Abstract
Synthesis of alkene/carbon monoxide cooligomers and copolymers by transition metal catalysts was pioneered more than 50 years ago by Reppe using nickel based complexes. The Reppe [1] catalyst produced only low- melting oligomers and was not used on an industrial scale. A further development of the nickel based catalyst by Klabunde [2] and Keim [3] led to the synthesis of low molecular weight copolymers.
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Margl, P., Michalak, A., Ziegler, T. (2003). Theoretical Studies on Copolymerization of Polar Monomers. In: Sen, A. (eds) Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers. Catalysis by Metal Complexes, vol 27. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9266-6_9
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