Abstract
New compounds with the rosiaite type structure LaM1/3Sb5/3O6, M = Co, Ni, and Cu, were synthesized. The compounds belong to quasi-two-dimensional magnets, in which magnetic interactions occur in the layers with a honeycomb structure. It is shown that there is no long-range magnetic order in these compounds. The temperature and field dependences of the magnetization in the compounds with M = Co, Ni indicate the presence of short-range anti-ferromagnetic and ferromagnetic exchange interactions. In the LaM1/3Sb5/3O6, M = Co, Ni, compounds, the interactions occur between Co2+ or Ni2+ ions of isolated magnetic clusters randomly distributed in the paramagnetic matrix in the chains of (M/Sb)O6 octahedrons. These clusters have sizes comparable with the crystal cell size. The LaCu1/3Sb5/3O6 compound is paramagnetic.
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This work was financially supported by the Ministry of Education and Science of the Russian Federation within the framework of the state task of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.
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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 80th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2397–2404, December, 2021.
The studies were carried out using the equipment of the Center of Collective Usage of Physical Research Methods at the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.
This paper does not contain descriptions of studies on animals or humans.
The authors declare no competing interests.
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Ellert, O.G., Egorysheva, A.V., Golodukhina, S.V. et al. Magnetic properties of new layered compounds LaM1/3Sb5/3O6, M = Co, Ni, and Cu, with a honeycomb structure. Russ Chem Bull 70, 2397–2404 (2021). https://doi.org/10.1007/s11172-021-3359-0
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DOI: https://doi.org/10.1007/s11172-021-3359-0