Abstract
Fe2O3–CaO–SiO2 glass ceramics containing nucleation agent P2O5/TiO2 were prepared by sol-gel method. The samples were characterized by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The activation energy and kinetic parameters for crystallization of the samples were calculated by the Johnson-Mehi-Avrami (JMA) model and Augis-Bennett method according to the results of DSC. The results showed that the crystallization mechanism of Fe2O3–CaO–SiO2 glass, whose non-isothermal kinetic parameter n = 2.3, was consistent with surface crystallization of the JMA model. The kinetics model function of Fe2O3–CaO–SiO2 glass, f(α) = 2.3(1–α)[–ln(1–α)]0.57, was also obtained. The addition of nucleation agent P2O5/TiO2 could reduce the activation energy, which made the crystal growth modes change from onedimensional to three-dimensional.
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Y. K. Lee, S. B. Lee, Y. U. Kim, et al., Mater. Sci. 38, 4221 (2003).
M. Miho, Lab. Invest. 23, 176 (2004).
M. Akihiko and K. Katsuyuki, Clin. Exp. Metastasis 24, 191 (2007).
Y. Y. Wang, B. Li, and Y. Y. Wang, Appl. Mech. Mater. 624, 114 (2014).
M. Baikousi, S. Agathopoulos, and I. Panagiotopoulos, J. Sol-Gel Sci. Tech. 47, 95 (2008).
M. Kamal, I. K. Battisha, and M. A. Salem, J. Sol-Gel Sci. Tech. 58, 507 (2011).
A. A. S. Lopes, R. C. C. Monteiro, and R. S. Soares, J. Alloys Compd. 591, 268 (2014).
M. Ghasemzadeh, A. Nemati, and A. Nozad, Ceramics-Silikaty 55, 188 (2011).
E. J. C. Davim, A. M. R. Senos, and M. H. V. Fernandes. J. Therm. Anal. Calorim. 117, 643 (2014).
A. Arora, E. R. Shaaban, and K. Singh, J. Non-Cryst. Solids 354, 3944 (2008).
G. C. Kang. J. Mater. Sci. 36, 1043 (2001).
G. O. Piloyan, I. D. Rybachikov, and O. S. Novikov, Nature 212, 1229 (1966).
H. E. Kissinger, Anal. Chem. 29, 1702 (1957).
J. C. Qiao and J. M. Pelletier, J. Non-Cryst. Solids 357, 2590 (2011).
N. Khair and M. A. Chaudhry, J. Mater. Sci. 48, 1368 (2013).
S. D. Stookey, Ind. Eng. Chem. 51, 805 (1959).
A. M. Hu, K. M. Liang, G. Wang, et al., J. Therm. Anal. Calorim. 78, 991 (2004).
P. E. Doherty, D. W. Lee, and R. S. Davis, Am. Ceram. Soc. 50, 7781 (1967).
J. W. Cao, Y. H. Li, and K. M. Liang, Adv. Appl. Ceram. 108, 352 (2009).
W. A. Johnson and R. F. Mehl, Trans. Am. Inst. Min. Metall. Pet. Eng. 135, 416 (1939).
M. J. Avrami, J. Chem. Phys. 7, 1103 (1939).
M. A. Gabal, Thermochim. Acta 402, 199 (2003).
P. Budrugeac and E. Segal, J. Therm. Anal. Calorim. 82, 677 (2005).
A. W. Coats and J. P. Redfern, Nature 201, 68 (1964).
B. Jankovic and S. Mentus, Metall. Mater. Trans. A 40, 609 (2009).
J. A. Augis and J. E. Bennett, J. Therm. Anal. 13, 283 (1978).
K. Matusita, T. Komatsu, and R. Yokota. J. Mater. Sci. 19, 291 (1984).
G. Baldi, E. Generali, C. Leonelli, T. Manfredini, G. C. Pellacani, and C. Siligardi, J. Mater. Sci. 30, 3251 (1995).
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Li, B., Wang, Y., Luo, W. et al. Non-isothermal crystallization kinetics of Fe2O3–CaO–SiO2 glass containing nucleation agent P2O5/TiO2 . Crystallogr. Rep. 62, 260–264 (2017). https://doi.org/10.1134/S1063774517020080
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DOI: https://doi.org/10.1134/S1063774517020080