Abstract
Relative oxidation rate constants of several normal, iso-, cyclo-and methylcycloalkanes have been measured in Cl2−H2O and Cl2−Hg2+−H2O solutions at 343K. The selectivity of C−H bond dissociation in both systems is the same. HOCl is assumed to be the active species for the two systems.
Abstract
В растворах Cl2−H2O и Cl2−Hg2+−H2O при 343 К измерены относительные константы скорости окисления ряда нормальных, изо-,цикло-и метилциклоалканов; селективность расщелления C−H связи в обеих системах одинакова. Заключено, что активной частицей в обеих системах является кислота HOCl.
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Rudakov, E.S., Volkova, L.K. & Tretiakov, V.P. Kinetics and selectivity of the oxidation of alkanes in Cl2−H2O and Cl2−Hg2+−H2O solutions. React Kinet Catal Lett 21, 357–360 (1982). https://doi.org/10.1007/BF02070639
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DOI: https://doi.org/10.1007/BF02070639