Abstract
The thermochemical properties of melts of the binary Gd–In system were studied by the calorimetry method at 1470–1700 K over the whole concentration interval. It was shown that significant negative heat effects of mixing are characteristic features for these melts. Using the ideal associated solution (IAS) model, the activities of components, Gibbs energies and the entropies of mixing in the alloys of this systems and its phase diagram were calculated. They agree with the data from literature.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
S. P. Yatsenko, Indium. Properties and Application (Nauka, Moscow, 1987) [in Russian].
Y. Wei, X. Su, F. Yin, Z. Li, X. Wu, and C. Chen, J. Alloys Compd. 333, 118 (2002).
F. Gao, S. L. Wang, C. P. Wang, and X. J. Liu, CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 35, 1 (2011).
V. V. Berezutskii, M. I. Ivanov, M. A. Shevchenko, and V. S. Sudavtsova, Powder Metall. Met. Ceram. 53, 693 (2015).
Y. Zhuang, S. Yuan, and J. Zheng, Acta Phys. Sin. (China) 31, 121 (1982).
A. A. Semyannikov and S. P. Yatsenko, in Synthesis and Properties of Rare Earth Element Compounds, Ed. by V. G. Bomburov (Akad. Nauk SSSR, Ural. Nauch. Tsentr, Sverdlovsk, 1982), p. 123 [in Russian].
S. Delfino, A. Saccone, and R. Ferro, Z. Metallkd. 74, 674 (1983).
A. Palenzona and S. Cirafici, Bull. Alloy Phase Diagrams 10, 234 (1989).
E. N. Dieva, Tr. Inst. Khim., Ural. Nauch. Tsentr AN SSSR 29, 98 (1974).
S. P. Vdovkina, V. A. Degtyar, L. A. Vnuchkova, and V. V. Serebrennikov, Tr. Tomsk. Univ., No. 249, 143 (1973).
A. P. Bayanov, Yu. A. Afanas’ev, and N. M. Pogorel’skaya, Zh. Fiz. Khim. 47, 2105 (1973).
Din Khue Wu, V. P. Vasil’ev, and V. P. Gerasimov, in Proceedings of the All-Union Conference on Calorimetry and Chemical Thermodynamics, Ivanovo, Sept. 25–27, 1979.
V. I. Kober, I. F. Nichkov, S. P. Raspopin, and V. M. Kuz’minykh, The Rare Metals Alloys with Special Properties: Rare-Earth and Precious Metals, Ed. by E. M. Savitskii (Nauka, Moscow, 1983), p. 132 [in Russian].
A. Palenzona and C. Cirafici, Thermochim. Acta 9, 419 (1974).
S. V. Meschel and O. J. Kleppa, J. Alloys Compd. 337, 115 (2002).
V. A. Lebedev, Thermochemistry of Alloys of Rare Earth and Actinide Elements, Reference Book, Ed. by V. A. Lebedev, V. I. Kober, and L. F. Yamshchikov (Metallurgiya, Chelyabinsk, 1989) [in Russian].
Binary Alloy Phase Diagrams, Ed. by T. B. Massalski, 2nd ed. (ASM International, Metals Park, OH, 1990).
B. Predel, in Landolt–Börnstein, New Series, Vol. IV/5 (1996).
V. P. Vassiliev, A. Benaissa, and A. F. Taldrik, J. Alloys Compd. 572, 118 (2013).
M. Ivanov, V. Berezutski, and N. Usenko, J. Mater. Res. 102, 277 (2011).
A. T. Dinsdale, CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 15, 319 (1991).
V. G. Kudin, M. A. Shevchenko, I. V. Mateiko, and V. S. Sudavtsova, Zh. Fiz. Khim. 87, 364 (2013).
M. A. Shevchenko, M. I. Ivanov, and V. V. Berezutskii, V. G. Kudin, and V. S. Sudavtsova, Russ. J. Phys. Chem. A 88, 897 (2014).
V. S. Sudavtsova, M. A. Shevchenko, V. V. Berezutskii, M. I. Ivanov, and V. G. Kudin, Russ. J. Phys. Chem. A 88, 200 (2014).
M. A. Shevchenko, V. G. Kudin, and V. S. Sudavtsova, in Modern Problems of Physical Materials Science, Tr. Inst. Prikl. Mat. (IPM im. Frantsevicha NANU, Kiev, 2012), Vol. 21, p. 67 [in Russian].
G. Kaptay, Metall. Mater. Trans. A 43, 531 (2012).
F. R. de Boer, R. Boom, W. C. M. Mattens, A. R. Miedema, and A. K. Niessen, in Cohesion and Structure, Ed. by F. R. de Boer and D. G. Pettifor (North–Holland, Amsterdam, 1988).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.A. Shevchenko, M.I. Ivanov, V.V. Berezutski, V.S. Sudavtsova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 1, pp. 3–12.
The article was translated by the authors.
Rights and permissions
About this article
Cite this article
Shevchenko, M.A., Ivanov, M.I., Berezutski, V.V. et al. Thermodynamic properties of alloys of the binary Gd–In system. Russ. J. Phys. Chem. 90, 1–10 (2016). https://doi.org/10.1134/S0036024415120274
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024415120274