Abstract
We describe the results of the X-ray diffraction study of a dysprosium(III) complex with trihydrazone of 3-methyl-1-phenyl-4-formylpyrazole-5-one and 1,3,5-benzenetricarboxylic acid, as well as a heteroligand gadolinium(III) complex with tri- and dihydrazone of 3-methyl-1-phenyl-4-formylpyrazole-5-one and 1,3,5-benzenetricarboxylic acid (H3L and H3L1 respectively). It is determined that the homoligand complex of dysprosium has a M4L4 composition and a pseudotetrahedral structure in which metal ions occupy vertices of a trigonal pyramid and trinucleating ligands are located on its sides. The heteroligand gadolinium complex Gd3(L)(HL1)3 has a trigonal structure. Metal ions at the triangle vertices are linked by a trinucleating ligand located above the triangle plane, and three binucleating ligands link the central atoms in pairs. The geometry of dysprosium and gadolinium coordination polyhedra correspond to a three-capped trigonal prism.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
D. L. Caulder and K. N. Raymond. J. Chem. Soc. Dalton Trans., 1999, 1185.
V. F. Shul’gin, Z. Z. Bekirova, O. V. Konnik, S. B. Meshkova, A. V. Kiriyak, G. G. Aleksandrov, and I. L. Eremenko. Rus. J. Inorg. Chem., 2014, 59, 441.
V. F. Shul’gin, Z. Z. Bekirova, O. V. Konnik, S. B. Meshkova, A. V. Kiriyak, G. G. Aleksandrov, and I. L. Eremenko. Rus. J. Coord. Chem., 2014, 40, 396.
O. V. Konnik, Z. Z. Bekirova, V. F. Shul’gin, S. B. Meshkova, P. G. Doga, S. S. Smola, G. G. Aleksandrov, and I. L. Eremenko. Rus. J. Inorg. Chem., 2014, 59, 308.
Y. Liu, Z. Lin, C. He, L. Zhao, and C. Duan. Dalton Trans., 2010, 39, 11122.
C. He, Z. Lin, Z. He, C. Duan, C. Xu, Z. Wang, and C. Yan. Angew. Chem. Int. Ed., 2008, 47, 877.
X. Wu, Z. Lin, C. He, and C. Duan. New J. Chem., 2012, 36, 161.
SMART (Control) and SAINT (Integration) Sofware, Version 5.0, Bruker AXS Inc., Madison (WI), 1997.
G. M. Sheldrick. Acta Crystallogr., 2008, A64(1), 112–122.
A. L. Spek. Acta Crystallogr., 2009, D65(2), 148–155.
F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. Taylor. J. Chem. Soc. Perkin Trans. 2, 1987, 12, S1.
H. Fenton, I. S. Tidmarsh, and M. D. Ward. Dalton Trans., 2009, 4199.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shul’gin, V.F., Baluda, Y.I., Gusev, A.N. et al. Coordination Compounds of Lanthanides with Hydrazones of 3-Methyl-1-Phenyl-4-Formylpyrazole-5-One and 1,3,5-Benzenetricarboxylic acid. J Struct Chem 60, 494–500 (2019). https://doi.org/10.1134/S0022476619030193
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476619030193