Abstract
Off-line analytical supercritical fluid extraction (SFE) has been largely studied for the analysis of solid samples. The versatility of the technique has led to a large number of applications, a diverse range of analytes being reported (Chester et al.,1994;Hawthorne, 1990;Taylor, 1995). Moreover, SFE of environmental matrices constitutes one of the largest groups of applications and has been previously reviewed (Barnabas et al., 1994;Bowadt and Hawthorne, 1995;Camel et al., 1993;Janda et al., 1993;McNally, 1995). In this chapter the discussion of analytical applications of SFE of solid samples will be updated, including general principals and current trends.
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Alexandrou, N., Lawrence, M. and Pawliszyn, J. (1992) Cleanup of complex mixtures using supercritical fluids and selective adsorbents.Analytical Chemistry64, 301–11.
Alzaga, R., Bayona, J.M. and Barceló, D. (1995) Use of supercritical fluid extraction for pirimi-carb determination in soil.Journal of Agricultural Food Chemistry43, 395–400.
Alzaga, R., Bayona, J.M. and Barceló, D. (1996) Supercritical fluid extraction of atrazine and itsmetabolites from soil.Journal of High Resolution Chromatography19, 23–6.
Alzaga, R.,Maldonado, C. and Bayona, J.M. (1998) Intercomparison between SFE, ASE, sonication and Soxhlet for the extraction of trialkylamines in environmental matrices. International Journal of Environmental Analytical Chemistryin press.
Ashraf-Khorassani, M., Houck, R.K. and Levy, J.M. (1992) Cryogenically cooled adsorbent trap for off-line supercritical fluid extraction.Journal of Chromatographic Science30, 361–6.
Ashraf-Khorassani, M., Taylor, L.T. and Zimmerman, P. (1990) Nitrous oxide versus carbon dioxide for supercritical fluid extraction and chromatography of amines.Analytical Chemistry62, 1177–80.
Barnabas, I.J., Dean, J.R and Owen, S.P. (1994) Supercritical fluid extraction of analytes from environmental samples. A review.Analyst119, 2381–94.
Bartle, K.D., Clifford, A.A., Hawthorne, S.B.et al(1990) A model for dynamic extraction using a supercritical fluid.Journal of Supercritical Fluids3, 143–9.
Bayona, J.M. (1993) The role of supercritical fluid extraction in the automation of sample preparation.Laboratory Robotics and Automation5, 283–92.
Bicking, M.K.L., Hayes, T.G., Kiley, J.C.et al(1993) An experimental design approach to the optimization of supercritical fluid extraction for the determination of oil and grease in soil.Journal of Chromatographic Science31, 170–6.
Bowadt, S. and Hawthorne, S.B. (1995) Supercritical fluid extraction in environmental analysis.Journal of Chromatography A703, 549–71.
Bewadt, S. and Johansson, B. (1994) Analysis of PCBs in sulfur-containing sediments by off-line supercritical fluid extraction and HRGC-ECD.Analytical Chemistry66, 667–73.
Burford, M.D., Hawthorne, S.B. and Miller, D.J. (1993) Evaluation of drying agents for off-line supercritical fluid extraction.Journal of Chromatography A657, 413–27.
Cai, Y. and Bayona, J.M. (1995) Simultaneous speciation of butyl-, phenyl-, and cyclohexyltin compounds in aqueous matrices using ethylation followed by solid-phase trace enrichment, SFE, and GC determination.Journal of Chromatographic Science33, 89–97.
Cai, Y., Alzaga, R. and Bayona, J.M. (1994) In situ derivatization and supercritical fluid extraction for the simultaneous determination of butyltin and phenyltin compounds in sediment.Analytical Chemistry66, 1161–7.
Camel, V., Tambuté, A. and Caude, M. (1993) Analytical-scale supercritical fluid extraction: a promising technique for the determination of pollutants in environmental matrices.Journal of Chromatography A642, 263–81.
Chau, Y.K. and Brown, F.Y. (1995) Supercritical fluid extraction of butyltin compounds from sediment.Analytica Chimica Acta304, 85–9.
Chester, T.L., Pinkston, J.D. and Raynie, D.E. (1994) Supercritical fluid chromatography and extraction.Analytical Chemistry66, 106R–130R.
Dachs, J., Alzaga, R., Bayona, J.M. and Quevauviller, P. (1994) Development of a supercritical fluid extraction procedure for tributyltin determination in sediments.Analytica Chimica Acta286, 319–27.
Dachs, J., Fernández, I. and Bayona, J.M. (1997) Combined experimental design and information theory for the optimisation of supercritical fluid extraction of organic priority pollutants from sediment.Analytica Chimica Acta351, 377–85.
Dooley, K.M., Ghonasgi, D., Knopf, F.et al(1990) Supercritical CO2—cosolvent extraction of contaminated soils and sediments.Environmental Progress9, 197–203.
Emteborg, H., Björklund, E., Ödman, F.et al(1995) Determination of methyl mercury in sediments using supercritical fluid extraction and gas-chromatography coupled with microwave-induced plasma emission spectrometry.Analyst121, 19–29.
Fahmy, T.M., Paulaitis, M.E., Johnson, D.M.et al(1993) Modifier effects in the supercritical fluid extraction of solutes from clay, soil, and plant materials.Analytical Chemistry65, 1462–9.
Fernández, P., Alder, A.C., Ster, M.J.F.et al(1996) Determination of the quaternary ammonium surfactant ditallowdimethylammonium in digested sludges and marine sediments by supercritical fluid extraction and liquid chromatography with postcolumn ion-pair formation.Analytical Chemistry68, 921–9.
Fernández, I., Dachs, J. and Bayona, J.M. (1995) Application of experimental design approach to the optimization of supercritical fluid extraction of polychlorinated biphenyls and poly-cyclic aromatic hydrocarbons.Journal of Chromatography A719, 77–85.
Fernández-Escobar, I. and Bayona, J.M. (1997) Supercritical fluid extraction of priority organotin contaminants from biological matrices.Analytica Chimica Acta351, 269–76.
Field, J.A., Miller, D.J., Field, T.M.et al(1992) Quantitative determination of sulfonated aliphatic and aromatic surfactants in sewage sludge by ion-pair/supercritical fluid extraction and derivatization gas chromatography/mass spectrometry.Analytical Chemistry64, 3161–7.
France, J.E., King, J.W. and Snyder, J.M. (1991) Supercritical fluid-based cleanup technique for the separation of organochlorine pesticides from fats.Journal of Agricultural Food Chemistry39, 1871–4.
Friedrich, C., Cammann, K. and Kleiböhmer, W. (1995) Matrix independent supercritical fluid extraction of polycyclic aromatic hydrocarbons by employing binary modifiers.Fresenius Journal of Analytical Chemistry352, 730–4.
Furton, K.G., Chen, L. and Jaffé, R. (1995) Rapid determination of uranium on solid matrices by synergistic in situ chelation supercritical fluid extraction and UV absorption spectroscopy.Analytica Chimica Acta304, 203–8.
Furton, K.G., Huang, C.-W., Jaffé, R.et al(1994) High-temperature supercritical fluid extraction of hydrocarbons from geological samples and comparison to Soxhlet extraction.Journal of High Resolution Chromatography17, 679–81.
Giddings, J.C., Myers, M.N., McLaren, L. and Keller, R.A. (1968) High-pressure gas chromatography of non-volatile species. Compressed gas is used to cause migration of intractable solutes.Science162 67–73.
Hale, R.C. and Gaylor, M.O. (1995) Determination of PCBs in fish tissues using supercritical fluid extraction.Environmental Science and Technology29, 1043–7.
Hawthorne, S.B. (1990) Analytical-scale supercritical fluid extraction.Analytical Chemistry62, 633A–642A.
Hawthorne, S.B. and Miller, D.J. (1994) Direct comparison of soxhlet and low-and high-temperature supercritical CO2extraction efficiencies of organics from environmental solids.Analytical Chemistry66, 4005–12.
Hawthorne, S.B., Galy, A.B., Scmitt, V.O.et al(1995) Effect of SFE flow rate on extraction rates: classifying sample extraction behavior.Analytical Chemistry67, 2723–32.
Hawthorne, S.B., Langenfeld, J.J., Miller, D.J. and Burford, M.D. (1992b) Comparison of supercritical CHC1F2N20 and CO2for the extraction of polychlorinated biphenyls and polycyclic aromatic hydrocarbons.Analytical Chemistry64, 1614–22.
Hawthorne, S.B., Miller, D.J., Nivens, D.E and White, D.C. (1992a) Supercritical fluid extraction of polar analytes using in situ chemical derivatization.Analytical Chemistry64, 405–12.
Hawthorne, S.B., Yang, Y. and Miller, D.J. (1994) Extraction of pollutants from environmental solids.Analytical Chemistry66, 2912–20.
Hillmann, R. and Bachmann, K. (1994) On-line supercritical fluid derivatization and extraction-capillary gas chromatography of polar compounds.Journal of High Resolution Chromatography17, 350–2.
Hillmann, R. and Bachmann, K. (1995) Extraction of pesticides using supercritical trifluoromethane and carbon dioxide.Journal of Chromatography A695, 149–54.
Hills, J.W. and Hill, H.H. (1993) Carbon dioxide supercritical fluid extraction with a reactive solvent modifier for the determination of polycyclic aromatic hydrocarbons.Journal of Chromatographic Science31, 6–12.
Hills, J.W., Hill, H.H. Jr, Hansen, D.Ret al(1994) Carbon dioxide supercritical fluid extraction of incinerator fly ash with a reactive solvent modifier.Journal of Chromatography A679, 319–28.
Ho, J.S. and Tang, P.H. (1992) Optimization of supercritical fluid extraction of environmental polutants from a liquid-solid extraction.Journal of Chromatographic Science30, 344–50.
Howard, A.L., Yoo, W.J., Taylor, L.T.et al(1993) Supercritical fluid extraction of environ-mental analytes using trifluoromethane.Journal of Chromatographic Science31, 401–8.
Janda, V., Bartle, K.D. and Clifford, A.A. (1993) Supercritical fluid extraction in environmental analysis.Journal of Chromatography A642, 283–99.
Kane, M., Dean, J.R., Hitchen, S.M.et al(1993) Experimental design approach for supercritical fluid extraction.Analyst271, 83–90.
King, J.W. (1989) Fundamentals and applications of supercritical extraction in chromatographic sciences.Journal of Chromatographic Science27, 355–64.
Laintz, K.E., Wai, C.M., Yonker, C.R.et al(1992) Extraction of metal ions from liquid and solid materials by supercritical carbon dioxide.Analytical Chemistry64, 2875–8.
Langenfeld, J.J., Burford, M.D., Hawthorne, S.B. and Miller, D.J(1992) Effects of collection solvent parameters and extraction cell geometry on supercritical fluid extraction efficiencies.Journal of Chromatography594, 297–307.
Langenfeld, J.J., Hawthorne, S.B., Miller, D.J.et al(1993) Effects of temperature and pressure on supercritical fluid extraction efficiencies of polycyclic aromatic hydrocarbons and polychlorinated biphenyls.Analytical Chemistry65, 338–44.
Langenfeld, J.J., Hawthorne, S.B., Miller, D.J.et al(1995) Kinetic study of supercritical fluid extraction of organic contaminants from heterogenous environmental samples with carbon dioxide and elevated temperatures.Analytical Chemistry67, 1727–36.
Lee, H.-B., Peart, T.E., Nimi, A.J. and Knipe, C.R. (1995) Rapid supercritical carbon dioxide extraction method for determination of polychlorinated biphenyls in fish.Journal of AOAC International78(2), 437–43.
Lee, H.-B., Peart, T.E. and You, R.L. (1992)In situextraction and derivatization of pentachlorophenol and related compounds from soils using a supercritical fluid extraction system.Journal of Chromatography605, 109–13.
Lehotay, S.J., Aharonson, N., Pfeil, E. and Ibrahim, M.A. (1995) Development of a sample preparation technique for supercritical fluid extraction for multiresidue analysis of pesticides in produce.Journal of AOAC International78, 831–40.
Lin, Y.L. and Wai, C.M. (1994) Supercritical fluid extraction of lanthanides with fluorinated 13diketones and tributyl phosphate.Analytical Chemistry66, 1971–5.
Lin, Y., Brauer, R.D., Laintz, K.E.et al(1993) Supercritical fluid extraction of lanthanides and actinides from solid materials with a fluorinated ß-diketone.Analytical Chemistry65, 2549–51.
Liu, Y., López-Avila, V., Alcaraz, M.et al(1993a) Determination of metals in solid samples by complexation-supercritical fluid extraction and gas chromatography-atomic emission detection.Journal of Chromatographic Scence31, 310–16.
Liu, Y., López-Avila, V., Alcaraz, M. and Beckert, W. F. (1993b) Determination of organotin compounds in environmental samples by supercritical fluid extraction and gas chromatography with an atomic emission detector.Journal of High Resolution Chromatography16, 106–12.
Llompart, M.P., Lorenzo, R.A. and Cela, R. (1996a) Optimization of supercritical fluid extraction of phenol and cresols in soil samples.Journal of Chromatography A723, 123–34.
Llompart, M.P., Lorenzo, R.A. and Cela, R. (1996b) Multivariate optimization of supercritical fluid derivatization and extraction of phenol in soil samples.Journal of Chromatographic Science34, 43–51.
López-Avila, V., Dodhiwala, N.S. and Beckert, W.F. (1990) Supercritical fluid extraction and its application to environmental analysis.Journal of Chromatgraphic Science28, 469–76.
López-Avila, V., Dodhiwala, N.S. and Beckert, W.F. (1993) Developments in the supercritical fluid extraction of chlorophenoxy acid herbicides from soil samples.Journal of Agricultural Food Chemistry41, 2038–43.
McNally, M.E.P. (1995) Advances in environmental SFE.Analytical Chemistry67, 308A–315A.
McNally, M.E.P., Deardorff, C.M. and Fahmy, T.M. (1992) Supercritical extraction: new directions and understandings, inSupercritical Fluid Extraction in Supercritical Fluid Technology(eds F.V. Bright and M.E.P. McNally), American Chemical Society, Washington, DC, pp. 144–64.
Macnaughton, S.J., Alessi, P., Cortesi, A.et al(1995) Predictive and experimental methods for the choice of cosolvent in the supercritical fluid extraction of pesticides, inInnovations in Supercritical Fluids(eds K.W. Hutchenson and N.R. Foster), American Chemical Society, Washington, DC, pp. 126–39.
Meyer, A., Kleibhöhmer, W. and Cammann, K. (1993) SFE of PAHs from soils with a high carbon content and analyte collection via combined liquid/solid trapping.Journal of High Resolution Chromatography16, 491–4.
Miao, Z., Zhang, Z. and Pawliszyn, J. (1994) Supercritical fluid extraction and clean-up with temperature fractionation: application to determination of polychlorinated dibenzo-p-dioxins.Journal of Microcolumn Separations 6459–65.
Miller, D.J., Hawthorne, S.B. and McNally, M.E.P. (1993) Solventless collection of analytes by rapid depressurization after static supercritical fluid extraction.Analytical Chemistry65, 1038–42.
Moore, W.N. and Taylor, L.T. (1995) Solid phase trapping mechanisms involved in the supercritical fluid extraction ofDigitalisglycosides with modified carbon dioxide.Analytical Chemistry67, 2030–16.
Morgan, S.L. and Deming, S.N. (1974) Simplex optimization of analytical chemical methods.Analytical Chemistry46, 1179–81.
Mulcahey, L.J. and Taylor, L.T. (1992) Collection efficiency of solid surface and sorbent traps in supercritical fluid extraction with modified carbon dioxide.Analytical Chemistry64, 2352–8.
Mulcahey, L.J., Hedrick, J.L. and Taylor, L.T. (1991) Collection efficiency of various solid-phase traps for off-line supercritical fluid extraction.Analytical Chemistry63, 2225–32.
Murugaverl, B. and Voorhees, K.J. (1991) On-line supercritical fluid extraction/chromatography system for trace analysis of pesticides in soybean oil and rendered fats.Journal of Microcolumn Separations3, 11–16.
Murugaverl, B., Gharaibeh, A. and Voorhees, K.J. (1993) Mixed adsorbent for cleanup during supercritical fluid extraction of three pesticides in tissues.Journal of Chromatography A657, 223–6.
Nguyen, D.-K., Bruchet, A. and Arpino, P. (1995) Determination of sterols in sewage sludge by combined in situ trimethylsilylation/supercritical fluid extraction and GC/MS.Environmental Science and Technology29, 1686–90.
Oostdyk, T.S., Grob, R.L., Snyder, G.J.L. and McNally, M.E. (1993) Study of sonication and supercritical fluid extraction of primary amines.Analytical Chemistry65, 596–600.
Page, S.H., Sumpter, S.R. and Lee, M.L. (1992) Fluid phase equilibria in supercritical fluid chromatography with carbon.Journal of Microcolumn Separations4, 91–122.
Pawliszyn, J. (1993) Kinetic model of supercritical fluid extraction.Journal of Chromatographic Science31, 31–7.
Porter, N.L., Rynaski, E.R., Campbell, E.R.et al(1992) Studies of linear restrictors and analyte collection via solvent trapping after supercritical fluid extraction.Journal of Chromatography30, 367–73.
Pyle, S.M. and Setty, M.M. (1991) Supercritical fluid extraction of high sulfur soils, with use of a copper scavenger.Talanta38, 1125–8.
Raynie, D. (1993) Warning concerning the use of nitrous oxide in supercritical fluid extractions.Analytical Chemistry65, 3127–8.
Reighard, T.S. and Olesik, S.V. (1996) Comparison of the extraction of phenolic and nitroaromatic pollutants using supercritical and enhanced-fluidity liquid methanol-CO2mixtures.Journal of Chromatography A737, 233–42.
Reindl, S. and Hofler, F. (1994) Optimization of the parameters in supercritical fluid extraction of polynuclear aromatic hydrocarbons from soil samples.Analytical Chemistry66, 1808–16.
Sauvage, E., Rocca, J.-L. and Toussaint, G. (1993) The use of nitrous oxide for supercritical fluid extraction of pharmaceutical compounds from animal feed.Journal of High Resolution Chromatography16, 234–8.
Smart, N.G., Carlesson, T., Kast, T.et al(1997) Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide.Talanta44, 137–50.
Souk, K. and King, J.W. (1994) Supercritical fluid extraction and enzyme immunoassay for pesticide detection in meat products.Journal of Agricultural Food Chemistry42, 1469–74.
Taylor, L.T. (1995) Strategies for analytical scale SFE.Analytical Chemistry67, 364A–370A.
Thompson, P.G. and Taylor, L.T. (1994) Liquid trapping after supercritical fluid extraction with modified carbon dioxide.Journal of High Resolution Chromatography17, 759–64.
Thompson, P.G., Taylor, L.T., Richter, B.E.et al(1993) Trapping efficiencies of various collec-tion solvents after supercritical fluid extraction.Journal of High Resolution Chromatography16, 713–16.
Tilio, R., Kapila, S., Nam, K.S.et al(1994) Reduction/elimination of sulfur interference in organochlorine residue determination by supercritical fluid extraction.Journal of Chromatography A662, 191–7.
Toews, K.L., Shroll, R.M., Wai, C.M.et al(1995) pH defining equilibrium between water and supercritical CO2. Influence of SFE of organics and metal chelates.Analytical Chemistry67, 4040–3.
Valverde-García, A. and Fernández-Alba, R. (1995) Extraction of methamidophos residues from vegetables with supercritical fluid carbon dioxide.Journal of AOAC International78(3), 867–73.
van der Velde, E.G., Dietvorst, M., Swart, C.P.et al(1994a) Optimization of supercritical fluid extraction of organochlorine pesticides from real soil samples.Journal of Chromatography A683, 167–74.
van der Velde, E.G., Ramlal, M.R., van Beuzekom, A.C.et al(1994b) Effects of parameters on supercritical fluid extraction of triazines from soil by use of multiple linear regression.Journal of Chromatography A683, 125–39.
Vejrosta, J., Ansorgová, A., PlanetaJ. et al(1994a) Solute trapping in off-line supercritical fluid extraction using controlled modifier condensation.Journal of Chromatography A683, 407–10.
Vejrosta, J., Planeta, J., Mikesová, M.et al(1994b) Solute collection after off-line supercritical fluid extraction into a moving liquid layer.Journal of Chromatography A685, 113–19.
Wai, C.M., Lin, Y., Brauer, R.et al(1993) Supercritical fluid extraction of organic and inorganic mercury from solid materials.Talanta40, 1325–30.
Wenclaviak, B.W., Heemken, O.P., Sterzenbacch, D.et al(1995) Device for efficient solvent collection of environmentally relevant compounds in off-line SFE.Analytical Chemistry 674577–80.
Wenclaviak, B.W., Maio, G., van Hoist, C.et al(1994) Solvent trapping of some chlorinated hydrocarbons after supercritical fluid extraction from soil.Analytical Chemistry 66 3581–6.
Wenclawiak, B.W. and Krah, M. (1995) Reactive supercritical fluid extraction and chromatography of arsenic species.Fresenius Journal of Analytical Chemistry351, 134–8.
Yang, Y., Bewadt, S., Hawthorne, S.B. and Miller, D.J. (1995a) Subcritical water extraction of polychlorinated biphenyls from soil and sediment.Analytical Chemistry 674571–6.
Yang, Y., Gharaibeh, A.S., Hawthorne, and Miller, D.J. (1995b) Combined temperature/modifier effect on supercritical CO2extraction efficiencies of polycyclic aromatic hydrocarbons from environmental samples. Analytical Chemistry 67641–56.
Yang, Y., Hawthorne, S.B. and Miller, D.J. (1995c) Comparison of sorbent and solvent trapping after supercritical fluid extraction of volatile petroleum hydrocarbons from soil.Journal of Chromatography A 699265–76.
Yang, Y., Hawthorne, S.B. and Miller, D.J. (1997) Class-selective extraction of polar, moderately polar, and nonpolar organics from hydrocarbon wastes using subcritical water.Environmental Science and Technology31, 430–7.
Young, T.M. and Weber, W.J. (1997) A distributed reactivity model for sorption by soils and sediments. 7. Enthalpy and polarity effects on desorption under supercritical fluid conditions.Environmental Science and Technology31, 1692–6.
Zhou, M., Trubey, R.K., Keil, Z.O. and Sparks, D.L. (1997) Study of the effects of environmental variables and supercritical fluid extraction parameters on the extractability of pesticide residues from soils using a multivariate optimization scheme.Environmental Science and Technology31, 1934–9.
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Bayona, J.M. (1998). Off-line supercritical fluid extraction for solid matrices. In: Ramsey, E.D. (eds) Analytical Supercritical Fluid Extraction Techniques. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4948-8_3
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