Abstract
Adonitol is oxidized to ribose by Mn(III) pyrophosphate under the conditions [adonitol] ≫ [Mn(III)]. The oxidation rate is first order with respect to both oxidatn and substrate and decreases inversly with [pyrophosphate]free. Thermodynamic parameters are reported and a suitable mechanism involving free radicals is proposed.
Abstract
Адонитол окисляется до рибозы пирофосфатом марганца(III) в условиях [адонитол]≫ [Mn(III)]. Скорость окисления подчиняется закону первого порядка как по окислителю, так и по субстрату и уменьшается обратно-пропорционально [пирофосфат]своб. Приводятся термодинамические параметры и вероятный свободно-радикальный механизм реакции.
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References
M. G. Ram Reddy, B. Sethuram, T. Navneet Rao: Curr. Sci. (India),42, 677 (1973).
A. Meenakshi, M. Santappa: J. Catal.,19, 300 (1970).
A. G. Fadnis, S. K. Kulshrestha: J. Indian Chem. Soc., 763 (1981).
R. P. Bhatnagar, A. G. Fadnis: Montash. Chem.,109, 319 (1978).
I. M. Kolthoff, J. I. Watters: J. Amer. Chem. Soc.,70, 2455 (1948).
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Fadnis, A.G., Kulshrestha, S.K. Kinetics of oxidation of adonitol by manganese(III) pyrophosphate. React Kinet Catal Lett 19, 267–269 (1982). https://doi.org/10.1007/BF02074043
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DOI: https://doi.org/10.1007/BF02074043