Abstract
By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
D. Aulakh, J. R. Varghese, and M. Wriedt. Inorg. Chem., 2015, 54, 8679.
Y. Lo, C. H. Lam, C.-W. Chang, A.-C. Yang, and D.-Y. Kang. RSC Adv., 2016, 6, 89148.
T. Tanasaro, K. Adpakpang, S. Ittisanronnachai, K. Faungnawakij, T. Butburee, S. Wannapaiboon, M. Ogawa, and S. Bureekaew. Cryst. Growth Des., 2018, 18, 16.
T. K. Koltunova, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. J. Struct. Chem., 2017, 58, 1048.
M. O. Barsukova, S. A. Sapchenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Rev., 2018, 87, 1139.
P. A. Demakov, S. A. Sapchenko, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Bull. (Int. Ed.), 2018, 67, 490.
M. Yu, S.-X. Liu, L.-H. Xie, R.-G. Cao, and Y.-H. Ren. Acta Cryst. Sec. E, 2007, 63, 1889.
Y.-J. Kim. and D.-Y. Jung. Chem. Commun., 2002, 8, 908.
G. Tian, G. Zhu, B.-L. Su, and S. Qiu. J. Mater. Sci., 2009, 44, 6576.
J. Lu, W. Bi, and R. Cao. CrystEngComm, 2009, 11, 2248.
K. P. Rao, A. Thirumurugan, and C. N. R. Rao. Chem.-Eur. J., 2007, 13, 3193.
J. Lu, W.-H. Bi, F.-X. Xiao, S. R. Batten, and R. Cao. Chem.-Asian J., 2008, 3, 542.
CrysAlisPro 1.171.38.41. Rigaku Oxford Diffraction, 2015.
G. M. Sheldrick. Acta Crystallogr., 2015, A71, 3–8.
G. M. Sheldrick. Acta Crystallogr., 2015, C71, 3–8.
Y. Guo, J. Zhang, L.-Z. Dong, Y. Xu, W. Han, M. Fang, H.-K. Liu, Y. Wu, and Y.-Q. Lan. Chem.-Eur. J., 2017, 23, 15518.
G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, and I. Margiolaki. Science, 2005, 309, 2040.
G. Zahn, P. Zerner, J. Lippke, F. L. Kempf, S. Lilienthal, C. A. Schröder, A. M. Schneider, and P. Behrens. CrystEngComm., 2014, 16, 9198.
Z. Hu, I. Castano, S. Wang, Y. Wang, Y. Peng, Y. Qian, C. Chi, X. Wang, and D. Zhao. Cryst. Growth Des., 2016, 16, 2295.
R.-Z. Zhang, Y.-Q. Huang, W. Zhang, and J.-M. Yang. CrystEngComm., 2018, 20, 5672.
Author information
Authors and Affiliations
Corresponding author
Additional information
Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 5, pp. 849-856.
Rights and permissions
About this article
Cite this article
Demakov, P.A., Sapchenko, S.A., Samsonenko, D.G. et al. Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements. J Struct Chem 60, 815–822 (2019). https://doi.org/10.1134/S0022476619050159
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476619050159