Abstract
An online analytical system using ion chromatography (IC) followed by inductively coupled plasma mass spectrometry (ICP-MS) was developed for the separate determination of I− and IO −3 in aqueous solutions with a detection limit 0.1–1 μg 1/1. The total iodine concentration was also directly determined by ICP-MS. Iodine in several environmental samples (i.e., rain, river water, brine, and soil solution) was successfully determined with information on its chemical form. The release of I− into soil solution with decreasing Eh was observed in an incubation experiment with flooded soil. An iodine form other than I− and IO −3 was observed in several environmental samples.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
B. Schnetger, Y. Muramatsu, S. Yoshida, Geostand. Newslett., 22 (1998) 181.
M. H. Gerzabek, Y. Muramatsu, F. Strebl, S. Yoshida, J. Plant Nutr. Soil. Sci., 162 (1999) 415.
Y. Muramatsu, U. Fehn, S. Yoshida, Earth Planet. Sci. Lett., 192 (2001) 583.
V. V. Salov, J. Yoshinaga, Y. Shibata, M. Morita, Anal. Chem., 64 (1992) 2425.
K. G. Heumann, L. Rottmann, J. Vogl, J. Anal. Atom. Spectrom., 9 (1994) 1351.
D. C. Whitehead, Environ. Intern., 10 (1984) 321.
J. B. Luten, J. R. W. Woittiez, H. A. Das, C. L. De Ligny, J. Radioanal. Chem., 43 (1978) 175.
S. Yoshida, Y. Muramatsu, S. Uchida, Water Air Soil Pollut., 63 (1992) 321.
S. Yoshida, Y. Muramatsu, S. Uchida, Radiochim. Acta, 82 (1998) 293.
Y. Muramatsu, S. Yoshida, S. Uchida, A. Hasabe, Water Air Soil Pollut., 86 (1996) 359.
Y. Muramatsu, S. Yoshida, Geomicrobiol. J., 16 (1999) 85.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yoshida, S., Muramatsu, Y., Katou, S. et al. Determination of the chemical forms of iodine with IC-ICP-MS and its application to environmental samples. J Radioanal Nucl Chem 273, 211–214 (2007). https://doi.org/10.1007/s10967-007-0738-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-007-0738-4