Abstract
Seasonal variation of ground water in Nayagarh district, Odisha is determined by analysing both pre and post monsoon water samples. The high fluoride content is an endemic problem in the area and special attention was attached to the point. The chemical compositions of the ground water of the area are dominated by CaCl, NaCl and mixed CaMgCl types in pre-monsoon and CaHCO3-mixed CaMgCl type in post-monsoon. This is largely due to chemical weathering of Eastern Ghats Mobile Belt rock types. Increasing alkalinity vis-a-vis F concentration in pre-monsoon is associated with sodium-bicarbonate water types having high pH (>7) and low calcium and magnesium contents. The percentage of total high fluoride containing water samples is nearly double in pre-monsoon than in post-monsoon. During both the seasons, pH values indicate mildly alkaline to weakly acidic nature of the water samples. Fluoride concentration has good correlation with pH in pre-monsoon whereas in post-monsoon it shows good correlation with Fe. Facies analysis indicates that water is becoming predominantly Ca-Na cation and Cl-SO4-HCO3 anion type in premonsoon than Ca-Mg type and HCO3-Cl-SO4 type in post-monsoon. The seasonal variations in concentrations of anthropogenic components demonstrate that the groundwater system is very less liable to pollution by human activities.
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References
Allmann, R. and Koritnig, S. (1974) Fluorine. In: K.H. Wedepohl (Ed.), Handbook of Geochemistry, vol.II/1. Berlin, Heidelberg; Springer Verlag.
APHA 1995) Standard methods for the examination of water and waste water, 19th ed., American Public Association, Washington D.C., 1467p.
Aris, A.Z., Abdullah, M.H., Ahmed, A. and Woong, K.K. (2007) Controlling factors of groundwater hydrochemistry in a small island aquifer. Jour. Environ. Sci. Tech., v.4(4), pp.441–45.
Back, W. (1961) Technique for mapping of hydrochemical facies. USGS Prof. Paper 424-D, pp.380–382.
Barrow, N.J. and Ellis, A.S., (1986) Testing a mechanistic model III. The effect of pH on fluoride retention by a soil. Jour. of Soil Science, v.37, pp.287–293.
Bartzokas, A and Metaxas, D.A. (1995) Factor analysis of climatological elements in Athens, 1931–1992: covariability and climatic change. Theoret. Appl. Climatol., v.52, pp.95–205.
Briz-Kishor, B.H. and Murali, G. (1992) Factor analysis for revealing hydrochemical characteristics of a watershed. Environ. Geol. and Water Sciences, v.19, pp.3–9.
Chidambaram, S., Ramanathan, A.L., Anandhan, P., Srinivasamoorthy, K. and Prasanna, M.V. (2005) A comparative study on the coastal surface and ground water in and around Puduchattiram region, Tamil Nadu. Special Internat. Jour. Ecology Environ. Sci., Spec. Issue, v.31(3), pp.299–306.
Davis, J.C. (2002) Statistics and data analysis in geology. New York, Wiley, pp.526–540.
Deer, W.A., Howie, R.A. and Zussman, J. (1985) An introduction to rock forming minerals, Longman Group Ltd., ELBS, Hong Kong, pp.193–222, 231–242, 250–275.
Frencken, J.E. (Ed.) (1992) Endemic Fluorosis in developing countries, causes, effects and possible solutions. Publication number 91.082, NIPG-TNO, Leiden, The Netherlands.
Hartmann, J. and Levy, J. (2005) Hydrogeological and gasgeochemical earthquake precursors—a review for application. Natural Hazards, v.24, pp.279–304.
Hartmann, J., Berner, Z., Stuben, D. and Henze, N. (2005) A statistical procedure for the analysis of seismotectonically induced hydrochemical signals: A case study from the Eastern Carpathians, Romania. Elsevier-science direct, Tectonophysics, v.405, pp.77–98.
Helena, B., Pardo, R., Vega, M., Barrado, E., Fernandez, J. and Fernandez, L. (2000) Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Res., v.34(3), pp.807–816.
Hem, J.D. (1991), Study and interpretation of the chemical characteristics of natural water, 3rd ed., Jodhpur, India. Scientific Publ., 2254p.
ISI (1991) Indian Standard Specification for Drinking Water IS:10500, Indian Standard Institute, India.
Kaiser, H.F. (1958) The varimax criterion for analytic rotation in factor analysis. Psychometrika, v.23, pp.187–200.
Karbassi, A. R. (1996) Geochemistry of Ni, Zn, Cu, Pb, Co, Cd, V, Mn, Fe, Al and Ca in sediments of North Western part of the Persian Gulf. Internat. Jour. Environ. Studies, v.54, pp.205–212.
Lakshmanan, E., Kannan, R. and Senthil Kumar, M. (2003) Major ion chemistry and identification of hydrogeochemical processes of groundwater in a part of Kancheepuram district, Tamil Nadu, India. Environmental Geosciences, v.10(4), pp.157–166.
Lee, J.Y., Cheon, J.Y., Lee, K.K., Lee, S.Y. and Lee, M.H. (2001) Statistical evaluation of geochemical parameter distribution in a ground water system contaminated with petroleum hydrocarbons. Jour. Environ. Quality, v.30, pp.1548–1563.
Madhavan, N. and Subramanian, V. (2006) Environmental impact assessment including evolution of fluoride and arsenic contamination process in ground water and remediation of contaminated ground water system. In: M. Thangarajan (Ed.), Sustainable Development and Management of Ground Water Reserve. Capital Publi. Co., New Delhi, pp.128–155.
Mezger, K. and Cosca, M.A. (1999) The thermal history of the Eastern Ghats Belt (India) as revealed by U-Pb and 40Ar-39Ar dating of metamorphic and magmatic minerals: implications for the SWEAT correlation. Precambrian Res., v.94, pp.251–271.
Mukherjee, A., Jana, P. and Das, S. (1999) The Banpur-Balugaon and Bolangir Anorthosite Diapirs of the Eastern Ghats, India: Implications for the Massif Anorthosite Problem. Internat. Geol. Rev., v.41, pp.206–242.
Panagopoulos, G., Lamprakis, N., Tsolis-katagas, P. and Papoulis, D. (2004) Cation exchange processes and human activities in unconfined aquifers. Environ. Geol., v.46, pp.542–552.
Pati, G.C. (2009) Ground water resource scenario of Orissa, Workshop on Ground water Scenario and quality in Orissa, 6th &7th March, Bhubaneswar.
Piper, A.M. (1944) A graphic procedure in the geochemical interpretation of water analysis. Amer. Geophys. Union Trans., v.25, 914–923p.
Prasanna, M.V., Chidambaram, S. and Srinivasamoorthy, K. (2010) Statistical analysis of the hydrogeochemical evolution of groundwater in hard and sedimentary aquifers system of Gadilam river basin, South India. Jour. King Saud University (Science), v.22, pp.133–145.
Prasanna, M.V., Chidambaram, S., Srinivasamoorthy, K., Anandan, P. and John Peter, A. (2008b) Assessment of groundwater quality using geographical information system in the Gadilam river basin, Tamil Nadu, India. Intl. Jour. Ecology and Environ. Conservation, v.14(2–3), pp.293–298.
Rajesh, R, Sreedhara Murthy, T.R. and Raghavan, B.R. (2002) The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India. Water Research, v.36, pp.2437–2442.
Ramesh Kumar, A. and Riyazuddin, P. (2008) Application of chemometric techniques in the assessment of ground water pollution in a suburban area of Chennai city, India. Curr. Sci., v.94(8), pp. 235–242.
Ravichandran, S., Ramanibai, R. and Punderikanthan, N.V. (1996) Ecoregions for describing water quality patterns in Tamiraparani basin South India. Jour. Hydrol., v.178, pp.257–276.
Romero, J., Kagalou, I., Imberger, J., Hela, D., Kotti, M., Bartzokas, A., Albanis, T., Evmirides, N., Karkabounas, S., Papagiannis, J. and Bithava, A. (2002) Seasonal water quality of shallow and eutrophic Lake Pamvotis, Greece: implications for restoration. Hydrobiologia, v.474, pp.91–105.
Sarin, M.M., Krishnaswami, S., Dilli, K., Somayajulu, B.L.K. and Moore, W.S. (1989) Major ion chemistry of the Ganga-Brahmaputra river system:Weathering processes and fluxes to the Bay of Bengal, Geochem. Cosmochim. Acta, v.53, pp.997–1006.
SRIVASTAVA (2005) Aquifer geometry, basement-topography and groundwater quality around Ken Graben, India. Jour. Spatial Hydrology, v.2(2), pp.1–7.
Weber, G.E., Furch, K. and Junk, W.J. (1996) A simple modeling approach towards hydrochemical seasonality of major cations in a Central Amazonian floodplain lake. Ecol. Model, v.91, pp.39–56.
WHO (2006) Guidelines for Drinking Water quality first addendum to third edition, Volume 1 recommendations. (http://www.who.int/water.pdf).sanitationhealth/dwq/gdwq0506.pdf).
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Routroy, S., Harichandan, R., Mohanty, J.K. et al. A Statistical appraisal to hydrogeochemistry of fluoride contaminated ground water in Nayagarh district, Odisha. J Geol Soc India 81, 350–360 (2013). https://doi.org/10.1007/s12594-013-0045-3
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DOI: https://doi.org/10.1007/s12594-013-0045-3