Abstract
Simultaneous removal of dyes in the effluents of printing and dyeing industries is challenging, and the mechanism of the co-adsorption of dyes is still unclear. In this context, a novel adsorbent based on microcrystalline cellulose from cotton fiber through a simplified chemical modification process was prepared. Methylene blue (MB) and neutral red (NR) were selected to investigate their adsorption/co-adsorption on such functionalized microcrystalline cellulose. The experimental adsorption results indicated that the adsorption quantity of both dyes was similar for the single solute. The kinetics of adsorption processes could be better described with the pseudo-second order models for both single and binary dye solutes. The results of the co-adsorption suggested that the extended Langmuir model could well predict equilibrium. The maximum adsorption capacity of MB and NR for the single systems was 115.2 and 83.2 mg/g, respectively. Moreover, an antagonistic effect could be found in the binary dye solute. The obtained results revealed that the co-adsorption of dyes might be driven by hydrogen bonding, π-π stacking interaction as well as electrostatic interaction.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
F. Wang, Y. Pan, P. Cai, T. Guo and H. Xiao, Bioresour. Technol., 241, 482 (2017).
F. M. Mpatani, A. A. Aryee, A. N. Kani, Q. Guo, E. Dovi, L. Qu, Z. Li and R. Han, Chemosphere, 259, 127439 (2020).
S. N. Jain, S. R. Tamboli, D. S. Sutar, S. R. Jadhav, J. V Marathe, A. A. Shaikh and A. A. Prajapati, J. Clean. Prod., 252, 119778 (2020).
W. Xiao, Z. N. Garba, S. Sun, I. Lawan, L. Wang, M. Lin and Z. Yuan, J. Clean. Prod., 253, 119989 (2020).
M. A. Islam, I. Ali, S. M. A. Karim, M. S. Hossain Firoz, A.-N. Chowdhury, D. W Morton and M. J. Angove J. Water Process Eng., 32, 100911 (2019).
F. C. Çavuşoğju, S. Akan, E. A. Arı, E. Çetinkaya, E. Çolak, G. N. Daştan, S. Deniz, D. Erdem, M. Köksal, S. Korkmaz, N. Onsekiz, B. Oruçoğlu, D. Ödkaya, H. B. Uslu, Ç. Ünal, O. Yıldız, Ş. Ödkara-Aydinoğlu and Ş. S. Bayazit, Korean J. Chem. Eng., 36, 1915 (2019).
G. D. Değermenci, N. Değermenci, V. Ayvaoğlu, E. Durmaz, D. Çakır and E. Akan, J. Clean. Prod., 225, 1220 (2019).
M. Sarabadan, H. Bashiri and S. M. Mousavi, Korean J. Chem. Eng., 36, 1575 (2019).
B. Chen, H. Zhao, S. Chen, F. Long, B. Huang, B. Yang and X. Pan, Chem. Eng. J., 356, 69 (2019).
Q. Zhou, W. Gong, C. Xie, D. Yang, X. Ling, X. Yuan, S. Chen and X. Liu, J. Hazard. Mater., 185, 502 (2011).
D. Humelnicu, M. M. Lazar, M. Ignat, I. A. Dinu, E. S. Dragan and M. V. Dinu, J. Hazard. Mater., 381, 120980 (2020).
Y. Pan, H. Xie, H. Liu, P. Cai and H. Xiao, Bioresour. Technol., 286, 121366 (2019).
E. F. Diogo Januário, N. de Camargo Lima Beluci, T. B. Vidovix, M. F. Vieira, R. Bergamasco and A. M. Salcedo Vieira, Process Saf. Environ. Prot., 134, 140 (2020).
N. C. Homem, N. de Camargo Lima Beluci, S. Amorim, R. Reis, A. M. S. Vieira, M. F. Vieira, R. Bergamasco and M. T. P. Amorim, Appl. Surf. Sci., 486, 499 (2019).
N. Ghaemi and P. Safari, J. Hazard. Mater., 358, 376 (2018).
A. S. Abdulhameed, A.-T. Mohammad and A. H. Jawad, J. Clean. Prod., 232, 43 (2019).
H. Bashiri, S. Nesari and M. Sarabadan, Korean J. Chem. Eng., 37, 240 (2020).
Q. Liu, Y. Li, H. Chen, J. Lu, G. Yu, M. Möslang and Y. Zhou, J. Hazard. Mater, 382, 121040 (2020).
E. K. Shirazi, J. W. Metzger, K. Fischer and A. H. Hassani, Chemosphere, 234, 618 (2019).
D. Yu, Y. Wang, M. Wu, L. Zhang, L. Wang and H. Ni, J. Clean. Prod., 232, 774 (2019).
K. Vijayalakshmi, B. M. Devi, S. Latha, T. Gomathi, P. N. Sudha, J. Venkatesan and S. Anil, Int. J. Biol. Macromol., 104, 1483 (2017).
M. H. Hussin, N. A. Pohan, Z. N. Garba, M. J. Kassim, A. A. Rahim, N. Brosse, M. Yemloul, M. R. N. Fazita and M. K. M. Haafiz, Int. J. Biol. Macromol., 92, 11 (2016).
J. Q. Xiong, C. L. Jiao, C. M. Li, D. S. Zhang, H. Lin and Y. Y. Chen, Cellulose, 21, 3073 (2014).
J. O. Gonçalves, K. A. da Silva, E. C. Rios, M. M. Crispim, G. L. Dotto and L. A. de Almeida Pinto, Int. J. Biol. Macromol., 142, 85 (2020).
Y. Rong and R. Han, Korean J. Chem. Eng., 36, 942 (2019).
E. A. Mohamed, A. Q. Selim, S. A. Ahmed, L. Sellaoui, A. Bonilla-Petriciolet, A. Erto, Z. Li, Y. Li and M. K. Seliem, Chem. Eng. J., 380, 122445 (2020).
M. A. Hossain, H. H. Ngo, W. S. Guo, L. D. Nghiem, F. I. Hai, S. Vigneswaran and T. V. Nguyen, Bioresour. Technol., 160, 79 (2014).
B. Agarwal, C. Balomajumder and P. K. Thakur, Chem. Eng. J., 228, 655 (2013).
Q. Chen, J. Zheng, L. Zheng, Z. Dang and L. Zhang, Chem. Eng. J., 350, 1000 (2018).
L. J. Li, F. Q. Liu, X. S. Jing, P. P. Ling and A. M. Li, Water Res., 45, 1177 (2011).
N. Deihimi, M. Irannajad and B. Rezai, J. Environ. Manage., 227, 277 (2018).
B. Wang, Y. B. Zhai, T. F. Wang, S. H. Li, C. Peng, Z. X. Wang, C. T. Li and B. B. Xu, Bioresour. Technol., 274, 525 (2019).
Z. B. Wu, H. Zhong, X. Z. Yuan, H. Wang, L. L. Wang, X. H. Chen, G. M. Zeng and Y. Wu, Water Res., 67, 330 (2014).
Acknowledgements
The authors acknowledge the financial support of National Natural Science Foundation of China (No. 41807120), the Fundamental Research Funds for the Henan Provincial Colleges and Universities in Henan University of Technology (No. 2018QNJH01), Doctor Foundation of Henan University of Technology (No. 2018BS003) and the Foundation of Province Key Laboratory of Cereal Resource Transformation and Utilization, Henan University of Technology (No. PL2018003).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bai, H., Chen, J., Zhou, X. et al. Single and binary adsorption of dyes from aqueous solutions using functionalized microcrystalline cellulose from cotton fiber. Korean J. Chem. Eng. 37, 1926–1932 (2020). https://doi.org/10.1007/s11814-020-0621-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-020-0621-3