Abstract
The possibility of utilizing Canarium schweinfurthii seed shell (CSSS) as a precursor to optimally produce activated carbon was harnessed by physico-chemical activation. Carbon (IV) oxide (CO2) and potassium acetate (CH3COOK) were employed as physical and chemical activating agents, respectively. Its ability as an effective adsorbent was tested on aqueous solution by removing 2,4,6-trichlorophenol (2,4,6-TCP). Central composite design was employed for the optimization giving rise to activation temperature of 670 °C, activation time of 100 min and impregnation ratio of 2.43. The optimal adsorbent (CSSS-AC) can be classified as mesoporous with surface area of 925.77 m2 g−1 and maximum adsorption capacity of 247.23 mg g−1. Higher amount of 2,4,6-TCP was removed at low pH with Freundlich and pseudo-second-order models found to be the most appropriate isotherm and kinetic model, respectively, in describing the adsorption process. The results reveal that C. schweinfurthii seed shell could be recommended as a promising novel precursor for producing activated carbons with high surface area and potentially desirable 2,4,6-TCP removal capacity, using CH3COOK as an effective activating agent.
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Introduction
Chlorophenols are group of hazardous compounds present in industrial wastewater that are popularly known to be toxic to living organisms and also contaminate environment (Sarnalk and Kanekar 1995; Wang et al. 2018). They are also pertinacious and carcinogenic with intense odour (Armenante et al. 1999; Tan et al. 2009). Discharging chlorophenols into aquatic environment represent a noteworthy source of environmental pollution. Adsorption (Afidah and Garba 2016; Alizadeh et al. 2017; Garba and Afidah 2015, 2016; Hussin et al. 2016; Madannejad et al. 2018), catalytic wet oxidation (Chaliha and Bhattacharyya 2008), biodegradation (Steinle et al. 2000), ozonation and electrochemical degradation (Lim et al. 2013) and reverse osmosis (Gogoi et al. 2018) are just few of the several treatment methods engaged for the chlorophenols removal from wastewater with adsorption being the most active and efficient among them (Garba and Afidah 2016; Garba et al. 2015a). Popularity of adsorption method is related to its simplicity in design, ability to remove high amount of contaminants as well as swift adsorption kinetics with the most widely used adsorbent being activated carbon (Lee et al. 2015; Lladó et al. 2015). Being the most popular and active adsorbent reported (Garba et al. 2015c; Salman 2014), activated carbons have a very big advantage in terms of industrial applications due to its flexible surface characteristics (Garba et al. 2015b, c; Hazzaa and Hussein 2015). However, their high cost in the market becomes a hindrance in their applicability for the treatment of industrial sewages and runoffs (Chang et al. 2014; Sivarajasekar and Baskar 2014). This prompted an increasing interest in using cheap and readily available materials as precursors for activated carbon production (Andrade et al. 2015; Mendes et al. 2015). Numerous waste materials such as vilayti tulsi (Pardeshi et al. 2013), natural walnut shell (Çelebi and Gök 2017), waste tea (Garba et al. 2015b; Özbaş et al. 2013), marble waste (Bouamra et al. 2018), egg shell (Mashangwa et al. 2017), saw palmetto spent (Papegowda and Syed 2017) and coconut spathe (Prashanthakumar et al. 2018) have been transformed effectively into adsorbents on a laboratory scale.
Canarium schweinfurthii is very popular plant in Africa with its seed shell very cheaply available in Nigeria. An attempt was made in this work to explore the potentials of Canarium schweinfurthii seed shell (CSSS) in the preparation of activated carbon after preliminary studies revealed CSSS to contain high carbon and low ash content which makes it a good precursor material for preparing activated carbon as adsorbent. To make the work better and more accurate, we seek the help of an adequate experimental design. Experimental design is a very useful tool that is widely reported in optimizing the preparation conditions of activated carbons (Garba et al. 2016) usually applied to simultaneously optimize the impact of variables in improving characteristics performance as well as minimizing error (Nouri et al. 2012). Currently to the best of our knowledge, no study has been reported on the optimization of activated carbon preparation conditions from CSSS using central composite design (CCD), a subset of response surface methodology (RSM) for the removal of 2,4,6-TCP.
Therefore, revealing the potentials of CSSS as a new precursor by optimizing the activated carbon preparation conditions for the removal of 2,4,6-TCP using CH3COOK as an activating agent constitutes the novelty of this work. The effects of preparation variables (activation temperature, activation time as well as impregnation ratio) were studied concurrently to obtain a high 2,4,6-TCP adsorption capacity as well as the maximum activated carbon yield possible from aqueous solution using CCD.
Methodology
Materials
Sigma-Aldrich supplied both the chemical activating agent (CH3COOK) and adsorbate (2,4,6-TCP) which were used without further purifying them. The chemical formula of the adsorbate (Fig. 1) is C6H3Cl3O with molecular weight of 197.45 g mol−1. Reagents of analytical grade were employed in this work with all the solutions prepared using deionized water. CSSS samples were obtained from Jos, Plateau State, Nigeria. The shells were washed, sun-dried and later crushed with a mechanical crusher in the Institute of Agricultural Research (IAR), Ahmadu Bello University, Zaria. The crushed shells were sieved to a 250-µm particle size and dried in an oven at 100 °C for 24 h before usage.
Preparation of adsorbent (CSSS-AC)
The CSSS sample was dried, weighed then impregnated with CH3COOK and later activated at temperature and time as determined by the design of experiment (DOE) in Table 1. The sample carbonization took place inside a furnace by transferring the mixture using a stainless steel vertical tubular reactor. Purified nitrogen gas (99.99%) atmosphere with the flow rate of 150 mL min−1 was used throughout in heating the reactor at 600 °C for the sample carbonization. The carbonization step was then followed by activation step which involved activating the carbonized sample under CO2 gas at the same flow rate of 150 mL min−1 using similar reactor as used for carbonization under different temperatures and held for varying periods of time. The product was cooled to room temperature, then washed with distilled water until a neutral pH was attained, oven-dried and finally stored in an airtight container for further use.
The impregnation ratio was computed using the following relationship:
The adsorbent preparation was strictly adhered to the DOE table as shown in Table 1.
Design of experiments using response surface methodology
An orthodox RSM design, known as central composite design (CCD), was applied in this work to study the variables for preparing the activated carbons from CSSS in the same way as reported in our previously published works (Garba and Afidah 2014; Garba et al. 2014, 2015a).
The variables studied in this work were activation temperature coded as a1, activation time coded as a2 and impregnation ratio also coded as a3 with their respective ranges chosen based on the literature as given in Table 2. The design-expert statistical software (version 8.0.6 Stat Ease, Inc., Minneapolis, MN 55413, USA) was employed for model fitting and significance for the CSSS-AC yield and adsorption capacity of the 2,4,6-TCP.
Characterization of the prepared activated carbon
Scanning electron microscope (FEI QUANTA) was used to study the surface morphology of CSSS-AC with CHNS and thermogravimetric (Perkin Elmer TGA, USA) analyser employed in determining the elemental composition and proximate analysis, respectively. Brunauer–Emmett–Teller (BET) equation was employed to determine the BET surface area, micropore volume, total pore volume and pore size of the CSSS-AC.
Adsorption isotherms
Langmuir, Freundlich and Temkin isotherms are the three most popular isotherm models that were applied to fit the experimental data for the adsorption of 2,4,6-TCP. Langmuir isotherm equation describes an adsorption process that occurs upon a homogeneous surface where the adsorbate is distributed in monolayers (Kumar et al. 2010). It is mathematically described as:
where Ce (mg L−1) is the equilibrium concentration of the 2,4,6-TCP, qe stands for the adsorbate amount adsorbed per unit adsorbent weight, while \( Q_{\text{a}}^{0} \) (mg g−1) and KL (L mg−1) are Langmuir constants related to maximum adsorption capacity and rate of adsorption, respectively. The essential characteristics of the Langmuir equation can be expressed in terms of dimensionless separation factor, RL, defined as (Baccar et al. 2013):
where Co is the highest initial solute concentration. RL values indicate whether the adsorption is unfavourable (RL > 1), linear (RL = 1), favourable (0 < RL < 1), or irreversible (RL = 0).
Freundlich isotherm on the other hand assumes adsorption on heterogeneous surface with sites of different affinities (Hameed et al. 2008). The logarithmic form of the Freundlich isotherm is given by the following equation:
where KF and n are Freundlich constants. KF (mg1−n g−1 Ln) is the adsorption capacity when the adsorbate equilibrium concentration equal to 1.00 mg L−1 (Oo et al. 2009) with n related to adsorption intensity (Wan Ngah et al. 2011). In general, n > 1 suggests that adsorbate is favourably adsorbed on the adsorbent. The higher the n value, the stronger the adsorption intensity.
The influence of indirect adsorbent/adsorbate interactions on adsorption isotherms was illustrated by Temkin isotherm model (Hadi et al. 2010). It is written as:
where \( \frac{RT}{b} \) = B (J/mol) and A (L/g) are Temkin constants, which are related to heat of sorption and maximum binding energy, respectively, R is the gas constant (8.31 J mol−1 K−1), and T (K) is the absolute temperature.
Batch equilibrium and kinetic studies for the removal of 2,4,6-TCP
For the batch equilibrium and kinetic studies, 0.15 g of the CSSS-AC was placed in a set of 250 mL Erlenmeyer flasks with each flask containing 150 mL of 2,4,6-TCP solution. An isothermal shaker was used at 30 °C at a speed of 150 rpm until equilibrium was attained. The 2,4,6-TCP equilibrium concentration was determined using UV–Vis spectrophotometer (Helios γ) at maximum wavelength of 296 nm.
The percentage removal of 2,4,6-TCP (% R) was evaluated using the following equation.
where Co and Ce are the liquid-phase concentrations at initial and equilibrium states (mg L−1), respectively.
The equilibrium amount of 2,4,6-TCP adsorbed per unit mass of adsorbent, qe (mg g−1), was estimated by equation as follows:
where qe (mg/g) is the equilibrium amount of adsorbate adsorbed per unit mass of adsorbent; V (L) is the volume of the solution; and W (g) is the mass of the adsorbent used.
In order to study the kinetics of the adsorption process, concentration of the 2,4,6-TCP solution was determined at intervals of time; the amount of the 2,4,6-TCP adsorbed at time t, qt (mg g−1), was calculated using equation:
where Co and Ct (mg L−1) are the liquid-phase adsorbate concentrations at the initial and any time t, respectively.
The effect of initial pH (2–12) on the adsorption of the 2,4,6-TCP by the adsorbents was conducted by adjusting the pH of the solution with 0.1 M HCl and 0.1 M KOH solutions. The final pH of the solutions was measured using a pH meter (Martini instrument, Mi 106). The 2,4,6-TCP initial concentration was 350 mg L−1 with adsorbents dosage of 0.15 g at a temperature of 30 °C for 12 h. The % R was calculated using Eq. (6).
Results and discussion
Development of regression model equation
Table 1 presented the range of variables considered for CSSS-AC preparation with two responses (Y2,4,6-TCP and YCSSS-AC). Responses were correlated using CCD which led to the development of polynomial regression equations (all quadratic expressions). The model expression was selected in accordance with sequential model sum of square that is based on the polynomial’s highest order where the model was not aliased and the additional terms were significant.
There was noticeable qualitative correlation between the predicted and experimental data as signified by the model’s R2 values of 0.9161 (2,4,6-TCP) and 0.9550 (yield) which were within suitability range (Sahu et al. 2010). The R2 values for the adsorption capacity of 2,4,6-TCP and CSSS-AC yield were reasonably high and in good agreement with adjusted R2 (Adj. R2) values of 0.8405 and 0.9145, respectively, indicating reasonable agreement between the predicted values and the actual values. Equations 3 and 4 show the final empirical model’s equations for the adsorption capacity of 2,4,6-TCP (Y2,4,6-TCP) and CSSS-AC yield (YCSSS-AC) responses, respectively, given as
Antagonistic and synergetic effects of the respective variables are indicated by the negative and positive signs before the terms, respectively. Uni-factor, double factor and quadratic effects are indicated by the appearance of a single variable, two variables and second-order variables, respectively.
Statistical analysis
Tables 3 and 4 demonstrate the results of the surface quadratic model in the form of analysis of variance (ANOVA) for adsorption capacity of 2,4,6-TCP and CSSS-AC yield, respectively. To validate the significance and adequacy of the models, ANOVA is very essential. The sum of the squares of each of the variation sources, the model and the error variance were divided by the respective degrees of freedom to acquire the mean squares (Ahmad and Alrozi 2010b). The model terms are thought to be significant only if Prob. > F is less than 0.05. With respect to the adsorption capacity of 2,4,6-TCP from Table 3, the model was deemed to be significant due to F value of 12.13 and Prob. > F of 0.0003. In this case, the significant model terms were \( a_{1} , a_{3} ,a_{1}^{2} ,a_{3}^{2} \;{\text{and}}\; a_{1} a_{3 } \); on the other hand, \( a_{2, } a_{2}^{2} , a_{1} a_{2} \;{\text{and}}\;a_{2} a_{3 } \) were insignificant to the response (Y2,4,6-TCP). The signal-to-noise ratio is gauged by adequate precision (AP). A ratio above 4 is appropriate. In this case, ratio of 10.92 for the adsorption capacity of 2,4,6-TCP signified an adequate signal which infers that his model can be used to steer the design space.
With respect to CSSS-AC yield from Table 4, the model F value and Prob. > F values were 23.58 and < 0.0001, respectively, signifying the model’s significance. The significant model terms in this case were \( a_{1} , a_{2} ,a_{3} , a_{1}^{2} \) and \( a_{1} a_{2} \) with \( a_{2}^{2} \), \( a_{3 }^{2} , a_{1} a_{3 } \) and \( a_{2} a_{3 } \) denoting the insignificant terms. Based on the adequate signal shown by AP (18.00), this model can be used to navigate the design space.
The ANOVA results obtained show the adequacy of both models [Eqs. (3) and (4)] in predicting the 2,4,6-TCP adsorption capacity as well as CSSS-AC yield, respectively, within the scope of variables studied. Additionally, Figs. 2 and 3 show the predicted values versus the experimental values for the 2,4,6-TCP adsorption capacity and CSSS-AC yield, respectively. The figures further proved the success of these developed models in effectively correlating the CSSS-AC preparation variables with the responses showing the closeness of the predicted values to the experimental values obtained.
Adsorption capacity of 2,4,6-TCP
From the ANOVA data generated in Table 3 with respect to the adsorption capacity 2,4,6-TCP, the three variables (activation temperature, time of activation and IR) can be seen to have uneven impact on the adsorption of 2,4,6-TCP onto the prepared CSSS-AC. The lowest effect was shown by the activation time (a2) with F value of 2.50, and also its variation did not have a significant effect on the processes. The most significant effect inflicted on the adsorption capacity of 2,4,6-TCP came from individual factors of activation temperature (a1) and IR (a3) as well as their interactions (a1a3) as can be seen by their large F values of 35.20 and 45.68, respectively (Table 3). IR imposed the most significant effect on the adsorption capacity of 2,4,6-TCP by the CSSS-AC having the largest F value of 45.68 in comparison with other factors. The effect of activation temperature was the moderate and also significant showing F value of 35.20. As can be seen from Fig. 4 (A&B), there was a direct relationship between activation temperature and IR with the adsorption capacity of 2,4,6-TCP.
CSSS-AC yield
The ANOVA data generated in Table 4 are with respect to the CSSS-AC yield. It can be observed that activation temperature (a1) inflicted the greatest effect on CSSS-AC yield with the highest F value of 120.17, whereas activation time (a2) and IR (a3) show less impact on this response with F values of 25.15 and 15.90, respectively. The quadratic effect of activation temperature (a 21 ) was more pronounced with F value of 27.36, while that of activation time (a 22 ) and IR (a 23 ) were lower with F values of 2.32 and 2.44, respectively. The interaction effect between temperature and IR (a1a3) and that of interaction between activation time and IR (a2a3) were low with F values of 1.15 and 3.86, respectively, while that of interaction between activation temperature and activation time (a1a2) was more significant with F value of 12.82. Figure 5a shows the 3D response surface plots for the studied variables demonstrating the effect of temperature and time of activation with impregnation ratio fixed at zero level (IR = 1.60), whereas Fig. 4b shows the contour plots effect of the same variables on the CSSS-AC yield response (YCSSS). From both figures, the CSSS-AC yield was found to decrease with an increase in both temperature and time of activation.
Our preceding works on preparation of activated carbons from Borassus aethiopum shells (Garba et al. 2014), Prosopis africana seed hulls (Garba and Afidah 2014) and Brachystegia eurycoma seed hulls (Garba et al. 2015a) agreed very well with the results obtained in this work. Other researchers like Sudaryanto et al. (2006), Hameed et al. (2009) and Tan et al. (2008) also reported similar observations, concluding less impact of activation time on the pore structure of activated carbon produced from cassava peel, oil palm fibre and coconut husk, respectively. They also reported noteworthy changes in the pore characteristics of their adsorbents due to the impact of activation temperature as well as the impregnation ratio. Sentorun-Shalaby et al. (2006) also reported activation time to show very negligible effect on the surface area of apricot stone activated carbon produced using steam as physical activating agent. However, according to Yang and Lua (2003), activation temperature and dwell time were the most significant parameters that affected the characteristics of pistachio-nut shell activated carbon.
Process optimization
One of the main objectives of this study is to find the optimum process parameters in which CSSS-AC prepared should have large 2,4,6-TCP adsorption capacity as well as high carbon yield. Optimizing these responses under the same conditions is very complicated because the interest region of factors is poles apart since 2,4,6-TCP adsorption capacity is inversely proportional to the CSSS-AC yield; therefore, the function of desirability was applied using the design-expert software, in order to compromise between these responses. The target criteria were set as maximum values for the two responses. The predicted and experimental results of 2,4,6-TCP adsorption capacity and CSSS-AC yield obtained at optimum conditions are listed in Table 5.
Activation temperature of 670 °C, activation time of 100 min and IR of 2.43 were required to produce the optimal CSSS-AC giving rise to 2,4,6-TCP adsorption capacity of 247.23 mg g−1 and CSSS-AC yield of 22.93%. It is clear from Table 5 that the experimental values obtained were in good agreement with the values predicted from the models, with relatively small errors which were only 1.85 and 0.93 for 2,4,6-TCP adsorption capacity and CSSS-AC yield, respectively.
Characterization of the optimized CSSS-AC
Surface morphology
Figure 6 shows the SEM image of the CSSS-AC showing large and well-developed pores on its surface. This might be attributed to the effect of activation process used which comprised both CO2 and CH3COOK as physical and chemical activating agents, respectively. The high 2,4,6-TCP adsorption capacity could also be attributed to the well-developed pores on the CSSS-AC. Comparable observations were reported by other researchers utilizing Borassus aethiopum shells (Garba et al. 2014), Prosopis africana seed hulls (Garba and Afidah 2014), Brachystegia eurycoma seed hulls (Garba et al. 2015a), oil palm shell (Hamad et al. 2011) and mangosteen peel (Ahmad and Alrozi 2010a) as precursors for activated carbon.
Elemental/proximate analysis
The elemental/proximate analysis of CSSS and CSSS-AC is presented in Table 6. The precursor shows high carbon content divulging its potential to be utilized as a suitable precursor for activated carbon preparation. There was good agreement between carbon content of CSSS and some carbonaceous materials (Cordero et al. 2001) with the tremendous increase from 47.11 to 85.02% after its transformation into CSSS-AC. The sulphur content of the CSSS-AC was insignificant (0.17%) which is similar to mangosteen peel-based activated carbon reported by Ahmad and Alrozi (Ahmad and Alrozi 2010a). After the carbonization and activation process transformed CSSS into CSSS-AC, there was tremendous decrease in volatile matter content (35.21–10.77%), whereas the fixed carbon content increased from 49.06 to 82.04%. The increase in carbon content as well as the decrease in volatile matter content observed in Table 6 was attributed to pyrolytic effect at high temperature which leads to the degradation of organic substances, discharged both as gas and liquid tars leaving a material with high carbon purity (Ahmad and Alrozi 2010a). Another sign attributed to a good precursor material is low ash content which is sign of a tendency that the precursor can withstand high temperature treatment during carbonization cum chemical activation. CSSS has ash content 3.91% and hence can be classified as a good precursor.
CSSS-AC surface area and pore volume
The BET surface area, total pore volume, micropore volume and an average pore size of the CSSS-AC obtained were 925.77 m2 g−1, 0.52 cm3 g−1, 0.29 cm3 g−1 and 3.62 nm, respectively, which lies in the mesopores region according to the IUPAC classification. Physico-chemical activation process which involved both CH3COOK and CO2 have big influence on the high BET surface area and total pore volume of the CSSS-AC. Carbonization process plays a key role in pore development as it leads to an increase in the BET surface area and pore volume of the activated carbon by promoting the diffusion of the activating agent molecules into the pores, thereby intensifying the CH3COOK—carbon and CO2—carbon reactions, which would then create more pores in the CSSS-AC (Stavropoulos and Zabaniotou 2005).
Effect of contact time and solution pH on the 2,4,6-TCP adsorption
Profiles portraying the impact of contact time and solution pH on the 2,4,6-TCP adsorption are presented in Fig. 7. The 2,4,6-TCP removal was rapid at the beginning, which then regressed slowly and steadily until an equilibrium time of about 7 h. This was attributed to availability of numerous vacant active sites on the adsorbent at the initial stage. The reduction in momentum of adsorption with time was due to saturation and reduction of the available active sites (Krishnan et al. 2011). The adsorption continued to be slow until a time when insignificant adsorption was observed, that is the dynamic equilibrium stage where the adsorption rate on the adsorbent surface was the same as the amount desorbed by the same surface. The above observations compared well with the literature. The adsorption of TCP on coconut shell-based commercial grade activated carbon needed 60–210 min for initial concentration of 10–100 mg L−1 (Radhika and Palanivelu 2006). About 10 h was also reported to be required for 200 mg L−1 concentrations of both 2,4-DCP and 2,4,6-TCP to reach equilibrium on their adsorption onto cattail fibre AC (Ren et al. 2011).
The influence of solution pH on the adsorption of 2,4,6-TCP onto CSSS-AC is shown in Fig. 7 (inset). As can be observed from the plot, the percentage 2,4,6-TCP removal shows a significant decrease with an upsurge in the solution pH from 2 to 12. The highest removal on CSSS-AC was achieved at pH 2, with percentage removal as high as 95.34%. The significant decrease in 2,4,6-TCP percentage removal with an increase in the solution pH from 2 to 12 was attributed to the 2,4,6-TCP being a proton donor. According to (Hamad et al. 2010), at a certain pH (when the solution pH is greater than the pKa of chlorophenols), they turn into anions, causing the negative charge of phenoxide ions to escalate thereby declining the adsorption due to a repulsive force between the phenoxide ions and negative groups on the surface (Hamad et al. 2010).
Equilibrium and kinetic data analysis
To analyse the equilibrium data, Langmuir, Freundlich and Temkin isotherm equations were plotted to determine the best fitted model. The respective plots are presented in Fig. 8a–c. The theoretical isotherm parameters \( Q_{\text{a}}^{0} \), KL, RL, KF, n, A, B and the correlation coefficients (R2) obtained from those plots are listed in Table 7. From the Langmuir isotherm, the CSSS-AC can be seen to exhibit \( Q_{\text{a}}^{0} \) value of 294.12 mg g−1. This high value can be related to its porosity and surface area. Additionally from Table 7, CSSS-AC has RL value of 0.064 which lies between 0 and 1, confirming that the adsorption is favourable under the studied conditions. The values of maximum monolayer adsorption capacity \( Q_{\text{a}}^{0} \) obtained in this work compare well with some other adsorbents reported from literature as shown in Table 8.
Meanwhile, from the Freundlich isotherm model, CSSS-AC has n value of 1.961 which is greater than unity, confirming CSSS-AC as good adsorbent for 2,4,6-TCP removal. The data were also fitted for Temkin model, and the values of A and B were 2.074 L g−1 and 40.912 J mol−1, respectively. Still from the fitting results listed in Table 7, Freundlich isotherm model with the highest R2 value of 0.9961 appeared to be much more applicable than the Temkin (0.9830) and Langmuir (0.9527) isotherm models. This connotes that the 2,4,6-TCP molecules from bulk solution were not adsorbed on specific monolayer and is heterogeneous in nature.
In order to examine the characteristics and mechanism of the 2,4,6-TCP adsorption onto CSSS-AC, the adsorption kinetics data generated were fitted by the pseudo-first-order, pseudo-second-order and intra-particle diffusion kinetic models with their respective equations expressed as:
where qe and qt are the amounts of 2,4,6-TCP adsorbed (mg g−1) at equilibrium and at time t (h), respectively, while k1 (h−1) and k2 (g mg−1 h) are the adsorption rate constants of pseudo-first- and pseudo-second-order adsorption, respectively, kip is rate constant of the intra-particle diffusion equation, and C gives information about the boundary layer thickness: larger value of C is associated with the boundary layer diffusion effect. The fitting curves are shown in Fig. 9a–c with the kinetic parameters reported in Table 9. As can be observed from Table 9, the R2 values for pseudo-first-order model (0.9667) and the intra-particle diffusion (0.9645) were not high. Additionally, the calculated qe value with respect to pseudo-first-order model (199.480 mg g−1) was not in good agreement with the experimental value (246.33 mg g−1), indicating that pseudo-first-order is not the most appropriate kinetic model to rationalize the adsorption of 2,4,6-TCP onto CSSS-AC adsorbent. However, there was a better agreement between the experimental and calculated qe values (270.270 mg g−1) obtained from pseudo-second-order model with the R2 value obtained also closer to unity (0.9948), confirming that the 2,4,6-TCP adsorption onto CSSS-AC adsorbent fitted better into the pseudo-second-order model.
Conclusions
Three preparation variables (activation temperature, activation time and IR) of CSSS-AC and their effects on two responses (2,4,6-TCP adsorption capacity and CSSS-AC yield) were studied by employing CCD, a subset of RSM. IR imposed the greatest effect on the adsorption capacity of 2,4,6-TCP with activation temperature showing the most significant effect on CSSS-AC yield. The optimum CSSS-AC preparation conditions obtained were activation temperature of 670 °C, activation time of 100 min and IR of 2.43 showing considerably high 2,4,6-TCP adsorption capacity as well as significantly good CSSS-AC yield. There was good agreement between the experimental values obtained with the values predicted from the models showing relatively small errors. The isotherm adsorption data fit well with Freundlich model and the kinetic data fit better with the pseudo-second-order model. The high maximum adsorption capacity of the adsorbent was attributed to CSSS-AC being mesoporous with considerably high BET surface area and well-developed pores on its surface, confirming potassium acetate (CH3COOK) and schweinfurthii seed shell (CSSS) to be a promising activating agent and a low cost precursor, respectively, for activated carbon production.
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Acknowledgements
The authors are thankful to the Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria, and School of Chemical Sciences, Universiti Sains Malaysia, for providing infrastructural facilities and active moral support towards completion of this work.
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ZNG, MHH, AG and IL designed the research; ZNG carried out the laboratory work and did the RSM modelling and statistical analyses; all the authors interpreted the results and participated in the writing of this research article.
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Garba, Z.N., Hussin, M.H., Galadima, A. et al. Potentials of Canarium schweinfurthii seed shell as a novel precursor for CH3COOK activated carbon: statistical optimization, equilibrium and kinetic studies. Appl Water Sci 9, 31 (2019). https://doi.org/10.1007/s13201-019-0907-y
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DOI: https://doi.org/10.1007/s13201-019-0907-y