Abstract
The changes of the free energy, enthalpy and entropy accompanying the extraction of the U/VI/, Np/VI/ and Pu/VI/ by TBP have been determined by the method of extraction chromatography. The results obtained indicate outer-sphere complexation.
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Fuks, L., Fidelis, I. Thermodynamic studies of complex formation of actinyl ions extracted with TBP from hydrochloric and nitric acids. Journal of Radioanalytical and Nuclear Chemistry Letters 118, 361–368 (1987). https://doi.org/10.1007/BF02170469
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DOI: https://doi.org/10.1007/BF02170469