Abstract
An increasing number of commercial polymer products is derived from blending two or more polymers to achieve a favorable balance of physical properties. As described in Chapter 2 of this Handbook, from the thermodynamic point of view there are two basic types of polymer blends: miscible and immiscible. The vast majority of polymer pairs are immiscible with one another. There are only few commercially important polymer blends based on miscible and partially miscible (i.e., miscible within a low range of concentration) polymer pairs. It is seldom possible to mix two or more polymers and create a blend with useful properties. Instead, when preparing a new polymer blend from immiscible resins, it is necessary to devise a specific strategy for compatibilizing the mixture to provide for optimum physical performance and long-term stability. Although there do exist a very small number of commercial blends of immiscible polymers that are not compatibilized, most commercially available blends of immiscible polymers have been compatibilized by some specific mechanism.
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Notes
- 1.
The references below are listed in alphabetical order by first author, then by second author, etc. If the same authors are present, the reference is listed by date with most recent first. If similar authors and the same year, then the reference is listed by year followed by a letter in alphabetical order.
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Brown, S.B. (2003). Reactive Compatibilization of Polymer Blends. In: Utracki, L.A. (eds) Polymer Blends Handbook. Springer, Dordrecht. https://doi.org/10.1007/0-306-48244-4_5
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DOI: https://doi.org/10.1007/0-306-48244-4_5
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