Abstract
The Scandinavian Caledonides contain several non-cogenetic eclogite-bearing terranes that were metamorphosed before the main orogenic stage in Scandian time (430–395 Ma). Although petrological and geochronological data from these terranes have provided essential information on the geodynamic history of the Caledonian orogenic cycle, the general picture is still patchy. To refine existing geodynamic models, we have dated the eclogite occurrence in the Jæren nappe, SW Norway, by Lu–Hf and Sm–Nd geochronology. Five out of the six studied samples provide a weighted mean Lu–Hf age of 469.9 ± 1.2 Ma (±2σ). One sample provided a significantly younger age of 457.9 ± 2.4 Ma. Garnet from the younger sample grew exclusively at eclogite facies conditions. In contrast, garnet from the other samples comprises prograde cores and peak metamorphic rims. Age estimates that take Lu-contributions of each zone into account provide an age of 471.0 ± 0.9 Ma for the cores and suggest a ca. 455 Ma age for the rims, which is identical to the bulk-garnet age of the younger sample. The same pattern is indicated by Sm–Nd ages, although these are relatively imprecise and reflect isotopic disturbance during thermal overprinting upon exhumation. The data define a new high-pressure age population for the Scandinavian Caledonides, which allows more detailed insight into the subduction history that affected the Baltoscandian margin before Scandian continental collision. Furthermore, this study highlights the potential complexities involved in garnet geochronology and shows the strength of Lu–Hf dating for unraveling the geochronological record of HP rocks.
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Introduction
The Scandinavian Caledonides comprise several eclogite-bearing terranes, which occur along the >2,000 km long axis of the orogen (Griffin et al. 1985; Bryhni and Andréasson 1985; Brueckner and van Roermund 2004). Such terranes represent fossil subduction zones and are therefore key targets for studying the geodynamic history of orogenic belts. The best known of these is the archetypal high- and ultrahigh pressure (HP and UHP) terrane of the Western Gneiss Complex (WGC) in western Norway, which is a spectacular example of a Proterozoic crustal fragment that was reworked during the Caledonian cycle by subduction to depths up to 200 km (e.g., Scambelluri et al. 2009; van Roermund 2009). The WGC has provided detailed insight into the processes that occur during deep burial and exhumation of continental crust in collision zones (e.g., Terry and Robinson 2004; Brueckner and van Roermund 2004; Tucker et al. 2004; Root et al. 2005; Kylander-Clark et al. 2008, 2009; Spengler et al. 2009). As shown by numerous geochronological studies that used various isotope systems having different closure temperature, the HP and UHP metamorphism of the WGC is related to the Scandian orogeny (e.g., Griffin and Brueckner 1980; Tucker et al. 1990, 2004; Carswell et al. 2003; Root et al. 2004; Kylander-Clark et al. 2007, 2008, 2009; Glodny et al. 2008a; Spengler et al. 2009). Other eclogite occurrences are found in various tectonic units of the Caledonian thrust belt that separates the WGC from the Baltic Crystalline Shield (BCS, Fig. 1). Geochronological studies indicate that eclogitization in these units occurred during several (U)HP stages between 505 and 430 Ma (Mørk et al. 1988; Corfu et al. 2003; Brueckner and van Roermund 2007; Glodny et al. 2008b). These data suggest that the Scandinavian Caledonides are an amalgamation of different HP and UHP terranes that record several possibly independent subduction–eduction cycles (Brueckner and van Roermund 2004).
In contrast to many other (U)HP occurrences in this orogen, the eclogites of the Jæren nappe, SW Norway (Fig. 1) have not been previously dated. The regional correlation of this occurrence to eclogite-bearing terranes to the north (Bergen Arcs, WGC) is unknown, i.e., it is unclear whether this tectonic subunit is a lateral continuation of other (U)HP terranes or if it is a distinct sub-unit with its own unique tectono-metamorphic history. To constrain the HP age of the Jæren eclogites, we subjected these rocks to a detailed Lu–Hf and Sm–Nd geochronological study. Interpretation of the resulting age data takes into account contributions of different garnet growth zones that were identified by major- and trace element analysis. This approach provides valuable insight into the tectono-metamorphic evolution of the south Scandinavian Caledonides and deepens the understanding of the (U)HP history of the Caledonian orogenic belt.
Geological setting and geochronological background
The Scandinavian Caledonides comprise a large NNE- to SSW-trending allochthonous thrust belt that was transported from west to east onto the western margin of the Baltic Crystalline Shield (Fig. 1). The orogen formed as a result of early- to mid-Palaeozoic convergence between the protocontinents Laurentia and Baltica and concomitant destruction of the intervening Iapetus Ocean. Final continental collision occurred during the Scandian orogeny (Roberts and Gee 1985), resulting in the westward continental subduction of Baltica underneath Laurentia. These final stages of the Caledonian Wilson cycle involved widespread tectono-metamorphic overprinting of crustal material along the western edge of BCS, as well as the (re-)assembly, rearrangement, and long-distance transport of various tectonic complexes that were thrusted onto the hinterland of the BCS (e.g., Brueckner and van Roermund 2004, and references therein).
Fragments of the Caledonian-reworked BCS are currently exposed in tectonic windows along the axis of the orogen and in the western sector (Fig. 1). The largest and most intensely metamorphosed of these is the WGC. The Caledonian deformation and metamorphism of this terrane becomes increasingly more pronounced and of higher grade towards the west and northwest (Krogh 1977; Griffin et al. 1985). In three regions on the west margin of the WGC—in the areas of Stadlandet–Nordfjord, Sørøyane, and Nordøyane–Moldefjord—the occurrence of coesite and diamond indicate that UHP metamorphic conditions were reached (e.g., Cuthbert et al. 2000). The (U)HP metamorphic overprint of WGC protoliths, which are of Sveconorwegian (=Grenvillian) or older age, documents long-lived, deep subduction of the Baltoscandian margin between 430 and 400 Ma (e.g., Kylander-Clark et al. 2009; Spengler et al. 2009).
Several tectonic units of the allochthonous complex that is juxtaposed between the WGC and the Baltic basement contain eclogite facies rocks (Fig. 1). The Lindås nappe of the Bergen Arcs consists of Sveconorwegian granulites (Bingen et al. 2001, 2004) that have been locally transformed to eclogite along veins and shear zones (Austrheim 1987; Jamtveit et al. 1990). Eclogitization occurred at 1.8–2.1 GPa and ca. 700°C (Jamtveit et al. 1990), and has been dated at ca. 430 Ma using U–Pb zircon geochronology and Rb–Sr internal mineral isochrons (e.g., Kühn et al. 2002; Glodny et al. 2002; Bingen et al. 2004; Glodny et al. 2008b). The Seve Nappe Complex contains two main eclogite-bearing sub-units: the Norrbotten Terrane (NT; Andréasson et al. 1985) and the Jämtland–Västerbotten Terrane (JVT; Van Roermund 1985; Fig. 1). Despite apparent similarities in field occurrence and structural relationships, the eclogites from these areas yielded different peak metamorphic pressure estimates (1.5–2.7 GPa for the NT versus 1.4–1.8 GPa for the JVT; e.g., Brueckner and van Roermund 2004). Furthermore, HP metamorphism of the JVT occurred at 457.9 ± 4.5 Ma (weighted mean of 6 Sm–Nd ages by Brueckner and van Roermund 2007), i.e., significantly later than eclogitization of the Norrbotten eclogites (503.5 ± 9.2 Ma; weighted mean of three Sm–Nd ages by Mørk et al. 1988). Peak metamorphism of eclogites in the Tromsø nappe of northern Norway (Krogh et al. 1990) occurred at 2.8 GPa or possibly even higher pressure (Krogh-Ravna and Roux 2006) and was dated at 452.1 ± 1.7 Ma by U–Pb in eclogitic zircon (Corfu et al. 2003). Even though this age overlaps with the data reported for HP metamorphism of the JVT, the terranes are unrelated in terms of composition, affinity, and protolith age, and they occur in different tectono-stratigraphic levels of the orogenic thrust complex (Brueckner and van Roermund 2004, 2007).
This study focuses on the eclogites of the Jæren nappe, which is a tectonic subunit within the allochthonous thrust complex of SW Norway (Fig. 1). The nappe is sandwiched between the overlying Karmsund Nappe, which is dominated by ca. 490 Ma meta-ophiolites (Sturt and Thon 1978; Dunning and Pedersen 1988), and a thin phyllite unit, which tectonically encloses slabs of Sveconorwegian gneiss (Roddick and Jorde 1981; Birkeland 1981). The three tectonic units together form the orogenic thrust complex in the Stavanger area. During the exhumation stage of the Scandian orogeny, this complex was emplaced onto the SW margin of the BCS (Verschure et al. 1980), which in this area mostly comprises felsic plutons and gneisses that yielded Sveconorwegian U–Pb zircon ages and provide evidence for 1.6- to 1.5-Ga age components (Möller et al. 2002). The basement rocks underwent ultrahigh temperature (UHT) metamorphism that was related to the ca. 930 Ma anorthosite emplacement (Schärer et al. 1996; Bingen and van Breemen 1998; Möller et al. 2002) and were pierced by ca. 616 Ma basaltic dikes (Bingen et al. 1998).
The Jæren nappe mainly consists of amphibolite facies gneisses, marbles, and quartzites. Locally, these rocks enclose kilometer-scale amphibolite and foliated granodiorite bodies (Birkeland 1981), the latter being of Sveconorwegian age (Roddick and Jorde 1981). The studied eclogites are exposed in the southeastern segment of the Jæren nappe, near the village of Garborg (Fig. 1). Only very limited geochronological data are available for these rocks. Polygenetic zircon grains in felsic lenses within the eclogites yielded a U–Pb age of ca. 920 Ma and contain a ca. 1,600 Ma age component (ID-TIMS analyses by Corfu, pers. comm.).
Field relationships and sample description
Outcrops in the study area are dominated by folded, mylonitized, and migmatized gneisses, comprising both amphibole- or mica-dominated rocks. These alternate on a decimeter- to decameter-scale and define a compositional banding structure that is parallel to the regional amphibolite-facies foliation. The eclogites occur either as bands that are concordant with the compositional layering in the host rocks or as decimeter- to decameter-sized lenses and boudins dispersed within the gneisses (Maijer et al. 1987, 1990; Smit et al. 2008). The eclogites are characterized by a HP foliation (S 1) that is defined by the alignment of fine-grained (<350 μm) omphacite and zoisite grains. In eclogite bands, the structure is sub-parallel or parallel to the compositional layering, therefore, to the regional amphibolite-facies foliation in the gneisses (S 2). The S 1 foliation in eclogite lenses is often at an angle to S 2 in the surrounding gneisses. Towards the retrogressed margins of the lenses, S 1 becomes gradually less pronounced and is overprinted by the S 2 structure.
The majority of the eclogites are mylonites that have a well-developed, penetrative S 1 fabric. In other eclogites, the S 1 foliation shows a spacing of up to 5 mm and occurs between composite eclogitic microlithons characterized by a granular texture and grain sizes up to 2 mm. Based on textural and compositional characteristics, the eclogites were further subdivided into two types by Maijer et al. (1987). Type 1 eclogite is characterized by millimeter-scale, idioblastic garnet grains in a fine-grained (<500 μm) foliated omphacite-, quartz-, and zoisite-rich matrix, whereas type 2 eclogite comprises millimeter-scale omphacite grains in a more-or-less foliated matrix of mostly zoisite, omphacite, garnet, quartz, and rutile. Eclogite boudins and lenses are dominated by type 2. Most eclogite bands consist of both type 1 and type 2, which alternate in a non-systematic way and are separated by ca. 10 cm thick transition zones of intermediate texture.
The eclogites comprise meta-basaltic rocks of E-MORB composition (Smit, unpublished data) that are dominated by the mineral assemblage garnet + omphacite + zoisite + clinozoisite + quartz + apatite + rutile ± dolomite ± kyanite ± phengite ± paragonite. Representative electron microprobe (EMPA) analyses were reported by Smit et al. (2008). Application of conventional geothermobarometry indicates pressure and temperature (P–T) conditions of 2.3–2.8 GPa and 585–655°C (Smit et al. 2008). Some eclogites have been subsequently affected by localized episodic CO2-metasomatism at equal or slightly lower pressures, giving rise to eclogite facies magnesite- and aragonite-bearing assemblages. Decompression was associated with an amphibolite facies deformational and metamorphic overprint, which caused the formation of the main mineral assemblages and deformation structures in the country-rock gneisses.
Six eclogite samples were selected for the current study. These include two type 1 (MS09001 and MS09002a) and two type 2 eclogites (MS08010 and MS08013b), as well as two eclogites of intermediate texture (MS03005 and MS10010d; for UTM coordinates see Supplementary Table 1). These samples were chosen because they cover the full range of observed eclogite textures and they are, with the exception of MS09002a, relatively pristine, meaning that over 80% of their volume consists of eclogite minerals. Simple outcrop maps of all sample locations are provided by Smit et al. (2008). Samples MS09001 and MS09002a (ca. 1 and 3 kg, respectively) are banded and foliated HP rocks from a single decimeter-thick eclogite layer. The layer is continuous over 2 meters, beyond which it is fragmented into a series of boudins. Similar rocks, which most likely represent the same layer, occur along strike in the same outcrop. Both samples contain relatively quartz-rich layers that host aragonite- and magnesite-bearing assemblages (Smit et al. 2008). These layers are separated from the bulk eclogite by a sharp interface in sample MS09001, whereas they define diffuse compositional variations in sample MS09002a. In both samples, garnet is abundant (ca. 50 vol%) and relatively coarse-grained (up to 2.5 mm). Mineral inclusions in garnet mostly consist of omphacite, kyanite, zoisite, clinozoisite, phengite, dolomite, quartz, rutile, and fluorapatite. These phases are homogeneously distributed or concentrated in rings. The innermost 10–30 μm of some garnet grains host inclusions of taramitic amphibole, quartz, rutile, and ilmenite. Omphacite grains in the matrix (150–250 μm) and in pressure shadows of garnet (up to 2 mm) contain inclusions of rutile, quartz, garnet, and phengite. The matrix of MS09001 shows a well-developed S 1 fabric, whereas the retrogressed matrix of MS09002a is dominated by statically crystallized amphibole, secondary clinopyroxene, micas, and plagioclase. Samples MS08010 (ca. 6 kg) and MS08013b (ca. 8 kg) represent two partially retrogressed eclogite lenses. These samples only show the S 1 fabric. Both samples contain ca. 25 vol% of omphacite porphyroclasts (up to 2.3 mm) in a mylonitic matrix of omphacite, zoisite, clinozoisite, quartz, apatite, dolomite, rutile, and fine-grained (<200 μm) garnet. The few inclusions that occur in omphacite and garnet consist of rutile and quartz, as well as other eclogite phases such as phengite and zoisite. The texturally intermediate sample MS03005 (ca. 2 kg) is from a transition zone between type 1 and 2 eclogites. The sample is a banded HP mylonite having an almost equigranular and relatively fine-grained (100–200 μm) eclogite assemblage. Inclusions in garnet and omphacite are common (up to 30 vol%) and mostly comprise rutile, garnet, and quartz. Sample MS10010d (ca. 4 kg) is from a meter-scale eclogite lens. The rock shows centimeter-scale compositional layering that reflects a variable modal abundance of quartz. Garnet grains (200–800 μm) contain sporadic inclusions of rutile, quartz, zoisite, and omphacite. These grains occur in a matrix that comprises (hyp-)idioblastic grains (150–250 μm) of omphacite, phengite, zoisite, and kyanite. The S 1 fabric in the sample is spaced and only weakly developed. The spatial distribution of S 1 structures is not related to variations in composition or garnet grain size.
Analytical methods
For whole-rock analysis, approximately 200 g of crushed sample were powdered in an agate ring mill. For mineral separation, the remaining crushed material was processed in a disk mill and was split into grain size fractions by sieving. Fractions containing monocrystalline garnet and omphacite grains were separated using a Frantz Isodynamic® magnetic separator. To avoid possible fractionation between core and rim based on differences in magnetic properties (Lapen et al. 2003), we carefully checked that 100% of the garnet and omphacite populations occurred within single magnetic fractions. The target phases were then handpicked under a binocular microscope. Clean, whole garnet grains or randomly picked grain fragments were selected for analysis (see representative photomicrographs in Supplementary Fig. 1). Care was taken to avoid fractionation based on color variations. Garnet grains hosting excessive amounts of inclusions were excluded, because these may harbor assemblages that crystallized during retrograde fracturing. In case of samples MS09001 and MS09002a, garnet fragments were sorted into different fractions by sieve size. Sample MS09002a allowed handpicking of whole garnet grains. The different separates were analyzed to test the influence of garnet grain size on ages and to monitor possible effects of analyzing whole garnet grains versus grain fragments.
Unlike garnet color, which can vary from core to rim depending on composition, omphacite color is typically uniform throughout grains. In the case of samples in which omphacite was partially replaced in a pseudomorphic fashion by amphibole, omphacite-bearing size fractions comprise grains having similar crystal shape and magnetic properties, but a different green color. To unambiguously identify omphacite in these fractions, different grains representing the variable tones of green in each sample were analyzed by confocal micro-Raman spectroscopy using the Jobin–Yvon HR-800 dispersive Raman spectrometer (for analytical details see Smit et al. 2008). The analyses showed that the green tone of omphacite varied from sample to sample and that a green tone typical of omphacite in one sample represented amphibole in another. It is stressed here that for accurate geochronological analysis of omphacite, the phase must be unambiguously separated from retrograde minerals. In cases where optical identification is difficult, the application of spectroscopic techniques is helpful. After the Raman identification test, omphacite grains were hand picked under a binocular microscope. Selected omphacite grains represent either the porphyroblastic assemblage that defines the S 1 (MS03005, MS09001, and MS10010d) or fragments of a coarse-grained, porphyroclastic omphacite population (MS08010 and MS08013b). Photomicrographs of omphacite separates are shown in Supplementary Fig. 1.
For EPMA and laser ablation ICP-MS (LA-ICP-MS) studies, omphacite and whole garnet grains were mounted in epoxy and polished down to their approximate geometric centers. The garnet grains were subjected to X-ray mapping by use of a JEOL JXA-8900M Superprobe®. The Ca X-ray maps of the grains that were used for modeling are shown in Fig. 2a, d and Supplementary Fig. 2a. Unmarked Ca-maps and maps of the Fe-, Mg-, and Mn-content of these grains are included in Supplementary Fig. 3. Trace element analysis was performed by LA-ICP-MS using a New Wave Research UP193HE ArF Excimer laser ablation system (λ = 193 nm), operating with ca. 9 J/cm2 at 5 Hz, coupled to a Thermo Scientific® Element2 ICP-MS. After 40 s of baseline monitoring, grains were analyzed for 1 min using a spot diameter of 25–35 μm for garnet and 90 μm for omphacite. During this period, 32 sweeps through the targeted isotope spectrum were performed. The Si contents based on EPMA data were used as an internal standard. External standardization was done by performing two replicate measurements of the NIST SRM-612 glass standard (Pearce et al. 1997; Jochum et al. 2005) between every 5 unknowns. Standards were crosschecked for accuracy by measuring the USGS BHVO-2G glass as an unknown. The accepted values for this standard (Jochum et al. 2005) lie within error (i.e., 2 SD) of the average concentration determined for each element. Data were screened and were filtered for inclusions by using isotope monitors (e.g., 43Ca, 49Ti, 88Sr, 90Zr). Precision on rare-earth element (REE) concentrations (based on measurements of the isotopes 139La, 140Ce, 141Pr, 146Nd, 147Sm, 153Eu, 157Gd, 159Tb, 163Dy, 165Ho, 166Er, 169Tm, 172Yb, and 175Lu) is 6–20% (1 SD) depending on absolute elemental abundance. Precision on V and Y concentrations (measured using 51V and 89Y, respectively) is better than 8%. Detection limits for the analyses of REE, V, and Y were below 0.3, 0.5, and 0.1 ppm, respectively. Results are summarized in Figs. 2, 3 and Supplementary Figs. 2, 4.
For Lu–Hf and Sm–Nd studies, mineral separates were cleaned in 2.5 M HCl at room temperature and were rinsed with de-ionized water. Garnet and omphacite fractions, as well as whole-rock samples were spiked with mixed 176Lu–180Hf and 149Sm–150Nd isotope tracers. Garnet and omphacite fractions were digested in Savillex screw-top PFA vials by sequential addition of HF-HNO3-HClO4 (4:2:1) and 10 M HCl, both steps being followed by drying down on a hot plate. This process was repeated until addition of the HCl provided a clear solution, indicating that full digestion of the target phase was achieved. This method dissolves the target phases while leaving behind robust phases that potentially harbor inherited Hf isotope signatures (e.g., rutile and zircon). Whole rock powders were digested in closed Savillex vials with HF-HNO3 on a hot plate and were then evaporated to dryness. After adding more HF–HNO3 to the vials, they were closed and placed with a few ml H2O into steel-jacketed Teflon® bombs at 180°C for 5 days to complete the digestion of refractory phases. All digested samples were then dried down again and were dissolved in 6 M HCl, then diluted to 3 M HCl with H2O, and centrifuged. The spike-equilibrated solutions were then loaded onto heat-shrink Teflon® columns containing Eichrom® Ln-Spec resin, where Lu and Hf were separated from the matrix elements using the method of Münker et al. (2001). The Lu and Hf fractions were purified further by passing them separately through the same columns, but using an abbreviated elution procedure and loading in HCl and ascorbic acid so that Fe is eluted rapidly as Fe2+ (P. Sprung, pers. comm.). The matrix cut from the first stage, which contains the light- and middle REE (LREE and MREE), was loaded in 2.5 M HCl onto glass columns containing Bio-Rad® 50 W-X8 resin. A REE cut was separated using 2.5 and 6 M HCl as eluents and was subsequently loaded onto glass columns packed with Teflon® beads coated with di-(2-ethyl-hexyl) phosphoric acid (HDEHP). Separation of Nd and Sm from the other REE and from each other was achieved by using 0.17 M and 0.4 M HCl, respectively.
Isotope analysis was done using a Micromass IsoProbe® MC-ICP-MS. The Hf standard used in this study is made from AMES Hf metal and has an isotope composition that is indistinguishable from that of the international JMC-475 standard. Hafnium and neodymium isotope ratios were corrected for mass bias using the exponential law and 179Hf/177Hf = 0.7325 and 146Nd/144Nd = 0.7219, respectively. The resulting 176Hf/177Hf values are reported relative to the JMC-475 value of 0.282163, whereas the 143Nd/144Nd measurements are reported relative to 0.511858 for the La Jolla Nd standard. The external reproducibilities of 176Hf/177Hf and 143Nd/144Nd analyses were estimated for individual analysis sessions by measuring standard solutions at various concentrations that spanned those of the sample solutions (8, 24, 40, and 80 ppb; see Bizzarro et al. 2003). In general, the external reproducibility (% 2 SD of multiple analyses of a single solution) is about twice the internal run statistic (% 2 SE of individual analyses). Instrumental drift, if present, was monitored by running standards after every 4–6 samples. Isochron ages and uncertainties were calculated using Isoplot v. 3.27 (Ludwig 2005) and decay constants of 1.867 × 10−11 year−1 for 176Lu (Scherer et al. 2001, 2003; Söderlund et al. 2004) and 6.54 × 10−12 year−1 for 147Sm. The Lu–Hf and Sm–Nd data, and associated ages are compiled in Table 1. Isochron plots for the Lu–Hf and Sm–Nd data are presented in Figs. 4, 5, and Supplementary Fig. 5. Uncertainties on calculated ages and initial isotope compositions are reported at the 2 SD-level, whereas the 95% confidence limits are quoted for weighted means and errors on intercepts. The uncertainties in the 176Lu and 147Sm decay constants are approximately 0.6 and 1.5%, respectively (Begemann et al. 2001, 2001; Scherer et al. 2001, 2003; Söderlund et al. 2004). For the purpose of comparing ages derived from a single isotope system, decay constant uncertainties have not been propagated into the ages.
Results
Garnet and omphacite trace element composition
Garnet grains are dominated by a central domain that is characterized by (1) concentric small-scale variations in Ca concentration with an overall increase in Ca from core to rim, (2) more-or-less obscured concentric variations in Fe and Mg concentrations, which are inversely related, and (3) Mn distributions that are often smoothed equivalents of the Fe distribution (Fig. 2, Supplementary Figs. 2a, 3). Such garnet zones are referred to as grt-1. With the exception of MS03005, garnet grains from all analyzed samples are rimmed by low-grossular garnet (grt-2), which occurs either as concordant rims (e.g., Fig. 2a) or as irregularly shaped zones (e.g., Fig. 2d). With the exception of blue-amphibole-bearing assemblages in the cores of some grains, the abundant inclusions in grt-1 comprise eclogite minerals. No inclusions were identified in grt-2 rims.
The distribution of REE in grt-1 domains is generally symmetric (Fig. 2, Supplementary Fig. 2b). Peak concentrations of the different REE occur at variable distance from the geometric cores of grains. Changes in the heavy REE (HREE) content within grt-1 zones are relatively abrupt, resulting in two types of REE patterns: one that is relatively flat with respect to the HREE normalized to CI-chondrite (hereafter ‘flat-HREE’) and another that is characterized by a decreasing concentration of HREE with increasing atomic number (‘low-HREE’, Fig. 2, Supplementary Fig. 2c). The grt-2 zones show relatively homogeneous REE content and yield only low-HREE patterns. The shift in REE composition along the interface between grt-1 and grt-2 is as abrupt as the change in Ca composition.
Garnet REE zoning is controlled by many aspects such as reactions that occur during garnet growth (e.g., Hickmott et al. 1987; Konrad-Schmolke et al. 2009), the fractionation of these elements into garnet relative to the matrix (e.g., Otamendi et al. 2002; Lapen et al. 2003; Kohn 2009), and rates at which they diffuse through the matrix towards the garnet surface (Skora et al. 2006; Kohn 2009) and through a garnet volume (Van Orman et al. 2002; Tirone et al. 2005). Identification of the imprint of metamorphic processes on garnet REE zoning requires knowledge on whether their incorporation into garnet was limited by diffusion through the matrix. This may be attained through a careful evaluation of the spatial distribution of REE relative to elements that fractionate equally or less strongly into garnet relative to the matrix and which diffuse faster through the rock matrix. For this purpose, we have compared zoning of Y and V in garnet. Yttrium is chemically similar to the middle- to heavier REE (e.g., Ho; Fig. 2), but is usually more abundant in the studied phases and could therefore be measured more precisely; hence it is used here as a M- to HREE proxy. Vanadium (as V3+) generally partitions less strongly into garnet than Y (e.g., data of Hermann 2002). Considering that matrix diffusion coefficients at least partly depend on ionic radius (IR), V (IR = 0.064 nm; Shannon 1976) is assumed to diffuse faster to the surface of growing garnet crystals than Y (IR = 0.090 nm; Shannon 1976).
The abundances of V and Y vary significantly across grt-1 zones. The abundances co-vary in central grt-1 zones (grt-1a) and, from core to rim, trend initially towards and then away from the whole-rock composition in Fig. 3. The change from increasing to decreasing V content from the core outwards in MS09002a is associated with a drastic decrease in the abundance of M- and HREE, forming low-HREE patterns. The abundance of V in grt-1a zones from MS03005 garnet is relatively low and shows only minor variation, plotting on the lower extent of the grt-1a trend. In mantles of grt-1 (grt-1b), Y shows core-to-rim depletion at relatively constant or steadily decreasing V content. The abundance of V and Y throughout grt-1b zones trends towards the composition of grt-2, which is relatively homogeneous among and between eclogite samples (Fig. 3). Although the V content of grt-1a zones of garnet in MS03005 is relatively low and is lower than that of grt-1b in the same sample, grt-1a compositions for this sample plot on the typical grt-1a trend in Fig. 3.
In the context of interpreting Lu–Hf and Sm–Nd age data, the Lu- and Sm contributions of individual garnet zones relative to the bulk-garnet Lu and Sm (X′ Lu and X′ Sm) were modeled following the methods and assumptions listed in Supplementary Text 1 and using the LA-ICP-MS data of representative garnet grains as input (Supplementary Table 2). The results, assuming a 10% 2 SD uncertainty on X′ due to variability of Lu- and Sm concentration and the relative volume of garnet zones among eclogite samples, are provided in Table 2 and Supplementary Fig. 6. For samples that have grt-2 zones, the relative contribution of Lu by these zones to the bulk-garnet Lu (X′ grt-2Lu ) varies between 0.02 and 0.28. The complementary Lu is provided by grt-1a and grt-1b. The relative contribution by either of these grt-1 zones varies strongly (ΔX′ Lu > 0.60). Due to relatively higher abundance of Sm in grt-2 zones, X′ grt-2Sm is generally higher than X′ grt-2Lu and ranges from 0.07 to 0.53. For both Lu and Sm, there is no correlation between X′ grt-1a or X′ grt-1b, and X′ grt-2.
The chondrite-normalized REE content in omphacite typically increases with increasing atomic number for the LREE, reaches a maximum in the MREE range, and decreases for the HREE (Supplementary Fig. 4). Differences between samples in the absolute REE abundance of omphacite, and in the slopes and the position of the peak in the CI-normalized REE diagram relate to differences in whole-rock REE content. Abundances of V vary between 415 and 640 ppm and they show a weak positive correlation with Y contents, which are relatively low (<2 ppm, Fig. 3). Compositional variations within samples are relatively small and not resolvable within individual grains.
Geochronology
Lu–Hf
Lutetium–Hafnium geochronology provided six high-precision internal isochrons (Fig. 4; Table 1). Sample MS03005 yielded a 7-point garnet + omphacite + whole-rock isochron with an age of 457.9 ± 2.4 Ma (MSWD = 1.3). A mineral isochron for sample MS08010, including all garnet analyses, indicates an age of 470 ± 27 (MSWD = 8.1). Excluding the grt.B.1 analysis significantly improves isochron statistics (466.3 ± 4.7 Ma, MSWD = 0.21) without significantly changing the age. The mineral isochron for MS08013b provides an age of 468.2 ± 2.5 Ma (MSWD = 1.4). Including the whole-rock analyses for both MS08010 and MS08013b provides identical, but relatively imprecise ages of 469 ± 14 Ma (MSWD = 2.7) and 470.0 ± 4.9 Ma (MSWD = 2.6), respectively. Sample MS09001 yielded a garnet + omphacite + whole-rock isochron age of 470.7 ± 0.9 (MSWD = 1.7). The isochron for sample MS09002a, which is based on one whole rock and six garnet analyses, yields 469.3 ± 0.8 Ma (MSWD = 1.2). The Lu–Hf age of the 6-point garnet + omphacite + whole-rock isochron for sample MS10010d is 470.7 ± 1.5 (MSWD = 0.71). For all samples except MS03005, the isochron ages overlap within 2 SD and provide a weighted mean age of 469.9 ± 1.2 Ma. For the five samples that have overlapping Lu–Hf ages, the calculated initial 176Hf/177Hf values also overlap within 2 SD, giving a weighted mean of 0.282826 ± 0.000017. The calculated initial 176Hf/177Hf values for sample MS03005 is significantly lower (0.282768 ± 0.000015). The whole-rock analyses by themselves do not define a Lu–Hf isochron. Calculation of depleted-mantle model-ages (t DM) using the CHUR parameters of Bouvier et al. (2008) yielded no solution for the type 2 samples MS08010 and MS08013b and gave highly variable results between 850 and 1,760 Ma for the other samples. The present day εHf value for sample MS03005 (+8.8) is lower than those of the other samples (+11.4 to +13.4).
The duration of garnet growth may exceed our chronological resolution, either due to slow growth rates or due to polygenesis. In such cases, the bulk garnet Lu–Hf and Sm–Nd ages would represent the average age of all growth zones weighted by their respective Lu and Sm contents (Lapen et al. 2003; Kohn 2009). To enable interpretation of the Lu–Hf ages, possible relationships between these ages and the distribution of Lu, i.e., the modeled Lu contribution of different garnet growth zones to the bulk garnet Lu (X′ Lu), were evaluated. A strong correlation exists between X′ grt-2Lu and Lu–Hf isochron age. A linear regression through the data (R 2 = 0.97) allows the estimation of intercepts at 471.0 ± 0.9 Ma for X′ grt-2Lu = 0 and 455 ± 10 for X′ grt-2Lu = 1 (Fig. 6a). The older intercept at X′ grt-2Lu = 0 is taken as an estimate of the grt-1 age, whereas the younger intercept at X′ grt-2Lu = 1 provides an estimate of the grt-2 age. If the grt-2 age component is removed by projecting it through the data points back to X′ grt-2Lu = 0, it is then possible to evaluate any age difference between grt-1a and grt-1b zones by the same approach. There is no significant correlation (R 2 = 0.11) between the resulting grt-1 age estimates and the distribution of Lu between grt-1a and grt-1b (Fig. 6b).
Sm–Nd
The results of Sm–Nd geochronology are shown in Fig. 5 and Table 1. Sample MS03005 provided the youngest isochron age (431 ± 13 Ma, MSWD = 0.30). Samples MS09001 and MS10010d yielded slightly older ages of 453.4 ± 9.6 Ma (MSWD = 0.58) and 457.7 ± 6.2 Ma (MSWD = 0.15), respectively. The isochrons for samples MS08010 and MS08013b indicate ages of 462 ± 14 Ma (MSWD = 0.11) and 464 ± 20 Ma (MSWD = 1.2), respectively. These apparent ages overlap within their relatively large uncertainties with the weighted mean of the Lu–Hf age cluster (469.9 ± 1.2 Ma). The garnet + whole-rock isochron of sample MS09002a provided an age of 470.7 ± 8.3 Ma (MSWD = 0.40). Calculated initial 143Nd/144Nd values range from 0.512240 to 0.512374, providing a weighted mean of 0.512322 ± 0.000051. No statistically valid Sm–Nd isochron could be constructed from whole-rock isotope data. Calculation of t DM using the CHUR values of Bouvier et al. (2008) did not yield systematic results. The present-day εNd value for sample MS03005 is +2.2, whereas other samples provide more positive values (+4.9 to +6.6). The Sm–Nd age data fall on or below the regression line through Lu–Hf age vs. X′ grt-2Lu (Fig. 6a). As was the case for Lu, there is no significant correlation (R 2 = 0.37) between grt-1 age estimates and the distribution of grt-1 Sm between grt-1a and grt-1b (Fig. 6b).
Discussion
Linking garnet compositions to petrological processes
Spatial distribution patterns of REE and other trace elements are potentially important indicators for the process that operated during garnet growth (e.g., Hickmott et al. 1987). Co-varying elemental contents from core to rim may be diagnostic of specific reactions such as amphibole- or epidote breakdown (Konrad-Schmolke et al. 2009). However, different elements may be released into—or taken up from—the matrix during a wide variety of mineral reactions that are not necessarily coeval (e.g., the breakdown of titanite, amphibole, or epidote, or the crystallization of zoisite and rutile), making trace element compositional variations difficult to interpret in terms of reaction processes. Furthermore, coefficients of matrix diffusion (Skora et al. 2006; Kohn 2009) and of garnet/matrix partitioning (e.g., Otamendi et al. 2002; Lapen et al. 2003; Kohn 2009) differ significantly for different elements, even among the REE. These differences may control or even inhibit the formation of reaction-induced zoning. Additionally, such zoning may be effectively removed by intracrystalline diffusion (Van Orman et al. 2002; Tirone et al. 2005).
In spite of these complexities, it can be concluded that if Y concentration anomalies (i.e., abrupt variations) occur systematically further from the core than those of V, then either REE uptake by garnet was kinetically or chemically obstructed, or the anomalies do not record a single reaction mechanism. The latter explanation also applies to garnet showing Y-concentration anomalies that are closer to the core than those of V. Trace element profiles of the studied garnet grains, however, show a wide range of negatively correlated V and Y (i.e., and M- to HREE) concentrations. First, this indicates that diffusive rehomogenization of these elements in garnet was not significant. Second, the observation that the concentration of Y, a REE proxy that is expected to diffuse more slowly through the matrix than V, mirrors that of V along garnet growth profiles shows that the uptake of these elements by the growing garnet was apparently not limited by diffusion through the rock matrix (cf. Skora et al. 2006). This, the differences in the position of peak abundance for the different REE relative to the core most likely reflect differences in their garnet/whole-rock partition coefficients. Furthermore, in the absence of diffusion-limited element uptake, garnet profiles should accurately reflect the changes in matrix composition that occurred as garnet grew. Compositional features common to all samples, such as the synchronized core-to-rim changes in V and Y concentration, suggest that similar metamorphic processes are recorded in the garnet of all samples regardless of grain size. Similarly, changes in concentration trends between garnet generations, e.g., between grt-1a and -1b, may record a specific shift in the reaction mechanism(s) that occurred during garnet growth.
The maximum V content at relatively low concentrations of Y and M- to HREE in grt-1a zones of MS09002a (Fig. 2b) occurs approximately at the transition between taramitic amphibole- and omphacite-bearing inclusion assemblages (core and rim, respectively). As such, the absence of taramitic-amphibole-bearing inclusions and the prograde compositional signature (i.e., high V and V/Y) in garnet from sample MS03005 suggests that it formed exclusively at HP conditions. It is possible that the variations in the concentrations of V, Y, and other elements in prograde garnet were controlled by the presence—and prograde breakdown—of amphiboles belonging to a pre-eclogite assemblage. However, the pre-eclogite assemblage is likely to have contained other phases that may have played an even more important role in the redistribution of the studied trace elements during prograde metamorphism (e.g., titanite, epidote), so interpretations of the observed compositional variations in terms of specific metamorphic processes remain speculative.
Compositional variation across the boundary between grt-1 and grt-2 are relatively abrupt in X-ray maps of Ca (Fig. 2, Supplementary Fig. 2a) and were most likely to have been equally abrupt for the more rapidly diffusing divalent elements (Fe, Mg, and Mn; e.g., Vielzeuf et al. 2007; Perchuk et al. 2009) before their remobilization during thermal overprinting (see maps in Supplementary Fig. 3). Abundances of REE and trace elements such as V and Y in grt-1b zones trend towards the composition of grt-2, indicating that the assemblage controlling the partitioning of elements into the growing garnet did not change significantly between formation of grt-1 and grt-2. This strongly suggests that grt-2 also crystallized at HP conditions.
The age of HP metamorphism
Garnet and omphacite in the studied samples formed during the eclogite stage at estimated peak temperatures of ca. 585–655°C and were subjected to thermal metamorphism after exhumation to upper-crustal levels (Smit et al. 2008). Some temperature estimates for the latter overprint potentially exceed the closure temperature for the Lu–Hf system (T Lu–Hfc ) in garnet grains of ca. 1 mm in diameter (≥680°C; Scherer et al. 2000, using the updated 176Lu decay constant; ≥630°C; Skora et al. 2008). Despite considerable variation in grain size between and within samples, different grain size fractions comprising both whole garnet grains and garnet fragments lie on Lu–Hf isochrons that yield precise and overlapping ages and show MSWD values close to unity (0.21–1.7). This suggests that (1) all garnet and omphacite grains crystallized—or cooled rapidly—below their T Lu–Hfc and (2) diffusion during thermal metamorphism and subsequent cooling did not significantly affect their Lu–Hf systematics. The latter indicates either that T Lu–Hfc is higher than previously estimated or that metamorphic temperatures upon uplift, as calculated by Smit et al. (2008), are overestimated.
As mentioned before, bulk garnet Lu–Hf and Sm–Nd ages represent average ages of all growth zones weighted by their respective Lu and Sm contents. Discrepancies between these ages, resulting from differences in Lu and Sm distribution, can be used to constrain growth histories of monogenetic garnet (e.g., Lapen et al. 2003). In the case of polygenetic garnet, weighted average ages may have little or no geological significance. However, if there is a systematic and resolvable age difference between non-cogenetic garnet zones and the chronometers have remained undisturbed, garnet samples with equivalent growth histories but having variable parent-isotope contributions from different zones (either due to volume or concentration differences) would provide age results that lie on mixing lines between the age components present. Christensen et al. (1989, 1994) have successfully used such an ‘age mixing’ concept to estimate garnet growth rates from centimeter-sized monogenetic garnet crystals, which were physically separated into their constituent growth zones to be individually dated by the Rb–Sr technique. As our samples contained garnet grains that were too small to allow dividing them into separate zones, we have applied a model-based approach. We observed a strong relationship between the Lu–Hf isochron age and X′ grt-2Lu (Fig. 6), which we interpret to represent a mixing line between the end-member age components of grt-1 and grt-2, whereby age variations primarily reflect the degree of mixing between grt-1 and grt-2 age components, and the age component of grt-2 is identical for each sample. The latter implies that grt-2 zones formed synchronously in all grt-2-bearing samples, presumably by the same process.
The mixing line yields an apparent age of 471.0 ± 0.9 Ma for pure grt-1. This is assumed to be an accurate age estimate for the growth of grt-1 in these samples during metamorphism and eclogitization (M A2 , following nomenclature of Smit et al. 2008) and provides a better age estimate for this stage than the weighted mean of the overlapping isochron ages (469.9 ± 1.2 Ma), which includes inaccuracy due to age mixing. There is no resolvable age difference between grt-1a and -1b (Fig. 6b), which implies that all grt-1 crystallized continuously over a time span that is within our estimated precision. This would suggest garnet growth rates that are comparable to those suggested by Christensen et al. (radial growth rates of ca. 0.5–2 mm/Myr; 1989, 1994). Considering that the distribution of Lu relative to garnet nuclei in grt-1 zones varies quite strongly between samples (X′ grt-1bLu normalized to X′ grt-1Lu = 0.3-1.0), a growth time span for grt-1 in excess of a few Myr would inevitably have resulted in increased scatter relative to the mixing line in Fig. 6a and in a mixing trend in Fig. 6b. The lower intercept at X′ grt-2Lu = 1 indicates a ca. 455 Ma age component for grt-2 (Fig. 6a). This age is significantly younger than the age estimate for grt-1 in grt-2-bearing samples and provides an age estimate for a subsequent stage of HP metamorphism (M B2 ). Considering the relatively small volumetric amount of grt-2 and its relatively homogeneous composition, it is likely that its growth duration was short and potentially even shorter than that of grt-1. We note that the precision on the grt-2 age estimate would benefit from precise analyses of garnet having X′ grt-2Lu > 0.5. Appropriate samples, however, i.e., eclogites containing garnet dominated by grt-2 zones, were not recognized.
The Lu–Hf age of grt-1 in sample MS03005 (457.9 ± 2.4 Ma), which nucleated and grew exclusively at eclogite facies conditions, is identical to the grt-2 age estimate, supporting the notion that the latter formed at HP conditions. The relatively young age of MS03005 garnet may be related to the deformation history of the sample, considering its extremely well developed S 1 structure. Either the sample represents an older (ca. 470 Ma) eclogite that was dynamically recrystallized at ca. 458 Ma, or eclogitization was delayed for some 15 Myr after burial to HP conditions. We reject the first hypothesis, considering that grt-1 in the sample exhibits concentric growth zoning and lacks typical internal structures that indicate deformation (e.g., healed fractures, sub-grains) and assume that MS03005 remained unequilibrated at HP conditions until it was dynamically eclogitized in response to extreme strain partitioning during M B2 . This is corroborated by the absence of a prograde growth record in its garnet.
Overall, the data imply that eclogite facies overprinting of the studied rocks occurred during protracted HP metamorphism or during at least two punctuated HP events in the Middle- and Late Ordovician and involved two brief garnet-forming episodes (M A2 and M B2 ). Multiple HP events seem less plausible because there is no petrological evidence for an intermediate stage of decompression. Most likely, the rocks underwent protracted HP metamorphism during which they underwent differential eclogitization and episodic garnet re-equilibration in response to changes in the P–T–D regime and the influx of fluids.
The relatively low precision of 143Nd/144Nd and Sm–Nd isochron ages mainly reflects analytical difficulties stemming from the low abundance of Nd in the analyzed separates. Nonetheless, the Sm–Nd ages are often younger than Lu–Hf ages and show negative deviations from the mixing line in Fig. 6. The amphibolite facies overprint, which resulted in the partial rehomogenization of Fe-, Mg-, and Mn throughout the studied garnet grains (Supplementary Fig. 3), is considered to be the main factor that caused resetting of the Sm–Nd system. The large scatter of the Sm–Nd data suggests that the isotope system was only partially reset and that the degree of resetting varies among samples. Sample MS03005, which yielded the youngest Sm–Nd age (430 ± 13 Ma) also shows the largest discrepancy between Lu–Hf and Sm–Nd ages. We speculate that the equigranular fine-grained texture of this specific sample, which resulted from dynamic HP metamorphism, would have provided relatively short diffusion radii, thus allowing more effective resetting of Sm–Nd systematics than in other samples. Therefore, the ca. 430 Ma age should provide the best age estimate for the resetting of the Sm–Nd system in the studied samples. This would imply that the post-eclogite thermal overprint occurred at least 40 Myr after the onset of eclogitization and was approximately synchronous with Scandian (U)HP metamorphism in other parts of the orogen.
The Jæren eclogites and Caledonian geodynamics
In contrast to the well-constrained ages of HP metamorphism for the studied rocks, the crystallization ages of their protoliths remain obscure. No Lu–Hf or Sm–Nd whole-rock isochron could be constructed and the calculation of t DM for both 176Hf/177Hf and 143Nd/144Nd did not yield consistent results. The only geochronological constraints available in this context are the U–Pb zircon ages reported for felsic lenses within the eclogites from the Garborg area (ca. 920 and 1,600 Ma; F. Corfu, pers. comm.). These ages are similar to igneous crystallization ages determined for SW Norwegian basement rocks (Schärer et al. 1996; Möller et al. 2002), for basement-related fragments in the Jotun nappe (Schärer 1980) and the Hardangervidda-Ryfylke complex (an allochthonous unit correlating to the studied rocks towards the northwest; Andresen and Færseth 1982), and for allochthonous rocks that occur in the Bergen arcs (e.g., Bingen et al. 2001) and in the WGC (Corfu and Andersen 2002; Walsh et al. 2007). The presence of Proterozoic components in the eclogites indicates either that these rocks are ‘Caledonized’ material derived from the cratonic basement, or suggests that a partial melt derived from Proterozoic source rocks was injected into the protoliths. The geological interpretation of the felsic lenses remains unresolved.
The HP ages presented in this study do not overlap with age estimates for HP metamorphism of the eclogite-bearing terranes in the Bergen area (e.g., 429.9 ± 3.5 Ma, Glodny et al. 2008b) and in Norrbotten (503.5 ± 9.2 Ma; Mørk et al. 1988), and a temporal relationship with the UHP metamorphic cycle of the WGC can also be ruled out (Supplementary Fig. 5). The ca. 455 Ma age of the M B2 -stage overlaps with the age of eclogites from the Tromsø area (452.1 ± 1.7 Ma; Corfu et al. 2003; Supplementary Fig. 5), but, in contrast to any other eclogite-bearing unit in the orogen, this terrane was metamorphosed in regions proximal to the Laurentic margin (e.g., Brueckner and van Roermund 2004, 2007). The data presented in this study provide the first Middle Ordovician HP age population for the Scandinavian Caledonides. It is not clear whether this age really dates a subduction episode that is unrelated to previously established pre-Scandian eclogite-forming events.
The HP age component of the M B2 -stage in the studied samples overlaps with the age estimate for HP metamorphism of the JVT in central Sweden (ca. 458 Ma; Brueckner and van Roermund 2007; Supplementary Fig. 5). These authors concluded that their Sm–Nd ages could represent cooling from a thermal maximum that occurred during a preceding metamorphic stage. A correlation with the ca. 500 Ma Finnmarkian orogeny could be excluded because (1) the age data on the JVT seems too consistent to be recording cooling so long after HP metamorphism and (2) the terrane that was most strongly metamorphosed during this stage, the Norrbotten HP terrane, had already been exhumed to upper crustal levels before the end of the Middle Ordovician (Dallmeyer and Gee 1986; Dallmeyer and Stephens 1991; Essex et al. 1997). The ages determined by Brueckner and van Roermund (2007) may record cooling of the JVT after a peak metamorphic stage synchronous with M A2 . In such a case, the difference between the older Jæren age group (471.0 ± 0.9 Ma) and the HP metamorphism of the JVT (ca. 458 Ma; Supplementary Fig. 5) would either reflect the difference in closure temperature between the Sm–Nd system (used by Brueckner and van Roermund 2007) and the Lu–Hf system applied in this study (ΔT c = 90–230°C; recalculated using data of Scherer et al. 2000), or show that the JVT underwent a Late Ordovician overprint that disturbed Sm–Nd systematics as observed in the samples dated in this study. Alternatively, the age data might document regional geological variations along the plate-destructive Baltoscandian margin, indicating either (1) that the studied rocks were buried in the same system as the JVT but at an earlier stage or (2) that they underwent a local HP event that arose independently of JVT subduction. The latter option is highly plausible when considering palaeogeography. Throughout the Ordovician, the southwestern margin of Baltica was separated from the protocontinent Avalonia by a contracting oceanic domain, the Tornquist Sea. Across the British Isles, northeastern Europe, and southern Scandinavia, Ordovician facies shifts in sedimentary successions and arc-related volcanic rocks in the Avalonian foreland record the closure of this ocean, which resulted in the subduction of the Baltoscandian margin underneath Avalonia and the docking of the latter to the BCS during the Late Ordovician (Pharaoh et al. 1993; Cocks et al. 1997; Torsvik and Rehnström 2003). This tectonic event is recorded along the Scandinavian Tornquist zone, i.e., in rocks that constitute—or are derived from—the southwestern segment of the BCS (e.g., Torsvik and Rehnström 2003). Considering the geographical position and the metamorphic age of the studied rocks, it is highly likely that these were reworked in a subduction system that accommodated Avalonia-Baltica convergence. If this system was—or became—tectonically related to the JVT subduction zone, the studied rocks would document a local imprint of the Ordovician subduction stage that was identified as the ‘Jämtlandian’ by Brueckner and van Roermund (2007). It would imply that this stage has a more extensive lateral imprint (>600 km) and affected rocks over a wider tectono-stratigraphic range than previously thought. This suggestion, originally made by Brueckner and van Roermund (2004), is supported by Late Ordovician cooling ages from the allochthonous Høyvik group in western Norway (Andersen et al. 1998; Eide et al. 1999) and by the Ordovician U–Pb zircon and monazite ages from eclogite-bearing allochthons that juxtapose the WGC (Walsh et al. 2007). The Sm–Nd data from the studied rocks suggest that exhumation to upper crustal levels was accomplished at the onset of the Scandian episode (ca. 430 Ma). This would be in concurrence with the timing of exhumation and lateral transport of the JVT, the Høyvik group, and several other allochthonous terranes in the central and southern Caledonides (e.g., Tucker et al. 2004; Hacker and Gans 2005). The post-eclogite history of the studied rocks will be elaborated on in a follow-up study.
Conclusions
Application of Lu–Hf and Sm–Nd geochronology to eclogites from the Jæren nappe, SW Scandinavian Caledonides, indicates that these rocks were affected by protracted HP metamorphism involving two brief episodes of garnet growth during the Middle and Late Ordovician. Five out of the six studied eclogite samples provided Lu–Hf ages of ca. 470 Ma. One sample yielded a younger age of 457.9 ± 2.4 Ma (±2 SD). Major- and trace element analyses showed that garnet in the younger sample comprises a single growth zone. Garnet porphyroblasts from the other samples have two growth zones that have distinct chemical compositions. The cores show a major- and trace element composition that is similar to that of garnet in the younger sample. Taking into account the Lu-contributions of individual zones allows age estimates of 471.0 ± 0.9 Ma for the cores of these grains and ca. 455 Ma age for the rims. The results presented in this study either document a hitherto unknown eclogite facies stage in the Caledonian Wilson Cycle, or provide a new and more-detailed picture of the HP event than has been deduced elsewhere in the orogen by means of other isotope systems. Furthermore, this study illustrates the complexities and advantages of garnet geochronology and shows the strength of Lu–Hf dating for uncovering the geochronological record of eclogites.
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Acknowledgments
We thank J. Berndt for assistance on the EPMA and the LA-ICP-MS, M. Menneken for help on the Raman spectrometer, E. Janots for constructive criticism, and E. Kooijman for her efforts in the field. Thanks are also due to P. Löbke for sample preparation and H. Baier for her kind help in the laboratory. We acknowledge C. Maijer for providing us with crucial information on the field locality and F. Corfu for generously sharing his preliminary U–Pb results. The constructive reviews of T. J. Lapen and B.R. Hacker and editorial handling by J. Hoefs were highly appreciated. Financial support by the Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged (grant BR 1068/14-1).
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Fig. 1 Representative photomicrographs of garnet and omphacite separates analyzed in this study. The scale bar applies to all photomicrographs
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Fig. 2 Composition of representative garnet grains from samples MS03005, MS08010, MS08013b, and MS09001, which were used for modeling: a: Ca X-ray maps illustrating the spatial distribution of the transition between individual garnet zones (solid black lines, unmarked Ca maps are shown in Supplementary Fig. 3) and the spots measured by LA-ICP-MS; b: V, Y, and stacked REE profiles; c: CI-normalized REE diagrams. Enlargements of the Lu and Sm profiles can be found in Supplementary Fig. 6
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Fig. 3 X-ray maps of garnet grains selected for age modeling (*) and of other garnet grains from the dated samples: a: Ca; b: Fe; c: Mg; d: Mn. Scale bars are 150 μm
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Fig. 5 Comparison of the Lu–Hf and Sm–Nd age data from this study and age estimates for (U)HP metamorphism in other eclogite-bearing units in the Scandinavian Caledonides. The HP stage from the studied rocks is generalized to 470-455 Ma, corresponding to the onset of the main eclogite stage (M A2 , outlined) and the youngest Lu–Hf age (457.9 ± 2.4 Ma, sample MS03005). Grey areas in the plot display the 2 SD range (Lindås nappe, WGC), the weighted mean ± 2 SD (JVT, NT), or the best estimate (Tromsø nappe) of the age determinations per (U)HP unit. Data from terranes besides the Jæren nappe are taken from the references as cited in the figure. References that are not included in the main text are given in full
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Fig. 6 Modeled elemental contributions by different garnet zones for Lu (a-c) and Sm (d-f): The elemental distribution of Lu (a) and Sm (d); the concentration of Lu (b) and Sm (e) multiplied by the incremental volume (dV); the relative contribution of Lu (c) and Sm (f) for the three garnet zones grt-1a, grt-1b, and grt-2. For figure clarity, error bars have been omitted
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Table 2 Lu and Sm distributions in garnet grains selected for age modeling. The axis label ‘Distance from start’ marks the distance between the start of the line-scan and the position of an analysis projected onto a line through the core of the analyzed grain
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Smit, M.A., Scherer, E.E., Bröcker, M. et al. Timing of eclogite facies metamorphism in the southernmost Scandinavian Caledonides by Lu–Hf and Sm–Nd geochronology. Contrib Mineral Petrol 159, 521–539 (2010). https://doi.org/10.1007/s00410-009-0440-3
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DOI: https://doi.org/10.1007/s00410-009-0440-3