Abstract
In this research, wool surface was successfully coated with polypyrrole (PPy) by one-step UV-induced polymerization using AgNO3 as catalyst for oxidation of pyrrole monomers. The influence of the concentration of materials on the surface morphology, thermal and electromagnetic shielding properties was investigated using FTIR, XRD, SEM, EDS, TGA, RS and NA. The new bands at 2369 and 1519 cm-1 appeared in FTIR clearly showed structural changes of wool proteins. XRD spectra revealed two new peaks related to silver planes at 2θ=33° and 47° for UV-induced PPy/Ag nanocomposite coated wool. Furthermore, EDS results confirmed the presence of different amounts of silver on wool proportional to the applied PPy/Ag nanocomposites. TGA results demonstrated that the PPy/Ag nanocomposite coatings could significantly improve the thermal stability of wool fibers. This paper introduces a simple and versatile method for production of PPy/Ag nanocomposite, which can be applied as a high electromagnetic shielding on textiles.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
M. Niu, X. Liu, J. Dai, H. Jia, L. Wei, and B. Xu, Fiber. Polym., 11, 1201 (2010).
M. Parvinzadeh Gashti, F. Alimohammadi, and A. Shamei, Surf. Coat. Technol., 206, 3208 (2012).
F. Alimohammadi, M. Parvinzadeh Gashti, and A. Shamei, Prog. Org. Coat., 74, 470 (2012).
E. Pakdel and W. A. Daoud, J. Colloid Interface Sci., 410, 1 (2013).
J. Bonastre, J. Molina, A.I. del Río, J. C. Galván, and F. Cases, Synth. Met., 161, 1958 (2011).
M. P. Gashti, J. Text. Sci. Eng. 4: e120. doi:10.4172/2165-8064.1000e120 (2014).
C. Y. Lee, D. E. Lee. C. K. Jeong, Y. K. Hong, J. H. Shim, J. Joo, M. S. Kim, J. Y. Lee, S. H. Jeong, S. W. Byun, D. S. Zang, and H. G. Yang, Polym. Adv. Technol., 13, 577 (2002).
A. Kaynak, E. Håkansson, and A. Amiet, Synth. Met., 159, 1373 (2009).
A. Oroumei, H. Tavanai, and M. Morshed, J. Electron. Mater., 40, 2256 (2011).
A. Zamanian and C. Hardiman, High Frequency Electronics, 4, 16 (2005).
J. S. Roh, Y. S. Chi, T. J. Kang, and S. W. Nam, Text. Res. J., 78, 825 (2008).
J. Yip, S. Jiang, and C. Wong, Surf. Coat. Technol., 204, 380 (2009).
H. Deng, L. Lin, M. Ji, S. Zhang, M. Yang, and Q. Fu, Prog. Polym. Sci., 39, 627 (2014).
P. Saini, V. Choudhary, N. Vijayan, and R. K. Kotnala, Phys. Chem. C, 116, 13403 (2012).
K. Jlassi, A. Singh, D. K. Aswal, R. Losno, M. Benna-Zayani, and M. M. Chehimi, Colloid Surf. A-Physicochem. Eng. Asp., 439, 193 (2013).
Y. Wei, L. Li, X. Yang, G. Pan, G. Yan, and X. Yu, Nanoscale Res. Lett., 5, 433 (2010).
D. Hodko, M. Gamboa-Aldeco, and O. J. Murphy, J. Solid State Electrochem., 13, 1063 (2009).
X. Yang and Y. Lu, Mater. Lett., 59, 2484 (2005).
C. R. Martins, Y. M. de Almeida, G. C. do Nascimento, and W. M. de Azevedo, J. Mater. Sci., 41, 7413 (2006).
A. Singh, Z. Salmi, N. Joshi, P. Jha, A. Kumar, H. Lecoq, S. Lau, M. M. Chehimi, D. K. Aswal, and S. K. Gupta, RSC Adv., 3, 5506 (2013).
P. Saini, M. Arora, G. Gupta, B. K. Gupta, V. N. Singh, V. Choudhary, and S. K. Dhawan, Nanoscale, 5, 4330 (2013).
P. Saini, V. Choudhary, and S. K. Dhawan, Polym. Adv. Technol., 20, 355 (2009).
P. Saini, V. Choudhary, B. P. Singh, R. B. Mathur, and S. K. Dhawan, Mat. Chem. Phys., 113, 919 (2009).
S. Maiti, N. K. Shrivastava, S. Suin, and B. B. Khatua, ACS Appl. Mater. Interfaces, 5, 4712 (2013).
B. Zhang, Y. Du, P. Zhang, H. Zhao, L. Kang, X. Han, and P. Xu, J. Appl. Polym. Sci., 130, 1909 (2013).
W Zhou, X. Hu, X. Bai, S. Zhou, C. Sun, J. Yan, and P. Chen, ACS Appl. Mater. Interfaces, 3, 3839 (2011).
S. N. Tripathi, P. Saini, D. Gupta, and V. Choudhary, J. Mater. Sci., 48, 6223 (2013).
P. Saini, V. Choudhary, B. P. Singh, R. B. Mathur, and S. K. Dhawan, Synth. Met., 161, 1522 (2011).
P. Saini, and M. Arora, Microwave Absorption and EMI Shielding Bahavior of Nanocomposites Based on Intrinsically Conducting Polymers, Graphene and Carbon Nanotubes, New Polymers for Special Applications, Dr. A. De Souza Gomes (Ed.), ISBN: 978-953-51-0744-6, InTech, DOI: 10.5772/48779. Available from: http://www.intechopen.com/books/new-polymers-for-special-applications/microwaveabsorption-and-emi-shielding-behavior-of-nanocompositesbased-on-intrinsically-conducting-, 2012.
P. Saini and V. Choudhary, J. Mater. Sci., 48, 797 (2013).
P. Saini and M. Arora, J. Mater. Chem. A, 1, 8926 (2013).
F. Jian-Jun, L. Su-Fang, Z. Wen-Ke, C. Hong-Yun, C. Jun-Fang, and C. Zong-Zhang, J. Inorganic Mater. 26, 467 (2011).
S. M. Abbas, R. Chatterjee, A. K. Dixit, A. V. R. Kumar, and T. C. Goel, J. Appl. Phys., 101, 074105 (2007).
A. Varesano, L. Dall’Acqua, and C. Tonin, Polym. Degrad. Stabil., 89, 125 (2005).
L. Wang, T. Lin, X. Wang, and A. Kaynak, Fiber. Polym. 6, 259 (2005).
A. Varesano, A. Aluigi, C. Tonin, and F. Ferrero, Fiber. Polym., 7, 105 (2006).
A. Boschi, C. Arosio, I. Cucchi, F. Bertini, M. Catellani, and G. Freddi, Fiber. Polym., 9, 698 (2008).
A. Kaynak, S. Shaikhzadeh Najar, and R. C. Foitzik, Synth. Met., 158, 1 (2008).
A. Kaynak, L. Wang, C. Hurren, and X. Wang, Fiber. Polym., 3, 24 (2002).
S. Garg, C. Hurren, and A. Kaynak, Synth. Met., 157, 41 (2007).
K. Firoz Babu, P. Dhandapani, S. Maruthamuthu, and M. Anbu Kulandainathan, Carbohydr. Polym., 90, 1557 (2012).
M. F. Attia, T. Azib, Z. Salmi, A. Singh, P. Decorse, N. Battaglini, H. Lecoq, M. Omastova, A. A. Higazy, A. M. Elshafei, M. M. Hashem, and M. M. Chehimi, J. Colloid Interface Sci., 393, 130 (2013).
M. A. Breimer, G. Yevgeny, S. Sy, and O. A. Sadik, Nano Lett., 6, 305 (2011).
M. Parvinzadeh Gashti and A. Almasian, Compos. Pt. BEng., 52, 340 (2013).
M. Parvinzadeh Gashti, B. Katozian, M. Shaver, and A. Kiumarsi, Color. Technol., 130, 54 (2014).
J. Cao and C. A. Billows, Polym. Int., 48, 1027 (1999).
M. Parvinzadeh Gashti, and A. Almasian, Compos. Pt. BEng., 43, 3374 (2012).
R. Hajiraissi and M. Parvinzadeh, Appl. Surf. Sci., 257, 8443 (2011).
Y. Chen, Z. Zhao, and C. Zhang, Synth. Met., 163, 51 (2013).
M. Omastova, P. Bober, Z. Moravkova, N. Perinka, M. Kaplanova, T. Syrový, J. Hromadkova, M. Trchova, and J. Stejskal, Electrochim. Acta, 296, 122 (2014).
M. Parvinzadeh, S. Moradian, A. Rashidi, and M. E. Yazdanshenas, Appl. Surf. Sci., 256, 2792 (2010).
M. Parvinzadeh, S. Moradian, A. Rashidi, and M. E. Yazdanshenas, Polym.-Plast. Technol. Eng., 49, 1 (2010).
M. Melgosa, D. H. Alman, M. Grosman, L. Gómez-Robledo, A. Trémeau, G. Cui, P. A. García, D. Vázquez, C. Li, and M. Ronnier, Color Res. Appl., 38, 429 (2013).
S. Chatterjee, A. Garai, and A. K. Nandi, Synth. Met., 161, 62 (2011).
M. Parvinzadeh Gashti, A. Almasian, and M. Parvinzadeh Gashti, Sens. Actuator A-Phys., 187, 1 (2012).
M. Parvinzadeh Gashti and S. Eslami, Superlattic. Microstruct., 51, 135 (2012).
M. Parvinzadeh and S. Eslami, Res. Chem. Interm., 37, 771 (2011).
D. D. L. Chung, Carbon, 39, 279 (2001).
P. Saini, V. Choudhary, and S. K. Dhawan, Polym. Adv. Technol., 23, 343 (2012).
A. Kaynak and E. Hakansson, Int. J. Cloth. Sci. Tech., 21, 117 (2009).
P. Saini and V. Choudhary, IJPAP, 51, 112 (2013).
P. Saini and V. Choudhary, J. Appl. Polym. Sci., 129, 2832 (2013).
A. Kaynak, E. Hakansson, and A. Amiet, Synth. Met., 159, 1373 (2009).
L. De C. Folgueras, E. L. Nohara, and M. C. Rezende, Mat. Res., 10, 95 (2007).
S. H. Kim, S. H. Jang, S. W. Byun, J. Y. Lee, J. S. Joo, S. H. Jeong, and M. J. Park, J. Appl. Polym. Sci., 87, 1969 (2003).
T. Mehmood, A. Kaynak, X. J. Dai, A. Kouzani, K. Magniez, D. Rubin de Celis, C. J. Hurren, and J. du Plessis, Mater. Chem. Phys., 143, 668 (2014).
Z. Yildiz, I. Usta, and A. Gungor, Fibres Text. East. Eur., 21, 32 (2013).
N. Onar, A. C. Aksit, M. F. Ebeoglugil, I. Birlik, and E. Celik, J. Appl. Polym. Sci., 114, 2003 (2009).
E. Håkansson, A. Amiet, and A. Kaynak, Synth. Met., 156, 917 (2006).
J. Ou, Y. Yang, Z. Yuan, Y. Zhang, L. Gan, and X. Chen, Synth. Met., 195, 9 (2014).
C. Y. Huang, J. Y. Wu, K. Y. Tsao, C. L. Lin, C. P. Chang, C. S. Tsai, Y. H. Chen, J. T. Yeh, and K. N. Chen, Thin Solid Films, 519, 4765 (2011).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gashti, M.P., Ghehi, S.T., Arekhloo, S.V. et al. Electromagnetic shielding response of UV-induced polypyrrole/silver coated wool. Fibers Polym 16, 585–592 (2015). https://doi.org/10.1007/s12221-015-0585-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-015-0585-9