Abstract
Ziyang County, Shaanxi Province, China is a world known selenium (Se)-enriched area, and a severe selenosis incident was reported in Naore Village during the 1990s. This study investigated the geochemical characteristics of Se and its fractions in Se-enriched rocks from Ziyang. Se distribution is uneven, ranging from 0.23 to 57.00 μg/g (17.29±15.52 μg/g). Se content is higher in slate than chert, and even lower in carbonate rocks. Cd, As and V are enriched but Pb is depleted in Se-enriched strata. Se has different correlations both with TS (total sulfur) (R 2=0.59 for chert) and TC (total carbon) (R 2=0.77 for slate, R 2=0.87 for carbonate). Se has significant positive correlations with V (r=0.65), As (r=0.485), Cd (r=0.459) and Pb (r=0.405). The Se level correlates with mineral content, positively with pyrite, chlorite and illite, negatively with albite. Se associated with sulfide/selenide and elemental Se are the predominant fractions of total recovered Se, suggesting that a reducing environment and the formation of sulfides were significant to Se deposition during its geochemical cycle. Although low concentration of bio-available Se (average 5.62%±3.69%) may reduce the risk of Se poisoning in the target area, utilization of Se-rich rock as natural fertilizer should be restricted.
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Tian, H., Ma, Z., Chen, X. et al. Geochemical characteristics of selenium and its correlation to other elements and minerals in selenium-enriched rocks in Ziyang County, Shaanxi Province, China. J. Earth Sci. 27, 763–776 (2016). https://doi.org/10.1007/s12583-016-0700-x
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DOI: https://doi.org/10.1007/s12583-016-0700-x