Abstract
The relationships among the pressure P, volume V, and temperature T of solid-state materials are described by their equations of state (EOSs), which are often derived from the consideration of the finite-strain energy or the interatomic potential. These EOSs consist of typically three parameters to determine from experimental P-V-T data by fitting analyses. In the empirical approach to EOSs, one either refines such fitting parameters or improves the mathematical functions to better simulate the experimental data. Despite over seven decades of studies on EOSs, none has been found to be accurate for all types of solids over the whole temperature and pressure ranges studied experimentally. Here we show that the simple empirical EOS, P = α1(PV) + α2(PV)2 + α3(PV)3, in which the pressure P is indirectly related to the volume V through a cubic polynomial of the energy term PV with three fitting parameters α1–α3, provides accurate descriptions for the P-vs-V data of condensed matter in a wide region of pressure studied experimentally even in the presence of phase transitions.
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Introduction
One of the most important issues in condensed matter sciences, particularly, in geology and geophysics, is to accurately predict the structural and physical properties of solids under high pressure and temperature1,2,3,4,5,6,7. In general, a solid-state material under high pressure and temperature can exhibit properties quite different from those found at ambient conditions. At a given temperature T, a solid under external pressure P decreases its volume V with increasing P, but V changes a lot more slowly than does P. The pressure-induced volume decrease may require a change in the structure type (i.e., the pattern of the relative atom arrangements in a repeat unit cell) thereby causing a structural phase transition and an associated physical property change. For example, when P is increased at room temperature, elemental chalcogen Te8,9,10,11,12,13,14, Se15,16,17,18,19,20, or S15,21,22,23,24,25 undergoes a number of structural phase transitions while its electrical property changes from insulating at ambient pressure to metallic and superconducting at high pressure26,27. Hydrogen sulfide H2S is a diamagnetic molecular species at ambient conditions, but is converted, under the pressure of over ∼110 GPa, to a condensed phase that becomes superconducting at ∼200 K25,28, the highest among all superconductors known so far. An isothermal EOS relates P and V at a certain temperature T. Over the past 70 years the P-vs-V data have been studied for a variety of solids in various pressure ranges (e.g., see Table 1), and their EOSs have been examined. So far, however, no isothermal EOS is applicable to all types of solids and is accurate over the whole range of pressure studied especially when a solid undergoes several structural phase transitions in the pressure region studied.
With increasing pressure P, the volume V of a solid under pressure changes very slowly compared with the pressure change. The shortcomings of the known EOSs originate essentially from the attempts to relate the fast changing variable P to a very slowly changing variable V. These problems can be circumvented if the pressure change is related to a pressure-induced energy change that is associated with the volume V and also varies nearly at the same rate as does P. The energy term PV satisfies these two requirements because, while increasing P, the volume V of a solid under pressure P decreases very slowly so that the term PV changes nearly as fast as P in the entire range of P. Furthermore, at a given P, the term PV is determined by the value of V, not by how the atoms are arranged within the volume so that the term PV cannot be overly sensitive to phase transitions. With increasing P, the term PV should increase slightly more slowly than does P because V decreases slightly under pressure. Therefore, it should be possible to accurately describe the P-vs-V data of any solid over the entire pressure range studied experimentally by the simple EOS,
which expands P as a polynomial of PV, where the constants αi (i = 1, 2, 3, etc.) are the fitting parameters. For those familiar with the traditional EOSs, use of Eq. 1 is quite unconventional because P is expanded in terms of the variable PV that contains itself. However, our goal is to find an accurate, though indirect, relationship between P and V valid for the entire pressure region studied experimentally by way of determining an accurate relationship between P and PV. From the resulting P-vs-V relationship, one can derive an accurate description of other thermodynamic quantity such as bulk modulus, as we demonstrated in our work. When this expression is truncated to P = α1(PV) + α2(PV)2, P = α1(PV) + α2(PV)2 + α3(PV)3, and P = α1(PV) + α2(PV)2 + α3(PV)3 + α4(PV)4, we obtain the quadratic, cubic and quartic approximations for Eq. 1. Here we establish that the cubic approximation with three fitting parameters α1–α3 is accurate enough in describing the P-vs-V data for condensed matter in a wide region of pressure experimentally probed even in the presence of several structural phase transitions.
Results
Formulation of the EOS
In testing whether an isothermal EOS is accurate over the entire range of pressure studied experimentally, the ideal systems to analyze would be elemental chalcogens Te, Se and S because they have been studied at room temperature over wide pressure ranges (i.e., 0–330 GPa for Te, 0–150 GPa for Se, and 0–213 GPa for S) (see Table 1), because each chalcogen undergoes a number of phase transitions with increasing P, and because their room-temperature atomic structures are known under widely different pressures. For each chalcogen, we begin our analysis by first determining the relative energies of its known atomic structures at various P on the basis of density functional theory (DFT) calculations, the details of which are described in Methods. We summarize the space groups of the known atomic structures at various pressures P (mostly around the room temperature), the volumes V per atom, the energies PV per atom, and the calculated electronic energies E per atom in Section 1(a)–(c) of the supporting information (SI). The calculated electronic structures are also presented in terms of density of states (DOS) plots in Section 1(d)–(f) of the SI. As anticipated, with increasing pressure, the DOS plot for each chalcogen is shifted toward the higher energy while the band gap present at low pressure disappears at high pressure.
The calculated energy E for Te is plotted as a function of P in Fig. 1a (those for Se and S in Section 2(a,b) of the SI), which shows a reasonable linear relationship, E≈a1P + a0, with slope a1 and intercept a0. Fig. 1a also plots the enthalpy H = E + PV per atom as a function of P using a0 as the intercept. This plot also exhibits a reasonable linear relationship, H≈b1P + a0, with the slope b1 > > a1 for all chalcogens. At a given temperature, therefore, the energy term PV = H–E varies almost linearly with P, i.e., P≈PV/(b1–a1). Unlike the case of gaseous substances for which the PV term is a constant independent of P at a given T, the PV term for each condensed-phase chalcogen increases almost linearly with P because, compared with the rate of change in P, that in V is very small. Nevertheless, the H-vs-P plot for each chalcogen is slightly concave down with respect to the base line, b1P. As already pointed out, this reflects that, with increasing P, the rate of change in P is slightly greater than that in PV due to a pressure-induced decrease in V. The latter allows one to expand P as a power series of PV as expressed in Eq. 1. Indeed, the P-vs-V data points used for constructing the H-vs-P plots are very well described, for example, by the quadratic approximation of Eq. 1 (see Section 2(c) of the SI). As will be discussed below, the nonlinear terms of Eq. 1, e.g., α2(PV)2 and α3(PV)3, are related to how the volume V of a solid decreases under pressure P.
To test the applicability of the isothermal EOS, Eq. 1, in a wide region of pressure studied experimentally, we first analyze the experimental P-vs-V data available in the literature for each chalcogen. The P-vs-PV plot for Te, presented in Fig. 1b, reveals that the experimental points in the 0–330 GPa region8,9,10,11,12,13,14 are very well described by the cubic approximation. The fitting curves from the quadratic and quartic approximations are not shown because they are practically impossible to distinguish, with naked eye alone, from that of the cubic approximation. The same conclusion is reached for Se15,16,17,18,19,20 and S15,21,22,23,24,25 (see Section 2(a,b) of the SI for Se and S, respectively). The fitting coefficients α1–α3 obtained for Te, Se and S resulting from the cubic approximation are summarized in Table 2, and those from the quadratic, cubic and quartic approximations are compared in Section 2(d) of the SI. The coefficients α1 and α2 are always positive, and α1 > > α2 > > |α3| with α2/α1 ≈ 10−3 and |α3|/|α2| ≈ 10−4.
Error analysis
To assess the accuracies of the quadratic, cubic and quartic approximations for Eq. 1, we analyze the pressure-dependence of the absolute errors, ΔP = Pcalc–Pexpt, as well as that of the % errors, 100 × ΔP/Pexpt, where Pexpt is the pressure observed experimentally, and Pcalc the one calculated from the fitting equations. The pressure-dependence of the % errors for Te is shown in Fig. 1c, and those for Se and S in Section 2(a,b) of the SI. The maximum % error is smaller than 5.5% in the 10.9–330 GPa region for the cubic and quartic approximations, but smaller than 5.4 % in the 38–330 GPa region for the quadratic approximation. The % errors are large in the low P region, but it should be pointed out that the associated absolute errors are rather small (for example, for Pexpt = 0.98 GPa, the corresponding Pcalc values are 1.44, 1.22 and 1.22 GPa from the quadratic, cubic and quartic approximations, respectively) (see Section 2(e) of the SI). In general, the cubic and quartic approximations are similar in accuracy, and are more accurate than the quadratic approximation especially in the low P region. A similar conclusion is reached from the % error and absolute error plots calculated for Se in the 0–140 GPa range and for S in the 0–213 GPa range (see Section 2(a,b) of the SI).
Applicability to other condensed matter
The above analyses of the experimental P-vs-V data for elemental chalcogens suggest strongly that the cubic approximation of the isothermal EOS, Eq. 1, can accurately describe the experimental P-vs-V data for various solids in the whole pressure range studied experimentally. To establish this point, we examine the experimental P-vs-V data for various solid-state condensed matter listed in Table 1, which include the elemental Sn, the transition-metals Au and Cu, the alkali halides LiF, NaF, NaCl and CsCl, ice VII, the oxides MgO and MgSiO3, the noble gases Ar, Kr and Xe, as well as molecular hydrogen H2 and D2. As representative examples of these analyses, we discuss the oxides MgO29,30,31,32,33,34,35 and MgSiO336,37,38,39,40,41. The isothermal P-vs-V relationships of these oxides have been extensively studied because they are the end members of (Mg,Fe)O42,43 and (Mg,Fe)SiO3 perovskite42,44, which are the important components of the Earth’s lower mantle. The P-vs-V relationships for MgO29,30,31,32,33,34,35 were examined at room temperature in the 0–140 GPa range, and those for MgSiO336,37,38,39,40,41 at room temperature in the 0–300 GPa range. The P-vs-PV plots and the % error vs. P plots for MgO and MgSiO3 are presented in Fig. 2. The maximum % error is smaller than ∼0.6% for MgO, and smaller than ∼1% for MgSiO3, in the entire pressure ranges studied experimentally. For the remainder of the solids listed in Table 1, our results are summarized in Section 3(a)–(k) of the SI. The fitting coefficients α1–α3 obtained for the solid-state condensed matter of Table 1 from the cubic approximation are listed in Table 2 together with the maximum % errors. It is clear that the cubic approximation of the isothermal EOS, Eq. 1, provides an accurate description in the entire pressure regions examined experimentally. (Hereafter, the cubic approximation of Eq. 1 will be used without further mentioning).
The isothermal EOS, Eq. 1, is also applicable to non-solid-state condensed matter. As examples, we analyze the experimental P-vs-V data for the polymer, poly(ε-caprolactone) (PCL)45, determined at 100.6 °C in the 0–0.2 GPa region as well as those for liquid H2O46 determined at 15 °C, 25 °C and 35 °C in the 0–0.1 GPa region. Our results summarized in Section 3(m)–(p) of the SI show that the maximum % error for the polymer is smaller than 0.3%, and that for liquid water is practically zero, in the entire pressure region studied. Clearly, Eq. 1, provides an accurate description of the P-vs-V relationship for these materials. It should be pointed out that the ideal gas law is a special case of Eq. 1, when the PV term is a constant independent of P.
Discussion
Bulk modulus
Now that Eq. 1 provides an isothermal EOS accurate for the entire pressure range studied for a given system, we search for a simple expression for the corresponding bulk modulus B valid for the entire pressure region. In the cubic approximation, Eq. 1 is a quadratic equation of P, from which P is written in terms of V as
Thus, the bulk modulus B is expressed as
This equation expresses the bulk modulus as a function of volume, namely, B(V). For each value of V, however, there is a unique value of P associated with it, so that the B(V) vs. V relationship can be easily converted to the corresponding B(P) vs. P relationship. For convenient use of this relationship, we fit the B(P)-vs.-P relationship by the polynomial,
The B(P)-vs-P plot thus-obtained for Te is presented in Fig. 1d. For other solids listed in Table 1, the B(P)-vs-P plots are presented in Section 3(a)–(r) of the SI. The coefficients B0, B1, B2 and B3 determined for each condensed matter are summarized in Table 3, which also lists the calculated bulk modulus at P = 0, referred to as B0,calc, for each system. The B0 deviates from the B0,calc because the polynomial fitting (Eq. 4) poorly describe the low-pressure region. Nevertheless, the B0 and B0,calc values are quite similar for all systems except for Te and Se.
For every system, our analysis leads to only one B0 value because the entire pressure region studied is represented by the single fitting curve, Eq. 4. In the traditional study for a system undergoing several phase transitions, each phase covering a certain pressure region (say, P1 to P2) is described by the EOS covering only the pressure region P1–P2. The resulting EOS for each different phase generates the bulk modulus, which we will refer to as B0,expt, and the virtual volume V0. It is the B0,expt obtained for the “first” phase (i.e., the phase stable in the lowest pressure region for which P1 = 0) that should be compared with the B0 or the B0,calc value obtained from our EOS. For systems with several phases, Table 3 lists only the B0,expt values of their first phases. Clearly, these B0,expt values are well described by the B0 and/or B0,calc values determined from our EOS analyses. The B0,expt values found for the various phases of Te, Se and S can be accounted for in terms of our EOS analyses as presented in Section 4 of the SI.
Qualitative meaning of the EOS
To gain insight into the meaning of the EOS, Eq. 1, we rewrite it in a slightly different form. In general, α1(PV) > > α2(PV)2 > > α3(PV)3 so that P≈α1(PV). By using this approximation, Eq. 1 is rewritten as
where the volume Vc is defined as Vc ≡ 1/α1, which is very close to the volume at zero-pressure, V0. Eq. 5 reveals that the decrease in the volume of a condensed matter under pressure is a polynomial function of P. Since α2(PVc)2 > > |α3|(PVc)3, the term α2Vc2P dominates over α3Vc3P2. Namely, the volume decreases with increasing P. The α3Vc3P2 term compensates the overcorrection (when α3 < 0), or the under-correction (when α3 > 0), given by the α2Vc2P term. In essence, the EOS, Eq. 1, reveals that the volume of a solid under pressure can be described as a polynomial function of pressure.
Summary
We presented the empirical equation of state that accurately describes the pressure-versus-volume data for various types of condensed matter in a wide region of pressure studied experimentally. This is also true for systems undergoing several phase transitions in the pressure region studied. This equation of states results from the fact that the pressure change of a condensed matter is accurately described by a cubic polynomial of the pressure times the volume.
Methods
Our non-spin-polarized DFT calculations employed the frozen-core projector augmented wave method47,48 encoded in the Vienna ab initio simulation package49, and the generalized-gradient approximation of Perdew, Burke and Ernzerhof 50 for the exchange-correlation functional. To ensure the accuracies of the calculations, a high plane-wave cut-off energy of 1000 eV was used, and the Brillouin zone associated with each repeat unit cell was sampled by a large number of k-points. For example, the structure of S at 206 GPa was calculated by using a set of 24 × 24 × 24 k-points. Our calculations for Te, Se and S employed their reported crystal structures under various pressures, except for the 160 and 173 GPa structures of S as described in Section 1(c). The threshold for the self-consistent-field energy convergence was set at 10−8 eV for all structures of Se, Te and S. For the optimization of the structures of S at 160 and 173 GPa, the threshold for the force convergence at each atom was set at 0.005 eV/Å.
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How to cite this article: Gordon, E. E. et al. Condensed-matter equation of states covering a wide region of pressure studied experimentally. Sci. Rep. 6, 39212; doi: 10.1038/srep39212 (2016).
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References
Birch, F. Finite Elastic Strain of Cubic Crystals. Phys. Rev. 71, 809–824 (1947).
Vinet, P., Ferrante, J., Smith, J. R. & Rose, J. H. A universal equation of state for solids. J. Phys. C: Solid State Phys. 19, L467–L473 (1986).
For a recent review, see: Garai, J. Semiempirical pressure-volume-temperature equation of state: MgSiO3 perovskite is an example. J. Appl. Phys. 102, 123506 (2007).
Cohen, R. E., Gülsren, O. & Hemley, R. J. Accuracy of equation-of-state formulations. Am. Mineral. 85, 338–344 (2000).
Roy, S. B. & Roy, P. B. Applicability of isothermal three-parameter equations of state of solids-a reappraisal. J. Phys.: Condens. Matter 17, 6193–6216 (2005).
Taravillo, M., Baonza, V. G., Núñez, J. & Cáceres, M. Simple equation of state for solids under compression. Phys. Rev. B 54, 7034–7045 (1996).
Anderson, O. L. Equations of State of Solids for Geophysics and Ceramic Science (Oxford University Press, 1994).
Sugimoto, T. et al. Bcc-fcc structure transition of Te. J. Phys. Conf. Ser. 500, 192018 (2014).
Hejny, C. & McMahon, M. I. Large structural modulations in incommensurate Te-III and Se-IV. Phys. Rev. Lett. 91, 215502 (2003).
Vaidya, S. N. & Kennedy, G. C. Compressibility of 22 elemental solids to 45 kB. J. Phys. Chem. Solids 33, 1377–1389 (1972).
Adenis, C., Langer, V. & Lindqvist, O. Reinvestigation of the structure of tellurium. Acta Cryst. C 45, 941–942 (1989).
Aoki, K., Shimomura, O. & Minomura, S. Crystal structure of the high-pressure phase of tellurium. J. Phys. Soc. Jpn. 48, 551–556 (1980).
Takumi, M., Masamitsu, T. & Nagata, K. X-ray structural analysis of the high-pressure phase III of tellurium. J. Phys.: Condens. Matter 14, 10609–10613 (2002).
Parthasarathy, G. & Holzapfel, W. B. High-pressure structural phase transitions in tellurium. Phys. Rev. B 37, 8499–8501 (1988).
Degtyareva, O. et al. Novel chain structures in group VI elements. Nat. Mater. 4, 152–155 (2005).
Akahama, Y., Kobayashi, M. & Kawamura, H. Structural studies of pressure-induced phase transitions in selenium up to 150 GPa. Phys. Rev. B 47, 20–26 (1993).
Marsh, R. E. & Pauling, L. The crystal structure of β selenium. Acta Cryst. 6, 71–75 (1953).
Parthasarathy, G. & Holzapfel, W. B. Structural phase transitions and equations of state for selenium under pressure. Phys. Rev. B 38, 10105–10108 (1988).
Akahama, Y., Kobayashi, M. & Kawamura, H. Structural studies of pressure-induced phase transitions in selenium up to 150 GPa. Phys. Rev. B 47, 20–26 (1993).
Akahama, Y., Kobayashi, M. & Kawamura, H. High-pressure phase transition to β-polonium type structure in selenium. Solid State Commun. 83, 273–276 (1992).
Luo, H., Greene, R. G. & Ruoff, A. L. β-Po phase of sulfur at 162 GPa: X-ray diffraction study to 212 GPa. Phys. Rev. Lett. 71, 2943–2946 (1993).
Warren, B. E. & Burwell, J. T. The structure of rhombic sulphur. J. Chem. Phys. 3, 6–8 (1935).
Akahama, Y., Kobayashi, M. & Kawamura, H. Pressure-induced structural phase transition in sulfur at 83 GPa. Phys. Rev. B 48, 6862–6864 (1993).
Degtyareva, O., Gregoryanz, E., Somayazulu, M., Mao, H. K. & Hemley, R. J. Crystal structure of the superconducting phases of S and Se. Phys. Rev. B 71, 214104 (2005).
Einaga, M. et al. Crystal structure of 200 K-superconducting phase of sulfur hydride system. arXiv 1509.03156v1 (2015).
Struzhkin, V. V., Hemley, R. J., Mao, H. K. & Timofeev, Y. A. Superconductivity at 10–17 K in compressed sulphur. Nature 390, 382–384 (1997).
Akahama, Y., Kobayashi, M. & Kawamura, H. Pressure induced superconductivity and phase transition in selenium and tellurium. Solid State Commun. 84, 803–806 (1992).
Drozdov, A. P., Eremets, M. I., Troyan, I. A., Ksenofonto, V. & Shylin, S. I. Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system. Nature 525, 73–76 (2015).
Speziale, S., Zha, C. S., Duffy, T. S., Hemley, R. J. & Mao, H. K. Quasi-hydrostatic compression of magnesium oxide to 52 GPa: Implications for the pressure-volume-temperature equation of state. J. Geophys. Res. 106, 515–528 (2001).
Li, B., Woody, K. & Kung, J. Elasticity of MgO to 11 GPa with an independent absolute pressure scale: Implications for pressure calibration. J. Geophys. Res. 111, B11206 (2006).
Fei, Y. Effects of temperature and composition on the bulk modulus of (Mg,Fe)O. Am. Mineral. 84, 272–276 (1999).
Dewaele, A., Fiquet, G., Andrault, D. & Hausermann, D. P-V-T equation of state of periclase from synchrotron radiation measurements, J. Geophys. Res. 105, 2869–2877 (2000).
Utsumi, W., Weidner, D. J. & Liebermann, R. C. Properties of Earth and Planetary Materials at High Pressure and Temperature (eds Manghnani, M. H. & Yagi, T. ) pp. 327–333 (American Geophysical Union, 1998).
Hirose, K., Sata, N., Komabayashi, T. & Ohishi, Y. Simultaneous volume measurements of Au and MgO to 140 GPa and thermal equation of state of Au based on the MgO pressure scale. Phys. Earth Planet. Interiors. 167, 149–154 (2008).
Jacobsen, S. D. et al. Compression of single-crystal magnesium oxide to 118 GPa and a ruby pressure gauge for helium pressure media. Am. Mineral. 93, 1823–1828 (2008).
Utsumi, W., Funamori, N. & Yagi, T. Thermal expansivity of MgSiO3 perovskite under high pressures up to 20 GPa. Geophys. Res. Lett. 22, 1005–1008 (1995).
Fiquet, G. et al. P-V-T equation of state of MgSiO3 perovskite. Phys. Earth Planet. Interiors. 105, 21–31 (1998).
Saxena, S. K., Dubrovinsky, L. S., Tutti, F. & Bihan, T. L. Equation of state of MgSiO3 with the perovskite structure based on experimental measurement. Am. Mineral. 84, 226–232 (1999).
Fiquet, G., Dewaele, A., Andrault, D., Kunz, M. & Bihan, T. L. Thermoelastic properties and crystal structure of MgSiO3 perovskite at lower mantle pressure and temperature conditions. Geophys. Res. Lett. 27, 21–24 (2000).
Vanpeteghem, C. B., Zhao, J., Angel, R. J., Ross, N. L. & Bolfan-Casanova, N. Crystal structure and equation of state of MgSiO3 perovskite. Geophys. Res. Lett. 33, L03306 (2006).
Sakai, T., Dekura, H. & Hirao, N. Experimental and theoretical thermal equations of state of MgSiO3 post-perovskite at multi-megabar pressures. Sci. Rep. 6, 22652 (2016).
Anderson, D. L. Theory of the Earth. Ch. 5, 79–102 (Blackwell Scientific Publications, 1989).
Crowhurst, J. C., Brown, J. M., Goncharov, A. F. & Jacobsen, S. D. Elasticity of (Mg,Fe)O Through the Spin Transition of Iron in the Lower Mantle. Science 319, 451–453 (2008).
Zhang, L. et al. Disproportionation of (Mg,Fe)SiO3 perovskite in Earth’s deep lower mantle. Science 344, 877–882 (2016).
Rodges, P. A. Pressure-volume-temperature relationships for polymeric liquids: A review of equations of state and their characteristic parameters for 56 polymers. J. Appl. Polym. Sci. 48, 1061–1080 (1993).
Chen, C. T., Fine, R. A. & Millero, F. J. The equation of state of pure water determined from sound speeds. J. Chem. Phys. 66, 2142–2144 (1977).
Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B 50, 17953–17979 (1994).
Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59, 1758–1775 (1999).
Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169–11186 (1996).
Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized Gradient Approximation Made Simple. Phys. Rev. Lett. 77, 3865–3868 (1996).
Anderson, M. S. & Swenson, C. A. Experimental compressions for normal hydrogen and normal deuterium to 25 kbar at 4.2 K. Phys. Rev. B 10, 5184–5191 (1974).
Wanner, R. & Meyer, H. Velocity of sound in solid hexagonal close-packed H2 and D2 . J. Low. Temp. Phys. 11, 715–744 (1973).
Acknowledgements
This research used resources of the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. MHW thanks Prof. Jerry L. Whitten for invaluable discussion concerning the qualitative meaning of the isothermal EOS, Eq. 2.
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This work was conceived by M.-H.W. and J.K., and E.E.G. carried out all DFT calculations. The empirical EOS was realized by M.-H.W. and E.E.G. while analyzing the computational results. Further testing of the EOS was designed by M.-H.W. and J.K., and E.E.G. carried out the analyses. All authors participated in the discussion of the draft written by M.-H.W.
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Gordon, E., Köhler, J. & Whangbo, MH. Condensed-matter equation of states covering a wide region of pressure studied experimentally. Sci Rep 6, 39212 (2016). https://doi.org/10.1038/srep39212
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DOI: https://doi.org/10.1038/srep39212
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