Abstract
The kinetics of the initial stage of the furfural reaction with hydrogen peroxide was studied in water in the presence of Na2MoO4 and in n-butanol without a catalyst. The mechanisms of furfural conversion in the Na2MoO4-H2O2 system and oxidation by hydrogen peroxide in the absence of sodium molybdate are discussed. Based on kinetic studies, the mechanism of furan peroxide formation is proposed.
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Proceedings of X International Conference on Chemistry of Organic and Organoelement Peroxides (Moscow, June 16–18, 1998).
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Grunskaya, E.P., Badovskaya, L.A., Kaklyugina, T.Y. et al. Kinetics and mechanism of the furan peroxide formation in the reaction of furfural with hydrogen peroxide in the presence or absence of sodium molybdate. Kinet Catal 41, 447–450 (2000). https://doi.org/10.1007/BF02756060
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DOI: https://doi.org/10.1007/BF02756060