In this paper, magnesium-doped CoFe2O4 (Co0.5Mg0.5Fe2O4) compound was synthesized by a solidstate reaction route. The impact of Mg inclusion on the structural parameters of the obtained compound and the subsequent development of thermally-assisted electro-active areas has been systematically examined, as this compound has a fit composition for doping at the site of Co due to its relevantly equal atomic radius. Also, Mg was established as highly ferroelectric and low-weight material. The compound structure and microstructure have been analyzed using the method of scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The dielectric properties were studied over a broad spectrum of frequency and temperature, and quite low dielectric loss was recorded. In the context of impedance and conductivity formalism, frequency-dependent electrical information has been evaluated at varying temperatures. The Nyquist plot represents the effect of grain and grain boundary. Thermally activated non-Debye type relaxation processes were observed in the composites. Jonscher universal power law follows the frequency-dependent AC conductivity at different temperatures. Temperature dependence of AC conductivity at various frequencies indicates a negative temperature coefficient of resistance (NTCR) behavior. Estimating the magnitudes of activation energies in different temperature ranges enables defining the nature of the species involved in the conduction system.
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Introduction
In recent years, spinel ferrites have been extensively studied owing to their outstanding electrical and magnetic characteristics, which allows for wide applications range in systems of information storage, sensors, telecommunications devices, microwave absorbers, etc. [1]. Therefore, great attention has been given to the synthesis and characterization of spinel ferrite nanoparticles.
Many scientists have performed extensive research on the structural and magnetic characterization of nanosized spinal ferrites [2]. Due to their mechanical hardness, mild saturation magnetization, elevated electrical characteristics, elevated magneto-crystalline anisotropy, thermal stability, elevated magnetostriction coefficient, big coercive field, and anisotropy coefficient, cobalt ferrites with reverse spinel structure are very promising material among other ferrites [3,4,5]. Also, cobalt ferrites are very favourable for applications in electronics for magnetic stress sensors, gas sensors, and high-density information storage systems due to these notable characteristics [6,7,8]. Magnesium (Mg2+) is considered a non-magnetic object when the structural and magnetic characteristics are altered by the solid-state response technique in cobalt ferrite [9, 10].
The objective of this study is, therefore, to synthesize Mg2+ cobalt ferrite by the solid-state reaction technique and examine the structural and electrical characteristics of the resulted compound. Recently, the investigation of the temperature-dependent dielectric properties of Mg-doped CoFe2O4 nanoparticles revealed a fast rise in dielectric constant and dielectric loss with an increase in temperature.
The emphasis of the current study is to systematically examine the impact of Mg inclusion on the structural parameters at the Co-site, i.e., Co0.5Mg0.5Fe2O4 and the subsequent development of thermally-assisted electro-active areas, as this compound has a fit composition for doping at the site of Co due to its relevantly equal atomic radius. Also, Mg is highly ferroelectric and low-weight material.
Experimental Procedure
The sample of Mg-doped CoFe2O4 (Co0.5Mg0.5Fe2O4) was prepared by high-temperature solid-state reaction technique using high-purity stoichiometry ingredients. The material weighed stoichiometrically was carefully ground, first for 2 h in an air atmosphere and then for another 1 h in alcohol. Afterward, the mixed powders were calcined at an optimized temperature of 950°C for 4 h in an alumina crucible of high purity (air media).
The compound formation was verified using the method of X-ray diffraction (Rigaku, Ultima IV). Calcined powders were then ground with polyvinyl alcohol (PVA) to produce the pellet. The fine homogeneous powders were cold-pressed into a cylindrical pellet of 3 · 106 N/m2 using a hydraulic press. Next, these pellets were sintered at 1000°C in an air atmosphere for 4 h. Finally, the sintered pellets were polished with the emery paper to make both surfaces smooth and parallel.
For electrical measurements, the pellet faces were coated with a silver paste of high purity and dried at 100°C. Dielectric and impedance measurements were performed using an LCR meter (Impedance Analyzer, IM 3570).
Results and Discussion
Structural and Dielectric Study. The room temperature of Mg-doped cobalt ferrite (Co0.5Mg0.5Fe2O4) is shown on the XRD pattern in Fig. 1. The X-ray diffraction analysis confirmed the Cubic Spinel Structure with a lattice parameter of a = 0.840 nm [11]. The chosen unit cells’ grid parameters are refined using a conventional ‘POWD’ computer program package [12]. A strong agreement has been established found between observed (obs) and calculated (cal) interplanar spacing and is well aligned with interplanar spacing (∑△d = dobs – dcal = minimum). The crystallite size is roughly estimated from the expansion of XRD peaks (two wide ranges) using Scherer’s equation [13]: P = Kλ/((β(1/2) · cosθhkl), where K is a constant (K = 0.89), λ = 0.1540(5) nm, and λ(1/2) is the peak width of the reflection at half intensity. The average crystallite size (P) is 29 nm.
Figure 2 represents the scanning electron microscope image of Co0.5Mg0.5Fe2O4. The method of scanning electron microscopy (SEM) is very helpful for thorough research of the specimen surface. The interactions between the sample and the electron beam resulted in distinct types of electron signals being emitted during the scanning. The grains are spread more or less homogeneously with less porosity throughout the sample surface. The shape of the grains is spherical. The average size of the grain is 10 μm. It has been noted that the size of the grain is greater than the size of the crystallite acquired from Scherer’s equation. Thus, several crystallites can consist of a single grain.
Figures 3 show the variation of εr and tanδ with the temperature at different frequencies. It shows that the dielectric constant (εr) increases with an increase in temperature [14]. Besides, a dielectric anomaly is noted at higher temperatures. The dielectric constant variation relies on the alignment of the domain and these results in an increase in the dielectric constant. The tanδ values decreased with the rise in temperature [15], which can be due to the improvement of electrical conductivity.
Impedance Properties. The complex impedance analysis [16] is quite a well-known and powerful tool for investigating the material’s electrical (i.e., transportation) properties at a wide frequency range. This technique helps to measure the real and imaginary components of complex electrical parameters like impedance, modulus, etc.
Figure 4a shows the variation of real impedance (Z') on the frequency of Co0.5Mg0.5Fe2O4 at different temperatures. The entire curve merges in one frequency region at the high-frequency area, which may be due to the release of space charges polarization with increasing frequency [17]. The magnitude of Z' is observed to decrease with the rise in temperature, which shows a negative temperature coefficient of resistance (NTCR) behavior [18].
Figure 4b shows the frequency dependence of Z" on the frequency of Co0.5Mg0.5Fe2O4 at different temperatures. Thus, the plot peak is moved to a greater frequencies side with an increase in temperature. The peak widening changes with temperature variations indicate the presence of relaxation processes depending on the temperature in the material, which can be attributed to the existence of immobile species and greater deficiencies at low temperature [19]. The maximum width of the loss spectrum displays relaxation time distribution. The maximum expansion and asymmetric spectrum suggest the relaxation method in the material to be of non-Debye type. The bulk resistance and grain boundary resistance decrease with the temperatures rise (Table 1).
The variation between Z' and Z" values of the Co0.5Mg0.5Fe2O4 compound at selected temperatures is demonstrated in Fig. 5. This figure shows that the material electrical characteristics occur due to the contribution of grain as well as grain boundary effects. It also shows that the intercept point on the real axis changes the origin with the temperature increase, suggesting a decrease in the resistive property of the material [20]. It provides the materials with the bulk (Rb) and grain boundary (Rgb) resistance.
The complex electrical modulus formalism was introduced to study the suppressed electrode polarization effects and for a better insight into the electric relaxation. Figure 6a depicts the real (M') parts of electric modulus data plotted against the frequency of the Co0.5Mg0.5Fe2O4 compound. Real modulus M' approaches to zero at low frequency, and the existence of a long tail may be due to the impact of electrode polarization connected with the high double-layer capacitance. An asymmetric maximum is achieved at a greater frequency that confirms the presence of space charge polarization phenomenon [20].
When the frequency increases, the dispersion is noticed and saturation is reached at the very high values in the real part of the modulus. A continuous dispersion on increasing frequency may be contributed to the conduction phenomena due to the short-range mobility of charge carriers [21].
The variation of M” with Co0.5Mg0.5Fe2O4 frequency at different temperatures is shown in Fig. 6b. The M” value rises to a peak and then decreases as the frequency goes low. The frequency at which M” reaches a maximum is called the frequency of relaxation. The M'max peak shifts with temperature increase to the higher frequency side.
This behavior confirms the presence of relaxation involvement in the materials. It is noted that the temperature reliance of asymmetric peak expansion confirms the spread of relaxation with distinct time constants. Hence, the relaxation in the material is considered to be of non-Debye type [22].
The scaling behavior of Co0.5Mg0.5Fe2O4 is studied by plotting Z”/Z”max and M”/M”max against frequency at selected temperatures (100–150°C) (Fig. 7). Normally, these plots are used to detect the existence of the lowest capacity and the greatest resistance proposed by Sinclair et al. [23], which will assist to define the relaxation method whether charging carriers have a brief variety or lengthy range movement. The low-frequency part of the peak in the M"/M"max vs frequency curves is the range in which the charging carriers can move over a long distance. The charging carriers are confined spatially to their potential wells within the high-frequency range and could thus make localized motions within the well. The region of the peak occurrence is an indication of the longrange shift to short-range mobility with increased frequency [24].
Conductivity Examination. The frequency dependence of AC conductivity in Co0.5Mg0.5Fe2O4 at different temperatures is shown in Fig. 8. Based on the dielectric information, the AC conductivity was assessed using the relationship σac = ωε0εrtanδ. All AC conductivity graphs are well suited to the Johns Cher’s power-law [25], and solid lines represent the fitted curves. The solid lines in the AC conductivity spectra denote the fit of exponential data to the power law expression: σac= σ0 + Aωn, where A is a parameter which has the conductivity unit, n is a dimensionless parameter, and ω is the angular frequency at which the AC conductivity σac was measured. The temperature variation of n indicates the conductive mechanism type in the material [21]. The AC conductivity spectrum shows that the material systematically shows a steadily growing trend towards growing frequency.
However, a frequency-independent plateau-like area appears in the low-frequency spectrum as a comparative assessment of conductivity spectra, and consequently, the nature of AC conductivity rises with an increase in frequency. The value n is noted to increase linearly with a temperature of 100–150°C, which may be the consequence of the increase in electrode polarization with temperatures at all levels.
The value n is less than 1 for the translation motion, whereas the value of localized n is more than 1 [26]. If n < 1, charge carriers take a translational motion with a sudden hopping, while n > 1 would mean a localized hopping of the species (small hopping without leaving the neighborhood), and at n = 1 they behave like ideal capacitors [27]. Figure 8 shows that n is temperature-dependent, decreasing with an increase in temperature, which follows the small polaron model given in Table 2.
Figure 9 shows the variation of σac (bulk) with the inverse of absolute temperature 103/T (K–1) for Co0.5Mg0.5Fe2O4. As can be seen, the AC conductivity is found to be higher with the temperature rise. At high temperature, σac of the different frequency merges. Hence, the frequency-independent nature corresponds to DC conductivity in that region. The activation energy of Mg doped CoFe2O4 decreases with growing frequency within a temperature range of 50–150°C: Ea = 0.63, 0.61, and 0.60 eV at frequency of 1, 10, and 50 kHz, respectively. Thus, the activation energy is the total of energy engaged in generating charge carriers, but for polycrystalline-like products, the faults at greater temperatures can provide extra acceptor centers, which means that the process is thermally activated.
Conclusions
The polycrystalline Co0.5Mg0.5Fe2O4 sample was prepared by a solid-state reaction method at high temperature. The preliminary structural analysis confirmed the formation of the material with a cubic spinel structure at room temperature. The material exhibited a dielectric anomaly at high-temperature values. It has been established that the average grain sizes are within the range of 10 μm, which confirmed that the grains were bigger than the average crystallite sample. The Nyquist plot revealed the bulk and grain boundary effects in the materials. The AC conductivity study with frequency obeys the power law of the form σac = σ0 + Aωn, with n found to be in the range 0.79–0.92. The AC conductivity acquired from dielectric information exhibited electrical conductivity of the Arrhenius type and the value of Ea reduces as temperatures rise.
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Published in Poroshkova Metallurgiya, Vol. 59, Nos. 9–10 (535), pp. 32–40, 2020.
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Mohanty, D., Naik, A., Nayak, P. et al. Structural and Electrical Properties of Magnesium-Doped CoFe2O4. Powder Metall Met Ceram 59, 507–514 (2021). https://doi.org/10.1007/s11106-021-00190-9
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DOI: https://doi.org/10.1007/s11106-021-00190-9