Abstract
The solubility of platinum in the molten BaO-Al2O3, BaO-SiO2, CaO-Al2O3, CaO-SiO2, Na2O-SiO2, and CaO-Al2O3-SiO2 systems has been measured in order to seek a new measure of basicity. The solubility of platinum increases with increasing content of basic oxide. The correlations among the solubility of platinum, carbonate, sulfide, and phosphate capacities, basic oxide activities, and theoretical optical basicity are discussed.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
S. Nakamura and N. Sano: Metall. Trans. B, 1991, vol. 22B, pp. 823–29.
D.D. Wagman, W.H. Evans, V.B. Parker, R.H. Schumm, I. Halow, S.M. Bailey, K.L. Churney, and R.L. Nuttall: J. Phys. Chem. Ref. Data, 1982, vol. 11, suppl. 2, pp. 2–186.
C. Wagner: Metall. Trans. B, 1975, vol. 6B, pp. 405–09.
T. Kawahara, K. Yamagata, and N. Sano: Steel Res., 1986, vol. 57, pp. 160–65.
M. Maeda, A. McLean, H. Kuwatori, and N. Sano: Metall. Trans. B, 1985, vol. 16B, pp. 561–67.
M. Iwase, S. Sugino, H. Sato, E. Ichise, and K. Kunitake: Trans. ISS, 1987, pp. 77–83.
C.J.B. Fincham and F.D. Richardson: Proc. R. Soc. London, 1954, vol. 223A, pp. 40–60.
R. Inoue and H. Suito: Trans. Iron Steel Inst. Jpn., 1982, vol. 22, pp. 514–23.
F. Tsukihashi, M. Nakamura, T. Orimoto, and N. Sano: Tetsu-to-Hagané, 1990, vol. 76, pp. 1664–71.
F. Tsukihashi, F. Matsumoto, T. Hyodo, M. Yukinobu, and N. Sano: Tetsu-to-Hagané, 1985, vol. 71, pp. 823–30.
I. Iwasaki: Bunseki-Kagaku-Gaisetsu, Gakujyutsu-Tosyo, Tokyo, 1960, p. 145.
J. Chipman: Phys. Chem. Proc. Metall., 1961, pp. 27–64.
P.T. Carter and T. MacFarlane: J. Iron Steel Inst., 1957, vol. 185 pp. 54–66.
F. Tsukihashi and N. Sano: Tetsu-to-Hagané, 1985, vol. 71, pp. 815–22.
J.A. Duffy and M.D. Ingram: Phys. Chem. Glasses, 1975, vol. 16, pp. 119–23.
T. Nakamura, Y. Ueda, and J.M. Toguri: J. Jpn. Inst. Met., 1986, vol. 50, pp. 456–61.
J.M. Duffy: Ironmaking and Steelmaking, 1989, vol. 16, pp. 426–28.
J.M. Duffy: Ironmaking and Steelmaking, 1990, vol. 17, pp. 410–13.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Nakamura, S., Sano, N. Solubility of platinum in molten fluxes as a measure of basicity. Metall Mater Trans B 28, 103–108 (1997). https://doi.org/10.1007/s11663-997-0132-1
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11663-997-0132-1