Abstract
The review analyzes the effects of the reaction conditions on the direction of the reactions between furans/formylfurans and hydrogen peroxide. The revealed dependences serve for the synthesis of the desired products and for development of new methods to access α-hydroxy hydroperoxides of furan aldehydes, 2-furanoic acid and its esters and amides, a series of furoic acids bearing the substituent at the furan ring, 2(5H)-furanone and its homologs and functional derivatives, as well as 2,5-dialkoxydihydrofurans. The developed procedures are more advantageous than the conventional methods.
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Based on the materials of International Congress on the Heterocyclic Chemistry "KOST-2015" (October 18—23, 2015, Moscow, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0593—0599, April, 2017.
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Badovskaya, L.A., Poskonin, V.V. & Povarova, L.V. Synthesis of functional furan derivatives by oxidation of furans and formylfurans with hydrogen peroxide. Russ Chem Bull 66, 593–599 (2017). https://doi.org/10.1007/s11172-017-1778-8
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DOI: https://doi.org/10.1007/s11172-017-1778-8