Abstract
The corrosion resistance of an aluminium alloy (AA 6351) reinforced with nano-Silicon Carbide particles and various weight ratios of nano-Zirconium dioxide particles is explored in this study. AA6351–nanoSiC (5 wt%) composites were treated using powder metallurgy to add nanoZrO2 (3–9 wt% in steps of 3%) to the composition. Electrochemical polarisation measurements assessed the effect of nano-Zirconium dioxide reinforcement on corrosion behaviour in a 3.5% sodium chloride solution. The Tafel method calculated the corrosion rate and the achieved polarisation results. Thus, according to findings, adding more nano-Zirconium dioxide particles into the aluminium alloy (6351) +5% SiC matrix increase corrosion resistance and decrease corrosion rate.
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Introduction
Due to their future use in automobiles, ships, offshore constructions, and marine environments [1, 2], a small number of aeroplanes, helicopters, and spacecraft-spatial framework [3, 4] and LNG carriers and pressure vessels, aluminium alloy composites are valuable materials. Recent studies were intrigued by aluminium metal matrix composites because they coupled strong corrosion resistance with strength, low density, low wear rate, good thermal stability and a minimal cost of production [5]. The alignment and dispersion of the reinforced particles, as well as manufacturing methods such as stir casting, squeeze casting, ultrasonic-assisted stir casting, and powder metallurgy [6, 7], all significantly affect the physical and mechanical properties of the aluminium metal matrix composite. The particulate reinforcements are most favourable due to the reduction in nano-size from micro-size particles, allowing for improved morphological, physical, and mechanical characteristics. Al2O3 [8], Graphite, B4C [9], MWCNT [7], SiC [5, 10, 11], TiB2 [12,13,14], TiC [15, 16], ZrO2 [17], Flyash [18], AlN[19], ZrB2, and Si3N4 are currently widely utilised as reinforcement to the base material in a bid to enhance mechanical characteristics. Due to its potential to produce products with a near-net-like form and its ability to achieve a good degree of reinforcing homogeneity in the composite material, powder metallurgy garnered the most interest amongst the many fabrication techniques for AMCs. As a result, the expensive manufacturing operations are reduced, which makes the production process cost-effective [17].
A better alternative to mono-reinforced composites, hybrid composites enhanced with a blend of micro-, nano-sized or nano–nano-sized particles, had additionally drawn scientific study focus [13]. This is owing to their superior physicomechanical characteristics. Nanosized particles empower the matrix function better because of the Orowan strengthening process.
Using traditional powder metallurgy procedures, the effects of Silicon Carbide grain size (11, 6, and 3 µm) and volume fraction (up to 15% vol%) on the microstructure and corrosion behaviour of Aluminium metal matrix composite strengthened by silicon carbide were investigated by Zakaria [20]. The corrosion rate of the Aluminium MMC reinforced with SiC is reduced by decreasing the grain size and/or raising the percentage volume of silicon carbide grains. At 50 and 75 °C, the composite samples corroded faster than the pure Aluminium.
The corrosion properties were tested on Al7075/Tic and [21] Al6061/SiC with 10 and 20 wt% particles by the Tafel method—one of the electrochemical analyses in a 3.5 M sodium chloride medium. The specimen's microstructure displayed pits, and pits grew as NaCl concentration increased [16].
Thiagarajan et al. [22] investigated the WEDM process parameters of Al6061-reinforced composites made of nanoSic and nanoZrO2 through stir casting. The aluminium matrix was strengthened with hybrid nano-powders, producing a tough material. Zirconia (ZrO2) nanoparticles offer excellent reinforcement for aluminium matrices due to their physical, mechanical, and wear properties. The blend of micro- and nanoSiC (5 wt%) and nano-Zirconia with various weight percentages (3, 6, and 9) is analysed for improving the tribological and mechanical characteristics of aluminium matrices [14, 23, 24] by powder metallurgy technique. The wear surface of pure aluminium and hybrid composites was analysed using Scanning electron microscopy and ANOVA.
[25] Investigated the corrosion resistance by salt spray corrosion test according to ASTM B117 observed for one day in NaCl (3.5%) solution on samples of AA6061 reinforced with TiB2 particles (2.5–7.5 wt% in steps of 2.5) produced by an in-situ process. The corrosion rate decreases, or corrosion resistance increases with an increase in TiB2 particles. The optimum corrosion rate of 1.4815 miles/ year is obtained for AA6061/TiB2 at 7.5 wt% TiB2.
The corrosion rate of Al6061 alloy and its composite with reinforcements are distinguished by two approaches—weight loss and electrochemical methods in acid and neutral chloride medium [26,27,28]. There is a slight difference between the corrosion rates obtained by the two approaches because the composite was exposed to the electrolyte for longer when weight loss measurements were made [28].
Karthikeyan [29] studied the corrosion properties of the Aluminium alloy 8011 strengthened with TiC (10 and 20 wt%) Gr (1 &2 wt%) through electrochemical methods like OCP, cyclic polarisation resistance and EIS, and observed that the corrosion rate decreases with increased TiC, whereas adding Graphite reduces the corrosion resistance. [30] Studied the potentiodynamic polarisation technique for calculating the corrosion resistance of an alloy of aluminium alloy 2024 reinforced with ZrO2 nanoparticles of varied weight percentages (0, 2, 4 and 6%) prepared by Stir casting. Including ZrO2 nanoparticles greatly improves the corrosion resistance of the aluminium metal matrix composite in a seawater environment.
Joel Hemanth et al. [31]: probed the corrosion behaviour of NanoZirconia of particle size 100–200 nm reinforced with LM-13 composites in a 3.5% NaCl solution by electrochemical method for aerospace application. Due to the nanoscale zirconia in ZrO2, the findings at 3, 6, 9 and 12 weight percent show that these composites have superior corrosion resistance than LM-13 alloy.
Prasannanagasai et al. [32] developed AA 7075 reinforced ZrO2 particles (2 and 4 wt%) made by stir casting to examine the wear, mechanical, and electrochemical corrosion properties. Due to the excellent bonding of the ZrO2 reinforcement in AA 7075 alloy, corrosion resistance is enhanced at 2 and 4 wt% ZrO2 reinforced composites.
Sukriti Yadav [33] investigated the mechanical and corrosion characteristics of the hybrid aluminium nanocomposites reinforced with 1–3 weight percent of each silicon carbide, graphite, and ZrO2 through a stir casting technique. Aluminium reinforced with one wt% each of SiC/ZrO2/Gr, i.e. at 3 wt%, was analysed in 3.5% NaCl solution at ambient temperature by the Tafel method had the maximum corrosion resistance.
In addition to being inexpensive and readily available, zirconium dioxide is a mineral metal oxide with excellent fracture toughness and wear properties. After reviewing the relevant literature, no detailed dissertation on nanoZrO2-strengthened AA6351 and nano-silicon carbide composites fabricated via the powder metallurgy method is available. Hence, powder metallurgy is utilised to develop hybrid aluminium nanometal matrix composites for hull structures, bicycle frames, and marine and aerospace applications. The microstructural analysis of samples has been performed, and the corrosion behaviour of nanohybrid SiC+ZrO2 aluminium alloy composites has been investigated by the electrochemical(Tafel) method in 3.5% NaCl solution.
Experimental Details
Fabrication of Composites
Aluminium alloy (6351) (Parshwamani metals, Mumbai), silicon carbide, and zirconium dioxide powders (Nano-Research laboratories, India) with average sizes of 70–80 μm and 30–50 nm particles, respectively, were acquired. Figure 1a–d displays the SEM images of the particles as they were received. For the study, the composition, as mentioned below, of nanocomposites is concocted using the powder metallurgy method.
S. No | Sample | Composition (wt%) | ||
---|---|---|---|---|
AA | SiC | ZrO2 | ||
1) | SAZ1 | 100 | 0 | 0 |
2) | SAZ2 | 95 | 5 | 0 |
3) | SAZ3 | 92 | 5 | 3 |
4) | SAZ4 | 89 | 5 | 6 |
5) | SAZ5 | 86 | 5 | 9 |
Initially, the weight of the enlisted powders was computed with a digital balance (AS R220 plus, Swiss Manufactured, ES 225SM-DR) with a minimum count of 0.1 mg. A preset quantity of nanoSiC (3.21 g/cm3), nanoZrO2 (5.68 g/cm3), and aluminium alloy 6351 powder (2.71 g/cm3) was profoundly blended Using a planetary ball mill (VBCRC, Chennai) with steel balls of dia 8 mm, and a 10:1 BPR was used to reduce the agglomeration of composite powders during blending for 30 min at a speed of 125 rpm. The characterisation of these milled blended powders is conducted on XRD (Bruker D8) to know the presence of various elements in each blend, functioning with a wavelength of 1.5418 Å using CuKα X-rays at 30 kV with a range (2θ) of 20°–80° and 0.02° step size. The obtained graph was validated with Match! Software. [17]. Pellets with a size of 13 mm dia and 5 mm thick were produced at a rate of 3 tonnes utilising a 20-tonne automated hydraulic pellet press (VBCRC, Chennai) for the sintering operation muffle furnace (VBCRC, Chennai). To ensure good die operation, the die surface was manually wiped and greased with zinc stearate for every compression process. The specimens were sintered at 550 °C for 1 h in a muffle furnace and cooled to room temperature in the furnace chamber.
Sample Preparation for Microstructure
The samples were sequentially ground, polished, etched, and examined under an optical microscope. Wet grinding with water uses SiC emery paper with different grits (220, 320, 500, and 1000). The sample is thoroughly cleaned to remove any remaining grit and swart before changing each grit and polishing paper. Polishing is carried out on a rotating wheel with select cloth and alumina powder in grades ranging from 1 to 2 µm. The sample is polished until it has a mirror finish. Polishing leaves a thin layer of amorphous metal on the sample's surface. This layer is known as the flowed layer, and it covers deep scratches, cavities, small non-metallic particles, and the sample's proper structure. The flowed layer can be removed entirely by etching when the etching process is done to the samples using an etchant of 99% H2O +1%HF. The suitability of its polishing surface is observed on a microscope before it is processed further to etching to get exemplary microstructures. Leica Microscope was used to inspect the samples optically and sample images for corrosion are shown in Fig. 5a–e.
Electrochemical Testing Method
Corrosion studies were conducted in Sodium chloride salt solution using approximately 13 mm diameter and 5 mm thick Aluminium alloy6351 and hybrid aluminium nano-metal matrix composite samples as shown in Fig. 3. Before the corrosion test, all five samples were polished with emery sheets of various grades until the samples had a mirror surface finish. The electrochemical corrosion test uses Vertex. C (IVIUM) workstations. The setup of the electrochemical test consists of aluminium alloys as working electrodes with a cross-sectional area of 1.0 cm2, Ag/AgCl as an electrode for reference, and a thin platinum wire as an auxiliary electrode. As shown in Fig. 2, functional electrodes were developed by coupling an insulated copper wire to one side of the specimen by sealing it with aluminium conducting tape and cold mounting it in epoxy resin. The electrode arrangements are as per ASTM G 102 standards [34].
Results & Discussion
X-ray Diffraction
Figure 3 shows the XRD pattern of the sample powders-SAZ2 (AA 6351 +5 wt%SiC), SAZ3 (AA 6351 +5 wt%SiC+3 wt%ZrO2), SAZ4(AA 6351 +5 wt%SiC+6 wt%ZrO2) and SAZ5 (AA 6351 +5 wt%SiC+9 wt%ZrO2) prepared by planetary ball mill for 30 minutes. The Aluminium peak is the largest observed at 38.45°. The XRD graph of the samples is valid with Match Software with Crystallography Open Database-CIF (crystallography information file) 9010158 for SiC [35], 1502689 for Aluminium [36] and 5000038 for ZrO2 [37]. X-ray Diffraction analysis reveals the peaks and phases of Aluminium, SiC and ZrO2 combinations which is good agreement with the literature [24]. Figure 4 illustrates the energy dispersive spectroscopy (EDS) investigation of the produced composite. The EDS analysis reveals distinct peaks corresponding to elements such as Aluminium, Silicon, Zirconium, Magnesium, Zinc, C, Fe, and O, Cu and Ti all of which are discernible in the depicted graph (Fig. 5), which confirms the homogeneous dispersion of the nanohybrid reinforcements (SiC and ZrO2) in
Tafel Plot
Electrochemical tests include potentiostatic holds, cyclic anodic polarisation, and open circuit potential monitoring. Figure 6 displays the Tafel polarisation curves for AA6351 and hybrid aluminium nanocomposite reinforced with nanoSiC and various weight percentages of zirconium dioxide nanoparticles 3–9 wt% in steps of 3 wt% in a 3.5% sodium chloride medium. These graphs show that the corrosion behaviour of all samples in a 3.5% NaCl solution exhibits identical cathodic and anodic polarisation curves. However, the five samples' corrosion current density and potential (SAZ1, SAZ2, SAZ3, SAZ4, and SAZ5) varied. In a different cell, open circuit potential observations were made for 20 min. The potentiodynamic polarisation behaviour of aluminium alloys in the potential range of − 1 to + 1.5 V s at room temperature is obtained using a sweep rate of 10 mV/sec to calculate the corrosion current density, corrosion potential and the corrosion rate (CR). The polished specimens were sterilised with water and acetone to eliminate any possible surface elements that could have deposited and influenced the measurement after each experiment, and the electrolyte was replenished. After finding signs of the initial pitting on the potentiodynamic curve, the testing was halted.
The Tafel curves were produced using the log of the corrosion current density to the potential. A linear zone has been seen in the tafel extrapolation close to the Ecorr on both the cathodic and anodic extremities. The Tafel constants βa and βc represent the slopes of the linear regions. These linear zones are extrapolated until they cross to produce Ecorr [26]. Corrosion current density is determined by the log Icorr values at the coordinates' intersection. Figure 6 shows the Tafel polarisation curves of the all the five samples (SAZ1-aluminium alloy 6351, SAZ2-aluminium alloy reinforced with nanoSiC and SAZ3, SAZ4, SAZ5-hybrid nanocomposites made from the base metal alloy AA 6351 and 5 wt% nanoSiC and nanoZrO2) in 3.5 wt%NaCl solution. The Tafel curves demonstrate that a hybrid composite's corrosion rate descends as the weight percentage of nanozirconia accelerates. Compared to three weight percent nanoZrO2, the hybrid composite's Tafel plot at nine wt% nanoZrO2 exhibits the steepest anodic slope and lower Icorr current; hence, it is corrosion resistant. The electrochemical variables such as anodic and cathodic slope (Volts/Decade), corrosion current density, corrosion potential, Rp Polarisation resistance (Ω cm2) and Corrosion rate (mpy or mm/yr) are obtained from the Tafel extrapolation curve as depicted in Table 1. This illustrates that with the increase in nano-ZrO2 from 3 to 9 wt% in the AA6351/SiC, the corrosion rate descends from 0.7440 to 0.1331 mm/yr or 29.333 to 5.2451 mpy as depicted in Fig. 7, and thus, SAZ5 has excellent resistance to corrosion in 3.5% sodium chloride solution. Zirconia and SiC are inert ceramic particles that the corrosion may scarcely impact, which may explain the enhanced corrosion resistance.
Computation of Rate of Corrosion
where CR is mm/year or mils/ year, Icorr (corrosion current density (µA/cm2)) is the ratio of the corrosion current (icorr) to the sample area (1sqcm) &(ρ) density of the aluminium alloy and its hybrid reinforced composites (g/cm3) and K1 = 3.27 × 10−3 mm g/µA cm y or 0.129 mpy g/µA cm. Sample equivalent weight is considered dimensionless. Table 1 displays the rate of corrosion for AA 6351 and its hybrid aluminium nanocomposites in 3.5% NaCl, calculated using the above Eq. (1) [34].
Conclusions
The main objective of this thesis is to study the corrosion performance of the nanohybrid metal matrix composite with varying weight percentages (3–9 in steps of 3) of nano-zirconium dioxide added to the base aluminium alloy6351 and nanoSiC.
-
The effect of adding five weight percent nanoSiC to the AA6351 and with various amounts of nano-zirconium dioxide reinforced to aluminium alloy 6351 and nanoSiC prepared by powder metallurgy was analysed to find the corrosion rate by an electrochemical method like Tafel extrapolation method in NaCl medium for applications like hull structures, bicycle frames, marine and aerospace sectors.
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X-ray Diffraction analysis and SEM–EDS confirms the presence of SiC and ZrO2 reinforcement in the aluminium alloy6351. Microstructure revealed a pitting form of corrosion on the material surfaces.
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The corrosion rate of the composites investigated can be formed in a descending order as: SAZ3 < SAZ4 < SAZ5. The corrosion resistance of the three nanohybrid metal matrix composite samples in descending order is: SAZ5 < SAZ4 < SAZ3 which clearly denotes that increasing the weight percentage of the Zirconium dioxide has improved the corrosion resistance of hybrid aluminium nanometal matrix composite. Despite of aluminium alloy6351 exhibits the excellent resistance, it is further concluded that SAZ5 showing an excellent resistance to corrosion in 3.5% NaCl solution which will be suitable for the applications like hull structures, bicycle frames, marine and aerospace sectors.
Data Availability
All data used to support the findings of this study are included within the article.
Abbreviations
- AA:
-
Aluminium alloy
- I corr :
-
Corrosion current density
- E corr :
-
Corrosion potential
- R p :
-
Polarization resistance
- β a :
-
Anodic slope (Volts/Decade)
- β c :
-
Cathodic slope (Volts/Decade)
- CR:
-
Corrosion rate (mm/year or mils per year)
- OCP:
-
Open circuit potential
- EIS:
-
Electrochemical impedance spectroscopy
- SEM:
-
Scanning electron microscopy
- ZrO2 :
-
Zirconium dioxide or zirconia
- SiC:
-
Silicon carbide
- BPR:
-
Ball to powder ratio
- ASTM:
-
American society for testing and materials
- HANMMC:
-
Hybrid aluminium nanometal matrix composite
- PM:
-
Powder metallurgy
- SEM:
-
Scanning electron microscope
- AMC:
-
Aluminium matrix composite
- BN:
-
Boron nitride
- ZrB2 :
-
Zirconium diboride
- Si3N4 :
-
Silicon nitride
- EDS:
-
Energy dispersive spectroscopy
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SarithNaidu, T., VenkataSubbaiah, K. Analysis of Corrosion Rate of Nanohybrid AA 6351/SiC/ZrO2 Composites by Tafel Extrapolation Technique. J. Inst. Eng. India Ser. D (2023). https://doi.org/10.1007/s40033-023-00567-7
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DOI: https://doi.org/10.1007/s40033-023-00567-7