Abstract
The thermochemical properties of melts of the binary In–Yb system were studied by the calorimetry method at 1160–1380 K over the whole concentration interval. It was shown that significant negative heat effects of mixing are characteristic features for these melts. Using the ideal associated solution (IAS) model, the activities of components, Gibbs energies and the entropies of mixing in the alloys, and the phase diagram of this system were calculated. They agree with the data from literature.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
S. P. Yatsenko, Indium Properties and Applications (Nauka, Moscow, 1987) [in Russian].
Y. Wei, X. Su, F. Yin, Z. Li, X. Wu, and C. Chen, J. Alloys Compd. 333, 118 (2002).
V. V. Berezutskii, M. I. Ivanov, M. A. Shevchenko, and V. S. Sudavtsova, Powder Metall. Met. Ceram. 53, 693 (2015).
O. D. McMasters, C. L. Nipper, and K. A. Gschneidner, J. Less-Common Met. 23, 253 (1971).
S. Cirafici and M. L. Fornasini, J. Less-Common Met. 154, 79 (1989).
A. Palenzona and S. Cirafici, Bull. Alloy Phase Diagrams 10, 588 (1989).
Binary Alloy Phase Diagrams, Ed. by T. B. Massalski, 2nd ed. (ASM Int., Metals Park, OH, 1990).
F. Gao, S. L. Wang, C. P. Wang, and X. J. Liu, CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 35, 1 (2011).
E. N. Dieva, Tr. Inst. Khim., Ural. Nauch. Tsentr AN SSSR 29, 98 (1974).
Thermochemistry of Alloys of Rare-Earth and Actinide Elements, The Handbook, Ed. by V. A. Lebedev, V. I. Kober, and L. F. Yamshchikov (Metallurgiya, Chelyabinsk, 1989) [in Russian].
A. Palenzona and C. Cirafici, Thermochim. Acta 9, 419 (1974).
S. P. Yatsenko, A. A. Semyannikov, H. O. Shakarov, and E. G. Fedorova, J. Less-Common Met. 90, 95 (1983).
S. Delfino, A. Saccone, and R. Ferro, J. Less-Common Met. 102, 289 (1984).
V. P. Vassiliev, A. Benaissa, and A. F. Taldrik, J. Alloys Compd. 572, 118 (2013).
M. Ivanov, V. Berezutski, and N. Usenko, J. Mater. Res. 102, 277 (2011).
A. T. Dinsdale, CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 15, 319 (1991).
V. G. Kudin, M. A. Shevchenko, I. V. Mateiko, and V. S. Sudavtsova, Zh. Fiz. Khim. 87, 364 (2013).
M. A. Shevchenko, M. I. Ivanov, V. V. Berezutskii, V. G. Kudin, and V. S. Sudavtsova, Russ. J. Phys. Chem. A 88, 897 (2014).
V. S. Sudavtsova, M. A. Shevchenko, V. V. Berezutskii, M. I. Ivanov, and V. G. Kudin, Russ. J. Phys. Chem. A 88, 200 (2014).
M. A. Shevchenko, V. G. Kudin, and V. S. Sudavtsova, in Modern Problems of Physical Science of Materials, Tr. IPM (Inst. Probl. Materialoved. I. M. Frantsevicha, Kiev, 2012), No. 21, p. 67 [in Russian].
G. Kaptay, Metall. Mater. Trans. A 43, 531 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.A. Shevchenko, M.I. Ivanov, V.V. Berezutski, V.S. Sudavtsova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 5, pp. 649–658.
The article was translated by the authors.
Rights and permissions
About this article
Cite this article
Shevchenko, M.A., Ivanov, M.I., Berezutski, V.V. et al. Thermodynamic properties of alloys of the binary In–Yb system. Russ. J. Phys. Chem. 90, 893–902 (2016). https://doi.org/10.1134/S0036024416050289
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024416050289