007) and Herwartz et al. (2008). The Lu–Hf separation as well as an additional clean-up step for the Hf fraction was carried out using the method of Münker et al. (2001). Samarium-Nd separation was carried out using the REE-rich matrix cut left over from the Hf separation, using BioRad® AG50W-X8 cation resin (200–400 mesh) and Eichrom Ln-spec resin (Pin and Zalduegui 1997). Procedural blanks were less than 50 pg for both Hf and Nd.
Measurements
Major element whole rock analyses were carried out using a PANalytical ProTrace XRF at Universität Bonn, Germany. The whole rock trace element contents were determined by quadrupole ICPMS using an Agilent 7500cs mass spectrometer at Universität Kiel, Germany. Analytical procedures followed those of Garbe-Schönberg (1993). Lutetium, Hf, Sm and Nd were measured using the Thermo-Finnigan Neptune MC-ICP-MS at the Steinmann-Institut Bonn, operated in static mode. Values of 143Nd/144Nd and 176Hf/177Hf were corrected for mass fractionation using the exponential law and 146Nd/144Nd = 0.7219 and 179Hf/177Hf = 0.7325, respectively. Measured 143Nd/144Nd and 176Hf/177Hf values of the samples are reported relative to 143Nd/144Nd = 0.511859 for the La Jolla Nd standard (measured value = 0.511836 ± 47 (2SE); n = 2) and 176Hf/177Hf = 0.282160 for the Münster Ames Hf standard (measured value = 0.282161 ± 44 (2SE); n = 27) that is isotopically identical to the JMC-475 standard.
Several garnet grains were also analysed in situ by laser ablation mass spectrometry along line profiles (Fig. 5), in order to measure their Mn and Lu abundances. Laser ablation of these garnet grains was carried out using a Resonetics M50-E ATL Excimer 193 nm laser system coupled to a Thermo-Finnigan X-series 2 quadrupole ICP-MS (Steinmann-Institut Bonn). Spot sizes were set between 33 and 75 μm depending on the size of the garnets analysed, as well as the amount of mineral inclusions found in the cores of the individual grains. Laser fluence at the sample surface was measured at 7 J/cm−2, and the laser repetition rate was set to 15 Hz. Count rates were normalized using 29Si as the internal standard and one external standard (NIST-610 glass, Pearce et al. 1997). The isotopes 29Si, 43Ca, 57Fe, 55Mn and 175Lu were monitored. Data reduction and evaluation were carried out following the procedure laid out by Longerich et al. (1996). Electron microprobe BSE images of the garnets before and after LA-ICP-MS analyses are enclosed in the Electronic Supplementary Material.
Mineral major element abundances were analysed by spot analysis using a JEOL superprobe JXA-8900 microprobe (Universität zu Köln) and a JEOL superprobe JXA-8200 microprobe (Steinmann-Institut Bonn) in wavelength dispersive mode (WDS) employing 15 kV acceleration voltage and 15 nA beam current. Calibrations for Mg, Al, Si, Ti, Ca, Fe, Na, K, Cr and Mn were carried out on andradite, rutile, basaltic glass (VG2–USNM 111240/52), and Jadeite-Diopside synthetic glass. In addition, high-resolution X-ray maps were made for selected garnet grains of all four samples, in order to identify and characterize their zonations with respect to Ca, Fe, Mg and Mn (see Figs. 4, 5). X-ray maps were performed using a JEOL superprobe JXA-8200 microprobe (Steinmann-Institut Bonn), with 15 kV acceleration voltage and 100 nA beam current over 24 h.
Petrography and equilibrium phase diagrams
Mineral compositions of garnet, omphacite, amphibole, phengite, plagioclase and sapphirine were analysed by electron microprobe, the results of which are listed in Tables 4 and 5. Using these data, we calculated equilibrium assemblage diagrams (Fig. 3) for the samples Rh-83, Rh-89 and Rh-210 using the whole rock compositions obtained by XRF (Table 2), the Domino-Theriak program package (de Capitani and Petrakakis 2010) and a modified JUN92 database (Berman 1988; upgrade 1992). The database was modified with non-ideal solid solution models for garnet (Berman 1990), phengite (Massonne and Szpurka 1997), and feldspar (Fuhrman and Lindsley 1988) and ideal approximations for clinopyroxene (endmembers: diopside-hedenbergite-jadeite), clinoamphibole (tremolite, pargasite, Fe-pargasite, glaucophane, tschermakite), spinel (spinel-hercynite), biotite (phlogopite-annite-Mn-biotite), chlorite (chlinochlore-daphnite-Mn-chlorite) and sapphirine. For sapphirine, we chose Mg-sapphirine Mg3.5AL9Si1.5O20 and Fe-sapphirine Fe3.5AL9Si1.5O20 as end-members, as these are compositionally close to the sapphirine observed in sample Rh-83. ΔfH0 and S0 of the sapphirine and daphnite end-members were adopted from Holland and Powell (1998) and slightly adjusted so that the internal consistency of the database was maintained. The equilibrium assemblage diagrams were calculated for water-saturated Si–Al-Ti–Fe–Mn–Mg-Ca–Na–K bulk rock compositions (see Table 2). In order to constrain the retrograde P–T path, we also calculated one diagram in a Si–Al-Ti–Fe–Mn–Mg-Ca–Na–K system for a retrograde corona forming around decomposing kyanite (sample Rh-83). The composition was estimated from the proportions and compositions of the minerals constituting the coronae (see Table 5).
Sample Rh-83 from the Middle Allochthon (Starcevo Unit) is a sapphirine-bearing kyanite eclogite, from the same unit as and similar to those described by Kolčeva et al. (1986) and Liati and Seidel (1996). It contains the high-pressure assemblage garnet-omphacite1 (Jd37–43)-kyanite-quartz-rutile-zoisite-apatite, corresponding to 600-830°C/19–27.5 kbar in the equilibrium assemblage diagram (Fig. 3a). Phengite was not observed, probably because it was completely consumed during retrograde growth of amphibole and biotite. Most of the omphacite was replaced during several stages of retrograde overprint, starting with the growth of pargasitic amphibole (mostly around garnet) and omphacite2 (Jd17–26)-plagioclase symplectites (mostly at the expense of omphacite1) that show ambiguous textural relations with the pargasitic hornblende. Symplectites of plagioclase (Ab29–57An41–69), spinel and sometimes rutile, sapphirine and/or corundum formed around decomposing kyanite (see BSE images in the Electronic Supplementary Material). Biotite is locally pseudomorphic after amphibole and together with plagioclase forms patches after the sapphirine-bearing symplectite coronae. Garnets in Rh-83 are several millimetre large, corroded grains that display a complex chemical zonation (Fig. 4a). A wide rim domain displays patches enriched in Fe and Ca and depleted in Mg. The inclusion-rich core has a composition similar to the outermost rim with respect to Fe, Mg and Ca, but shows a higher Mn content than the rest of the grain. This Mn-rich domain preserves an edgy euhedral shape in some garnet grains (Fig. 4a) and a more diffuse shape in others (Fig. 5a). We interpret this compositional pattern to result from partial resetting (resorption) of the garnet rims that also result in an increase in abundance of trace elements like Lu in the resorbed rims (Fig. 5a and discussion below).
Based on chemical and textural evidence, we propose that the growth of the plagioclase-spinel-sapphirine symplectites around kyanite was controlled by local chemical equilibria. Therefore, we used a composition estimated as described above (Table 5) as input for the calculation of the equilibrium assemblage diagram (Fig. 3b). For a dry composition, the observed assemblage plagioclase-spinel-sapphirine-corundum-rutile is predicted to be stable in the grey-shaded field of Fig. 3b, that is, above 610°C. Adding excess water to the same composition leads to a shift of the plagioclase-spinel-sapphirine-corundum-rutile stability field to higher temperatures, that is, above 670°C. The maximum pressure is constrained by the boundary of the plagioclase-spinel-sapphirine-corundum-rutile stability field towards garnet stability and increases from c. 8 kbar at 710°C to c. 12.5 kbar at 900°C. It is therefore realistic to assume that the sapphirine-bearing coronae formed at temperatures around or even below 700°C, that is, roughly at the same temperatures where the orthogneissic country rocks underwent migmatization (Georgieva et al. 2002). Likewise, if calculated for a broader compositional range, the absence of garnet from the observed assemblage requires pressures significantly below those of a high-pressure granulite-facies overprint above 12 kbar, which was previously postulated by various authors (Liati and Seidel 1996, Carrigan et al. 2002).
The matrix assemblage of sample Rh-197 (Starcevo Unit) is much more strongly affected by retrogression than documented for sample Rh-83. However, large garnet porphyroblasts are much better preserved, are euhedral and clearly exhibit growth zonation (Figs. 4c, 5c). Manganese, Ca and the Fe to (Fe+Mg) ratio show the classic bell-shaped distribution. Zonations of Fe and particularly Mn are edgy, discontinuous and parallel to the grain boundaries. Nevertheless, garnets in Rh-197 also display thin channels, along which transport and some re-equilibration might have occurred (Fig. 4c). However, Lu element profiles (Fig. 5c) strongly indicate that garnets in Rh-197 preserve their original trace element zonation displayed by the high Lu concentration in the core and decreasing concentrations towards the rims (see also discussion below). Clinopyroxene (Di62–79Hd6–23Acm5–15Jd1–4) is abundant in symplectites with plagioclase. Pargasitic amphibole grew along the rims of garnet and within the matrix. Rh-197 also contains Al-rich symplectite patches comprising plagioclase (Ab46–57An43–53), kyanite, amphibole, spinel, ilmenite and sometimes corundum (see BSE images in the Electronic Supplementary Material). Unlike in Rh-83, we did not observe specific mineral relicts within the symplectite patches.
Sample Rh-89 contains the high-pressure assemblage garnet-omphacite (Jd27–35)-quartz-phengite-rutile, corresponding to the grey-shaded stability field in the phase diagram (Fig. 3c). Garnets occur as slightly corroded, euhedral grains and are much smaller than in the two previous samples (Figs. 4b, 5b). They show distinct Ca-poor and Fe- and Mg-rich rims. The Fe to (Fe+Mg) ratio is slightly elevated in the core. However, the distribution of Mn is flat (Figs. 4b, 5b) and indicates resorption of garnet. Altogether, the chemical zoning, at least of Fe, Mg and Mn, appears to be strongly reset in sample Rh-89, which is also documented by the enrichment of Lu in the rim domains (Fig. 5b). Metamorphic retrogression caused growth of pargasitic amphibole, plagioclase-clinopyroxene (Di70–83Hd0–18Acm0–12Jd8–12) symplectites and biotite together with plagioclase. Al-rich symplectites as in Rh-83 and Rh-197 were not observed in Rh-89.
The overlapping stability fields of the high-pressure assemblages in samples Rh-83 and Rh-89 and the Al-rich symplectites in both Rh-83 and Rh-197 allow to roughly constrain a pressure–temperature path for the exhumation of the lower part of the Middle Allochthon (Fig. 3d).
The observed high-pressure assemblage in Rh-210 is garnet-omphacite (Jd32–41)-amphibole-phengite-rutile. Mica is scarce (<1%) due to the low potassium content of the sample (0.02 wt%). Garnets are again large (>2 mm) and show original growth zonation with humps of Ca, Mn and the Fe to (Fe+Mg) ratio (Fig. 4d) and Lu (Fig. 5c) in the core. In the equilibrium assemblage diagram (Fig. 3e), this assemblage is predicted to be stable under somewhat lower pressures (15–19 kbar) than those estimated from the high-pressure assemblages of the samples from the Middle Allochthon (20–25 kbar). Sample Rh-210 exhibits little evidence of retrogression other than the growth of chlorite along isolated cracks.
Geochemical results
Major and trace elements
The major and trace element concentrations of all four eclogite samples are given in Table 2. The four analysed samples yield basaltic whole rock compositions (SiO2 = 45.8–51.1 wt. %; MgO = 6.71–8.32 wt. %; Al2O3 = 14.0–17.0 wt. %), with both high Zr (113–200 ppm) and compatible element contents (e.g., Cr = 182–320 ppm; Ni = 54.2–142 ppm).
With the exception of sample Rh-210, all samples are LREE-enriched (LaN/YbN = 1.4, 2.0, 4.5 for Rh-83, Rh-89 and Rh-197, respectively), but exhibit similar magnitudes of HREE abundances as N-MORB (Fig. 6a). Sample Rh-210 from the Upper Allochthon is characterized by a strong LREE depletion and a slight enrichment of the HREE with respect to N-MORB (LaN/YbN = 0.13). In the primitive mantle-normalized trace element diagram (Fig. 6b), sample Rh-210 is depleted in Th and La, Ce and Nd and displays positive anomalies of high field strength elements (HFSE) like Nb, Ta, Zr and Hf. In contrast, sample Rh-197 displays a striking negative Nb–Ta anomaly and Th-U enrichment. Samples Rh-83 and Rh-89 are enriched with respect to N-MORB (Fig. 6b), especially with regard to U and Th. All four samples display similar Nb/Ta ranging from 13.4 to 15.3 at high Zr/Hf (37.9–44.5), broadly overlapping the range of values found in MORBs and island-arc basalts (Büchl et al. 2002; Münker et al. 2004).
Lu–Hf and Sm–Nd geochronology
We analysed the four eclogite samples for their Lu–Hf and Sm–Nd isotope compositions, using one whole rock aliquot as well as three to five mineral separates per sample (garnets and pyroxenes).
The results of the Lu–Hf and Sm–Nd measurements are given in Table 3 and are illustrated in Fig. 7. Isochron regressions were calculated using ISOPLOT v.2.49 (Ludwig 2001) and λ 176Lu = 1.867 × 10−11 year−1 (Scherer et al. 2001; Söderlund et al. 2004). The external reproducibilities of the isochron calculations were estimated by the empirical relationship 2σ external reproducibility ≈ 4σm (σm = standard error of a single analysis; Bizzarro et al. 2003).
The Hf contents of the whole rock samples range from 2.92 to 4.78 ppm and those of the garnets from 60 to 150 ppb. The 176Lu/177Hf of the garnets range from 1.60 to 3.78 and the pyroxenes from sample Rh-210 display a 176Lu/177Hf of 0.00124. For each sample, mineral separates and whole rock aliquots define statistically significant isochrons (MSWDs of 0.1–0.7; Fig. 7), also suggesting full sample-spike equilibrium during tabletop digestion. The Lu–Hf ages of the samples from the Middle Allochthon are 44.6 ± 0.7 Ma for Rh-83 (n = 6), 43.5 ± 0.4 Ma for Rh-89 (n = 4) and 42.8 ± 0.5 Ma for Rh-197 (n = 5). The sample from the Upper Allochthon (Rh-210) yields a Lu–Hf age of 126.0 ± 0.7 Ma (n = 6).
The Nd contents of the whole rock samples range from 4.28 to 20.1 ppm with 147Sm/144Nd of 0.14–0.37. The garnet (Gt-4) and the pyroxene (Px-1) fractions of sample Rh-210 display Nd concentrations of 1.96 and 1.67 ppm with 147Sm/144Nd of 0.726 and 0.440, respectively. The Sm–Nd age determined for sample Rh-210 is 109 ± 11 Ma (n = 3). Samarium-Nd garnet analyses of the other three samples were hampered by the presence of inclusions with low Sm/Nd in garnet.
Discussion
Significance of the Lu–Hf geochronological results
In order to adequately interpret the age information from the analysed garnet populations, several important issues have to be addressed first. Two major points addressed here in detail are the representative sampling of garnet as well as protracted metamorphism and garnet growth.
Representative sampling of bulk garnet and the problem of inclusions
The mineral separation technique employed in this study allows to test for any possible bias in the analysed garnet separates. Pure garnet fractions (without visible inclusions; Gt-1, Gt-4, Gt-5 of each sample) as well as garnet fractions with a high density of inclusions were separated (Gt-2, Gt-3; see also Figs. 4 and 5, garnet major element distribution maps) and used for the Lu–Hf/Sm–Nd geochronological study. As illustrated in Fig. 7, all garnet separates define isochrons with considerably low MSWDs (<1.7).
Furthermore, inclusions in garnet may significantly compromise the measured Hf isotope composition (e.g., Scherer et al. 2000). This issue is readily avoided by the employed tabletop digestion technique, which prevents the dissolution of Hf-rich phases like rutile or zircon (e.g., Scherer et al. 2000; Lagos et al. 2007). In contrast to the Lu–Hf isotope system, the Sm–Nd system is very sensitive to inclusions of apatite and monazite (Scherer et al. 2000) that are abundant as inclusions in garnet in samples Rh-83, Rh-89 and Rh-197, lowering the 147Sm/144Nd of the garnet separates. Hence, no meaningful Sm–Nd age could be determined for the samples from the Middle Allochthon.
Constraints on protracted metamorphism and garnet growth
The good fit of all isochrons (MSWDs ≤ 1.7) strongly suggests that the Lu–Hf isotope system was not disturbed at a later stage, that is, that garnets and whole rocks remained closed systems after formation. This is especially interesting for sample Rh-210 from the Upper Allochthon, which yields a Lu–Hf age of 126 ± 0.7 Ma. Based on U–Pb geochronology on zircons, Bauer et al. (2007) and Liati et al. (2002) infer a metamorphic event at ca. 74–77 Ma for the Kimi Complex, which supposedly reached amphibolite-facies conditions (Bauer et al. 2007) or even eclogite- to UHP metamorphic conditions (Liati et al. 2002). Considering the results of the Lu–Hf and Sm–Nd geochronology of sample Rh-210 as well as similar results by Wawrzenitz and Mposkos (1997; 117 ± 3.5 Ma; Sm–Nd of gt-cpx-whole rock of a garnet-pyroxenite), it appears rather unlikely that a high-grade (eclogite- or UHP) post-Barremian metamorphic event affected sample Rh-210. To a certain degree, similar conclusions can be drawn with regard to older metamorphic events affecting the rocks from the Middle Allochthon as suggested from U–Pb zircon geochronology (~148 Ma, for the Nestos Shear Zone; Liati 2005; Krenn et al. 2010). If garnet relicts from this Late Jurassic high-grade event had been preserved in the studied eclogite samples, then a mixture of old (radiogenic 176Hf/177Hf; = garnet cores) and young (unradiogenic 176Hf/177Hf; = garnet rims) garnet domains would be expected. Such observations have recently been made by Herwartz et al. (2011) for the Adula Nappe in the Central Alps.
Consequently, the Lu–Hf isochrons defined by the studied Rhodopean eclogites argue either (1) for a pervasive nature of both the Eocene and Cretaceous HP events in the Starcevo Unit and the Kardžali Unit, respectively or (2) for the absence of relictic garnet associated with previous metamorphic events in the respective unit. Moreover, the low MSWDs and the generally good fit between three (Rh-83, Rh-89 and Rh-197) of the four Lu–Hf isochrons provide strong evidence for a relatively short duration of garnet growth during the Eocene metamorphic cycle. This is also in line with the phase diagrams (Fig. 3) that predict garnet growth over a relatively small P–T interval just before reaching peak pressure conditions, that is, only above 500°C. If garnet grew over a period of several tens of Myr, the data points would show a higher scatter, that is., a higher MSWD (e.g., Kohn 2009).
Prograde growth ages versus cooling ages
During the nucleation and subsequent growth of garnets along a prograde P–T path, minerals such as garnet develop a growth zonation, which can be approximated by a Rayleigh process (or fractional crystallization and thermodynamic equilibrium; after Kohn 2003). Of fundamental interest here is the preservation of undisturbed distribution patterns for Lu–Hf (and Sm–Nd) in the garnets. Especially during the thermal peak of metamorphism diffusion of these elements would get enhanced. These effects may reset the Lu–Hf and Sm–Nd isotope systems, and the ages defined by the isochrons may then reflect cooling ages. Element diffusivity in garnet depends on a variety of other factors in addition to temperature, for example, grain size, peak temperature, garnet composition, matrix composition, oxygen fugacity (f2), duration of prograde metamorphism, cooling rate and ionic charge (e.g., Chakraborty and Rubie 1996; Ganguly et al. 1998; van Orman et al. 2002; Skora et al. 2006, Caddick et al. 2010). A useful proxy to assess the effects of diffusion is the major element zonation found in garnets (Figs. 4, 5). As shown by experimental studies (e.g., van Orman et al. 2002), the ionic charge of an element exerts a major control on its diffusivity, where 2+ ions diffuse by orders of magnitude faster than 3+ (e.g., Lu), and presumably 4+ ions (e.g., Hf). Furthermore, it appears that the Lu–Hf system is more resistant to diffusion compared to the Sm–Nd system, as relatively higher closure temperatures have been proposed for Lu–Hf (e.g., Scherer et al. 2000; Lapen et al. 2003).
The bell-shaped distributions of Mn, Ca and Fe/(Fe+Mg) in garnet in combination with elevated Lu concentrations in the garnet cores as it is shown for samples Rh-197 (Figs. 4c, 5c) and Rh-210 (Figs. 4d, 5d) can therefore be readily regarded as evidence for the preservation of the prograde growth zonation patterns for Lu–Hf. In these two cases, the Lu–Hf ages clearly reflect the time of garnet growth (e.g., Lapen et al. 2003). Based on mass balance arguments, however, Skora et al. (2009) pointed, furthermore, out that the Lu–Hf ages reflect peak metamorphic conditions due to volumetrically higher abundance of garnet rims relative to garnet cores.
The large garnets in sample Rh-83 show a certain degree of garnet rim resorption (~30% of the garnet radius). However, the very cores still show elevated Mn (and to a certain degree also Lu) contents. Considering the near-identical Lu–Hf age of Rh-83 (44.6 ± 0.7 Ma) with that of Rh-197 (42.8 ± 0.5 Ma), it is evident that resorption of the garnet rims is geochronologically barely resolvable and must have occurred at near-peak metamorphic conditions. Otherwise, the Lu that diffused back into the garnet rims would have compromised the fit of the Lu–Hf isochron and biased the isochron towards an apparently younger age (see Kelly et al. 2011).
The more or less homogeneous major element composition of the small garnets in sample Rh-89 (Figs. 4b, 5b) probably results from diffusive reequilibration of formerly prograde zoned garnets. However, this feature may not necessarily indicate a concurrent diffusive mobilization of REEs, in line with findings by Dutch and Hand (2010), who reported garnets with flat equilibrated major element zonations but preserved primary REE zonations. Major element distribution maps shown in Figs. 4b and 5b in combination with the Lu concentration data obtained by LA-ICP-MS (Fig. 5b), however, also suggest the diffusion of Lu and resorption of large parts of the garnets. Considering the small garnet diameters of Rh-89 (less than 600 μm) compared to Rh-83 (2–3 mm), garnets in Rh-89 might have been more susceptible to complete resorption and equilibration than the larger garnets in Rh-83. Furthermore, as all three eclogites from the Middle Allochthon (Rh-83, Rh-89 and Rh-197) display virtually identical Lu–Hf ages, it seems likely that the same near-peak metamorphism affecting sample Rh-83 also affected sample Rh-89.
Collectively, the Lu–Hf age of Rh-197 can be interpreted as closest representing the age of the peak metamorphic event affecting the Middle Allochthon. Samples Rh-83 and Rh-89 were affected by different degrees of garnet resorption close to the timing of the metamorphic peak. The Lu–Hf age in sample Rh-210 furthermore can be readily regarded as representative of the age of HP metamorphism in the Kardžali Unit. As mentioned above, the Sm–Nd isotope system of sample Rh-210 has been affected by element mobility during the metamorphic cycle. Therefore, we interpret the Sm–Nd age of 109 ± 11 Ma as only representing a minimum age for garnet growth.
Constraints on exhumation rates
Considering the Lu–Hf results discussed above, we can now place a robust age constraint on the P–T path of the investigated samples, in particular on the prograde flank towards peak pressure conditions (Fig. 3). Combining these results with published stratigraphic and geochronological data from the retrograde path allows to roughly estimate the orders of magnitudes of the cooling and exhumation rates. For the timing of prograde metamorphism, we use the Lu–Hf age of sample Rh-197 (42.8 ± 0.5 Ma), as it represents the youngest garnet growth age and we therefore place minimum constraints on the exhumation rate. The depth of formation inferred from phase relationships corresponds to ca. 70 km. From Ar–Ar geochronology carried out on rocks from nearby units of the Middle Allochthon, the timing of cooling below 380–320°C is constrained by ages of 37.1 ± 2.4, and 36.1 ± 0.4 Ma (Lips et al. 2000), which might be considered as minimum ages due to a relatively low blocking temperature applied by the authors (350 ± 30°C). Following Liati and Gebauer (1999), we assume a mean depth of c. 10 km for this phase of retrograde cooling. Complete exhumation of the Middle Allochthon to the surface is robustly constrained by unmetamorphosed marine sediments of Priabonian age that are unconformably resting on top of the Starcevo Unit north-east of Ardino (Yordanov et al. 2007). Hence, vertical exhumation from 70 km depth had to be accomplished within less than 8 Myr and exhumation rates are therefore around 1 cm/year, similar to values estimated for the exhumation of the Arda 1 and Starcevo Unit by Pleuger et al. (2011). This is clearly a minimum rate because the maximum subduction depths were probably reached somewhat later than the determined Lu–Hf age (<42.8 ± 0.5 Ma). Moreover, exhumation and cooling in the study area may have occurred successively, the lithologies may have been exhumed isothermally first and then cooled (Fig. 3). Collectively, the actual exhumation may probably have occurred much faster, even before cooling started. Independent of this uncertainty, our results suggest higher exhumation rates than those proposed by Liati and Gebauer (1999), in the order of 5.7–11.8 mm/year (mean of 7.7 mm/year); nevertheless, the order of magnitude is similar between both studies.
Constraints on the magmatic protolith
In developing a palaeotectonic model for the Rhodopes, it is essential to constrain the nature of the eclogite protoliths, that is, the tectonic environment in which the eclogite precursors formed. Of importance for the present study is the distinction between a divergent (MORB), a convergent (island-/continental- or back-arc), and an intra-plate setting (e.g., OIB). In this regard, the whole rock trace element budget as well as the Hf–Nd isotope compositions serve as a valuable tool to identify the original composition of the magmatic precursor (e.g., Becker et al. 2000; John et al. 2004; Zack and John 2007; Zhao et al. 2007).
The mobility/immobility of trace elements during blueschist to eclogite transition has been the subject of extensive research over the past years where, for example, it has been shown that many trace elements are easily mobilized from the slab to the overlying mantle wedge during dehydration reactions (e.g., John et al. 2004, 2008; Zack and John 2007; Beinlich et al. 2010). However, these processes are likely limited to zones with a high fluid flux (veins, channels and other fluid pathways). Other authors proposed a decoupling of fluid and trace element flux during subduction, that is, only very limited amounts of trace elements are released from the subducting slab during prograde metamorphism (Spandler et al. 2003; 2004; 2007). Considering these interpretations, the bulk trace element patterns of the studied eclogite samples (Fig. 6a, b) may mirror element-loss of a more LREE-enriched precursor, like arc-related basalts or even OIBs, or may be considered as representative of the original magmatic protolith composition.
Sample Rh-210 from the Upper Allochthon appears to be affected by a selective loss of LILE (Cs, Rb, Ba) and LREE (La, Ce, Pr, Nd), leaving behind positive anomalies of the HFSE and HREE (see Fig. 6a, b). Evidence for either a dehydration- or partial melt-mediated dissipation of Nd and Hf in sample Rh-210 is provided by increased 147Sm/144Nd (0.3664) and 176Lu/177Hf (0.03468) when compared to the other three samples (see Fig. 8a). This feature has also major implications for the interpretation of the Sm–Nd age determined for Rh-210 (see below). In any case, the consistently low 147Sm/144Nd and 176Lu/177Hf of the samples Rh-83, Rh-89 and Rh-197 might provide some evidence that these samples preserved their original magmatic REE and HFSE compositions.
A further tool to discriminate possible tectonic settings of metamorphic protoliths are the HFSE, which are considered as relatively immobile during subduction-zone metamorphism and subsequent retrograde overprint (e.g., Kogiso et al. 1997; Becker et al. 2000; Spandler et al. 2004; Schmidt et al. 2009). Ratios like Nb/Ta and Zr/Hf (13.4–15.3 and 37.9–44.5, respectively) of the four eclogites broadly overlap the fields of N-MORB, OIB and subduction-related basaltic rocks. The derivation of the protoliths from an enriched OIB-type source however can be excluded based on the high Zr/Nb (19.4–45.1) and low Nb concentrations (<6 ppm), which would be expected to be higher if an OIB-type protolith is considered (Pfänder et al. 2007, Spandler et al. 2004). Furthermore, the negative Nb–Ta anomaly in sample Rh-197 (and to a lesser degree also in Rh-83 and Rh-89) are tentatively regarded as reflecting the derivation from a source with an island-arc setting.
Whole rock Hf (and to a lesser degree also the Nd) isotope compositions can be highly useful to constrain the nature of the eclogite protoliths due to the particular robustness of the Lu–Hf isotope system with respect to metamorphic overprints (e.g., Blichert-Toft et al. 1999; Polat et al. 2003). However, for the studied eclogites this approach is hampered by uncertainties in the protolith formation age, which is required to calculate initial isotope compositions. Therefore, we assume a similar protolith formation age as was determined for eclogites near Sidironero by Liati (2005), reporting U–Pb SHRIMP ages for zircons of ~250 Ma (=t 1). Furthermore, a second protolith formation age (t 2) of 500 Ma was employed as a maximum estimate, as the presence of (possibly inherited) ~430-Ma-old zircon domains (Liati 2005) might indicate even older formation ages. Independent of the protolith age assumed, calculated εHf(t) and εNd(t) values for Rh-83 and Rh-197 are consistently low (see Fig. 8b), and they rather agree with the characteristics of a more enriched magmatic protolith than MORB. Conversely, initial values for Rh-89 well overlap the field for MORB. Due to the near-chondritic 176Lu/177Hf of 0.03468, the whole rock εHf value of sample Rh-210 (εHf (i) ~ +10) is rather independent of the protolith age and overlaps the lower limit of the MORB field (Fig. 8b). However, back-calculated Hf and Nd isotopes of samples Rh-83 and Rh-197 unambiguously indicate a more enriched protolith than MORB (Fig. 8b).
Collectively, our trace element and Hf–Nd isotope data for the four eclogites indicate significant element loss for sample Rh-210 and possibly preserved original magmatic trace element signatures for samples Rh-83, Rh-89 and Rh-197. We can furthermore confidently exclude an OIB-type source for all four eclogites. The protoliths of samples Rh-83, Rh-89 and Rh-197 most likely originate from an island-arc setting based on the negative Nb–Ta anomalies and the rather unradiogenic Hf–Nd isotope systematics that are inconsistent with a MORB-setting. For sample Rh-210, we propose that the modified trace element pattern (loss of LREE, Th and also low K content) as well as the elevated 147Sm/144Nd and 176Lu/177Hf is the result of a partial melting event affecting the protolith somewhat before the closure of the Lu–Hf and Sm–Nd chronometers.
Implications for the tectonics of the Rhodopes and Hellenides
Our results show that two subduction events of different age are recorded in different structural levels of the Rhodopean nappe stack: Early Cretaceous in the Upper Allochthon and Eocene in the basal part of the Middle Allochthon. Such a distribution, older ages in the structurally higher nappes and younger ages in the deeper levels, is typical for collisional orogens and is also seen, for example, in the Alps (e.g., Gebauer 1999) and the Norwegian Caledonides (e.g., Brueckner and Van Roermund 2004). Our geochronological study confirms the results of Liati and Gebauer (1999) and Liati (2005) from U–Pb zircon dating, in that subduction-related metamorphism in the Rhodopes occurred more than once. In earlier studies, however, the geochronological results were rather assigned to specific areas (e.g., Western Rhodopes, Central Rhodopes—Liati 2005) and not to specific structural levels in the Rhodopean nappe stack. In the present study, we connect the results of the geochronology with the respective tectonostratigraphy, an approach that has emerged in the last few years (Krohe and Mposkos 2002). It is also important to emphasize that our data actually support two metamorphic events (Early Cretaceous and Eocene), but do not preclude the existence of other subduction events, for example, in the Jurassic (Liati 2005; Bauer et al. 2007; Krenn et al. 2010; Nagel et al. 2011), at a more regional scale.
Significance of the Eocene ages from the Middle Allochthon
According to the most widely accepted evolutionary models for the Hellenic-Aegean orogenic system (van Hinsbergen et al. 2005; Papanikolaou 2009; Jolivet and Brun 2010), subduction and related metamorphism and deformation migrated progressively southwards during the Mesozoic and Cenozoic. These models have assumed that the stacking of the Rhodopean nappes is Cretaceous in age. It has also been assumed that from the end of the Cretaceous onward, the Rhodopes were already in the hinterland of the southward-retreating subduction zone (e.g., von Quadt et al. 2005) and thus were only affected by HT metamorphism, magmatism and exhumation. However, this view cannot be maintained any longer. Instead, the basal part of the Middle Allochthon records subduction in the Eocene. Eocene ages for the peak pressure were already determined by U–Pb zircon SHRIMP dating of kyanite-eclogites from the area of Thermes in northern Greece (42.2 ± 9 Ma; Liati and Gebauer 1999). The results presented in our study thus confirm the inferences of Liati and Gebauer (1999). In the Nestos Shear Zone near Sidironero, further west but still in the same structural level, Liati (2005) dated the HP stage of an amphibolitized eclogite to 51.0 ± 1.0 Ma. Our new Eocene ages (44.6 ± 0.7 Ma, 43.5 ± 0.4 Ma, 42.8 ± 0.5 Ma) partially fill the gap between the ages from Thermes and from Sidironero. Hence, we assume that the ages from Thermes and Sidironero do not represent different metamorphic events, as suggested by Liati (2005), but rather point to protracted subduction lasting at least between 51 and 42 Ma. During the course of this subduction episode, different parts of the Middle Allochthon appear to have reached their peak pressure at different times.
Given the age constraints above, the question arises in which subduction zone system, from a palaeogeographic point of view, the Eocene eclogites of the Rhodopes formed. All of the Eocene eclogites are from the lower part of the Middle Allochthon. This tectonic unit disappears beneath the Upper Allochthon towards the south-west. It is unlikely that the Middle Allochthon re-emerges in the ophiolite-bearing Vardar Zone, adjacent to the Rhodopes to the SW, as no Eocene HP metamorphism is known from that area. In the Cycladic Blueschist Unit, however, which is derived from the more south-westerly located Pindos-Cyclades Ocean, eclogite-facies metamorphism is also Eocene in age (U–Pb zircon and Lu–Hf garnet ages from 50 to 52 Ma; Tomaschek et al. 2003; Lagos et al. 2007). From stratigraphic evidence, ophiolites from the Pindos-Cyclades ocean were emplaced towards south-west onto continental crust of the Apulian continent during the Middle to Late Eocene (Papanikolaou 2009). The emplacement of the Middle on the Lower Allochthon of the Rhodopes is also of Middle to Late Eocene age, as it postdates ca. 43 Ma old eclogite-facies metamorphism in the Middle Allochthon (this study, Nagel et al. 2011), and predates granitoid intrusions at 32 Ma (Jahn-Awe et al. 2010). Therefore, we suggest that the base of the Middle Allochthon in the Rhodopes represents the continuation of the Pindos-Cyclades suture towards deeper levels. In consequence, the underlying Lower Allochthon is correlated with the continental crust of Apulia (External Hellenide carbonate platform), as suggested by Dinter (1998), Krohe and Mposkos (2002), Jahn-Awe et al. (2010), and as illustrated in a palaeotectonic sketch map in Fig. 9b. The Rhodopes are therefore interpreted as a large-scale tectonic window, exposing in its core the deepest nappe units of the Hellenides (see also Mposkos and Krohe 2000). The sutures of both the Vardar and Pindos-Cyclades oceans are rooted along the northern border of the Rhodopes, north of the metamorphic domes (Arda).
Significance of the Early Cretaceous age from the Upper Allochthon
The new 126.0 ± 0.7 Ma age for the eclogite from the Upper Allochthon is similar to published ages from the Kimi Complex (119.0 ± 3.5 Ma, Sm–Nd age for a garnet-pyroxenite; Wawrzenitz and Mposkos 1997; and 117.4 ± 1.9, U–Pb zircon SHRIMP age for a garnet-rich mafic rock; Liati et al. 2002) and indicates that the Upper Allochthon in the Eastern Rhodopes was subducted during the Early Cretaceous. We assume that the Upper Allochthon represents the continental margin of Europe (Moesia), which collided with a Jurassic arc formed above a south-west-dipping subduction zone that consumed the Meliata Ocean (Bonev and Stampfli 2008; Jahn-Awe et al. 2010; see Fig. 9a). During and after this collision, the European margin entered the subduction zone and was affected by eclogite-facies metamorphism. Between the Lower Cretaceous and the Eocene HP metamorphism, a subduction polarity switch occurred and the kinematic framework changed fundamentally.
Conclusions
New combined petrological and geochronological data for metamorphic rocks from the Bulgarian section of the Rhodopes can place new constrains on the tectonic evolution of the Eastern Mediterranean region. Lu–Hf garnet geochronological results for four eclogites from the Middle and Upper Allochthon reveal two high-pressure metamorphic events: (1) in the Lower Cretaceous (126 Ma) for the Upper Allochthon and (2) in the Eocene (45–42 Ma) for the Middle Allochthon. Geothermobarometry can place the peak metamorphic conditions in the Middle Allochthon at c. 700°C/20–25 kbar. Major and trace element analyses of the whole rocks point to an island-arc origin of the samples from the Middle Allochthon and clearly exclude OIB-like protoliths. Our data furthermore support previous findings that the Rhodopes represent a large-scale tectonic window, emphasizing a key role of the Rhodopes to understand the tectonic evolution of the Hellenides.
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Acknowledgments
The authors are very grateful to Dieter Garbe-Schönberg, Ulrike Westernströer and the technical staff of the ICPMS lab at CAU Kiel for trace element measurements. Furthermore, Radegund Hoffbauer, Universität Bonn, is thanked for XRF analyses. We also thank D. Herwartz and J. E. Hoffmann for constructive discussions and help in the laboratory and V. Laurenz for assistance during electron microprobe measurements. We also thank J.-P. Burg, E. Moulas and N. Georgiev for discussions. This work greatly benefited from the reviews of Jan Kramers, Susanne Skora and an anonymous reviewer. Editorial handling by Jochen Hoefs was highly appreciated. Funding by DFG (Deutsche Forschungsgemeinschaft) grants BR1909/8-1 and Mu1490/9-2 to CM and FR700/10 to NF are highly acknowledged.
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Kirchenbaur, M., Pleuger, J., Jahn-Awe, S. et al. Timing of high-pressure metamorphic events in the Bulgarian Rhodopes from Lu–Hf garnet geochronology. Contrib Mineral Petrol 163, 897–921 (2012). https://doi.org/10.1007/s00410-011-0705-5
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DOI: https://doi.org/10.1007/s00410-011-0705-5