Abstract
A DTA study of thermal decomposition of (NH4)2[Ru(NO)Cl5] in helium atmosphere has been carried out, a synthetic procedure for preparation of the trans-diammine complex mer-[Ru(NO)(NH3)2Cl3] (I) with yield ∼70% has been developed. On re-crystallization of I from aqueous solution a trans-aquanitroso complex [Ru(NO)(NH3)2Cl2(H2O)]Cl·H2O (II) has been isolated. The structures of the compounds have been determined by single crystal X-ray diffraction: space group Pbcn, a = 6.607(1) Å b = 11.255(2) Å c = 9.878(2) Å (I) and space group Ima2, a = 8.3032(3) Å, b = 8.0890(2) Å, c = 15.9192(5) Å II).
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Original Russian Text Copyright © 2008 by M. A. Il’in, V. A. Emel’yanov, and I. A. Baidina
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Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 6, pp. 1128–1136, November–December, 2008.
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Il’in, M.A., Emel’yanov, V.A. & Baidina, I.A. Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl·H2O. J Struct Chem 49, 1090–1097 (2008). https://doi.org/10.1007/s10947-008-0183-4
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DOI: https://doi.org/10.1007/s10947-008-0183-4