Abstract.
A method was developed for the determination of trichloroanisole, tribromoanisole and pentachloroanisol by solid-phase microextraction and gas chromatography in paper samples (Kraft liner, Test liner and Miolo). Four commercial SPME fibers were evaluated: Polydimethylsiloxane (PDMS), Polyacrylate (PA), Carbowax/Divinylbenzene (CW/DVB) and Divinylbenzene/Carboxen/Polydimethylsiloxane (DVB/CAR/PDMS). DVB/CAR/PDMS gave the best results and was therefore selected. Other variables involved in the extraction procedure were studied and optimized, such as: sample volume, salting-out effect, temperature and extraction time, effect of organic solvent and previous sample preparation. Optimum conditions were obtained using 20 mL of sample with 5 mol L−1 NaCl in a 40 mL vial, extraction temperature of 70 °C and sonication and extraction time of 30 and 40 min, respectively. Detection limits ranged from 0.43 to 1.32 ng g−1 for all analytes. Recoveries between 70 and 100% were obtained and relative standard deviation was below 10% for all compounds.
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Martendal, E., Budziak, D., Debastiani, R. et al. Determination of haloanisoles in paper samples for food packaging by solid-phase microextraction and gas chromatography. Microchim Acta 159, 229–234 (2007). https://doi.org/10.1007/s00604-007-0746-7
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DOI: https://doi.org/10.1007/s00604-007-0746-7