Abstract
The examined method of processing cellulose can be used to conduct solid-phase EDA-complexation of cellulose with high-melting MMO hydrates in conditions of the effect of shear strains and pressure. The method allows: expanding the concentration range of the solubility of cellulose in MMO to 50% and obtaining highly concentrated spinning solutions with a concentration of up to 30%; decreasing the duration of dissolution to 5–10 min; regulating the process of thermal degradation of MMO and cellulose: fabricating “Orcel®” fibre with a high degree of orientation and high strength and modulus of elasticity. The solid-phase amine oxide method of processing cellulose was developed by the contract group at the All-Russian Scientific-Research Institute of Polymer Fibres (VNIIPV): Candidate L. K. Golova (director), candidate N. V. Vasil'eva, Candidate L. K. Kuznetsova. Candidate T. A. Lyubova, Research Associate O. E. Borodina, and Research Associate T. B. Krylova with the participation of leading specialists at the Institute's BI Center (director of the Center, Candidate I. Z. Eifer). The studies of the properties and structure of Orcel® fibre were conducted by leading specialists at the Institute's BIFIM Complex (Professor M. M. Iovleva. Director). Candidates V. N. Smirnova, S. I. Banduryan, T. A. Belousova, L. P. Mil'kova, I. N. Andreeva, L. P. Konovalova, V. G. Brusentsova, Dr. A. T. Kalashnik, Research Associate G. Ya. Rudinskaya, and Dr. A. Sh. Goikhman.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
N. Franks and J. K. Varga, U. S. Patent No. 4, 196,282 (1989).
H. Chanzy and A. Peguy, J. Polym. Sci., Polym. Phys.,18, No. 5, 1137–1141 (1980).
H. Chanzy, S. Nawrot, et al., J. Polym. Phys.,20, No. 10, 1909–1924 (1982).
B. Lukanoff and H. Schleicher, East German Patent No. 158,656 (1983); Chem. Abstr., 98217475s, CA.
W. Berger, Lenzinger Ber., No. 9, 11–18 (1994).
S. Davis, Chemiefas./Textilind.,39, No. 4, 347–348 (1989).
L. Vollbracht, Chemiefas./Textilind.,39, No. 9, 935–936, 938, 942 (1978).
A. Peguy and B. Dache, 33rd IUPAC Int. Symp. Macromol., Montreal (July), pp. 8–13.
W. B. Davidson, Am. Text.,15, No. 9, 26–27 (1986).
A. A. Kapkaev, Khim. Volokna., No. 2, 3–9 (1995).
C. Michels, R. Maron, and E. Taeger, Lenzinger Ber., No. 9, 57–61 (1994).
C. C. McCorsley and J. K. Varga, US Patent No. 4,142,913 (1979).
C. C. McCorsley, US Patent No. 414,080 (1979).
S. P. Papkov and V. G. Kulichikhin, Khim. Volokna, No. 2, 29–33 (1981).
V. G. Kulichikhin, Yu. Ya. Belousov, et al., Proceedings of the All-Union Seminar “Structure and Reactivity of Cellulose and Its Derivatives” [in Russian], Minsk (1982), pp. 27–29.
Yu. Ya. Belousov, N. V. Vasil'eva, et al., Khim. Volokna, No. 1, 32–33 (1981).
M. M. Iovleva, A. Sh. Goikhman, et al., Vysokomolek. Soedin.,B25, No. 11, 803 (1983).
E. G. Kogan, V. A. Platonov, et al., Khim. Volokna, No. 4, 30–32 (1984).
V. V. Romanov, N. P. Kruchinin, et al., Khim. Volokna, No. 6, 30–31 (1985).
L. K. Golova, V. G. Kulichikhin, and S. P. Papkov, Vysokomolek. Soedin.,A27, No. 9, 1795–1809 (1986).
T. A. Belousova, M. V. Shablygin, et al., Vysokomolek. Soedin.,A28, No. 5, 999–1005 (1986).
S. P. Papkov and I. P. Baksheev (eds.), Physicochemical Principles of Fabrication of Hydrated Cellulose Fibres by Nontraditional Methods [in Russian], Mytishchi (1989), p. 166.
L. K. Golova, T. P. Stepanova, et al., Khim. Drevesiny, No. 2, 33–37 (1987).
M. M. Iovleva, Vysokomolek. Soedin.,A31, No. 4, 808–812 (1989).
C. C. J. Culvenor and Ph. D. Phil, Rev. Pure Appl. Chem., No. 20, 20–23 (1953).
P. Navard and J. M. Haudin, J. Therm. Anal.,22, No. 1, 107–118 (1981).
L. K. Golova, O. E. Andreeva, et al., Vysokomolek. Soedin.,A28, No. 11, 2308–2312 (1986).
L. K. Golova, O. E. Borodina, et al., Khim. Volokna, No. 3, 30–32 (1987).
E. Taeger, C. Michels, and A. Nechwatal, Papier, No. 12, 784–788 (1991).
L. K. Golova, V. V. Romanov, and O. V. Lunina, Russian Federation Patent No. 1,645,308 (1992).
T. A. Akopova, S. Z. Rogovina, et al., Vysokomolek. Soedin.,B33, No. 10, 735–737 (1991).
S. Z. Rogovina, V. A. Zhorin, and N. S. Enikolopyan, J. Appl. Polym. Sci., No. 57, 439–447 (1995).
L. K. Golova, N. V. Vasil'eva, et al., in: Proceedings of the VIth International Conference on “Problems of Solvation and Complexation in Solutions [in Russian], No. 10, Ivanovo (1995).
M. M. Iovleva, V. N. Smirnova, et al., Vysokomolek. Soedin.,A28, No. 4, 749–752 (1986).
I. D. Zenkov, L. K. Golova, and O. E. Borodina, in: Proceedings of the All-Union Scientific Conference on Chemistry, Technology, and Use of Cellulose and Its Derivatives [in Russian], Suzdal' (1990). p. 233.
T. I. Borisova, N. V. Afanas'eva, et al., Vysokomolek. Soedin.,A35, No. 8, 1326–1331 (1993).
O. E. Borodina, L. K. Golova, et al., in: Proceedings of the VIth International Conference on Problems of Solvation and Complexation in Solutions [in Russian], No. 4, Ivanovo (1995).
R. M. Kolontyrskii, N. V. Vasil'eva, et al., in: Proceedings of the XVIIth Symposium Rheology-92 [in Russian], Dnepropetrovsk (1992). p. 109.
L. P. Braverman, V. V. Romanov, et al., Khim. Volokna, No. 6, 32–34 (1990).
H. Chanzy and A. Peguy, Paper and Textile Division, Houston (1980), p. 23.
P. Navard and J. Haudin, Brit. Polym. J.,12, No. 4, 174–176 (1980).
L. K. Golova and N. V. Vasil'eva, in: Proceedings of the IInd International Conference on Lyotropic Crystals [in Russian], Ivanovo (1993), p. 45.
L. K. Golova, N. V. Vasil'eva, et al., in: Proceedings of the IIIrd All-Russian Symposium on Liquid Crystalline Polymers [in Russian], Chernogolovka (1995), p. 72.
British Patent No. 8,216,566.
US Patent No. 4,246,221.
Additional information
All-Russian Scientific-Research Institute of Polymer Fibres, Mytishchi. Translated from Khimicheskie Volokna, No. 1, pp. 13–23, January–February, 1996.
Rights and permissions
About this article
Cite this article
Golova, L.K. Processing of cellulose via highly concentrated “solid solutions”. Fibre Chem 28, 5–16 (1996). https://doi.org/10.1007/BF01130691
Issue Date:
DOI: https://doi.org/10.1007/BF01130691