Abstract
A treatment of the kinetics of internal oxidation of ternary alloys in the absence of an external scale is presented. The analysis involves simultaneous internal oxidation of the two solutes in the ternary alloys. A comparison with measurements on Ni-4 at.% Al-1 at.% Si alloys at 800°C reveals a good agreement between theory and experiment.
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F. H. Rhines, W. A. Johnson, and W. A. Anderson,Trans. AIME 147, 205 (1942).
C. Wagner,Z. Elektrochem. 63, 772 (1959).
R. A. Rapp,Corrosion 21, 382 (1965).
H. L. Toor,AIChE J.,10, 460 (1964).
H. C. Yi, S. W. Guan, W. W. Smeltzer, and A. Petric,Acta Metall. 42, 981 (1994).
M. Hansen,Constitution of Binary Alloys (McGraw-Hill, New York, 1958), p. 1025.
J. Park and C. J. Altstetter,Met. Trans. 18A, 43 (1987).
J. S. Kirkaldy and D. J. Young,Diffusion in the Condensed State (The Institute of Metals, London, 1987), p. 237.
K. Chou,Calphad 11, 293 (1987).
L. Kaufman and H. Nesor,Calphad 2, 325 (1978).
L. Kaufman,Calphad 3, 45 (1979).
D. Ludecke,Z. Metallk. 77, 279 (1986).
R. A. Swalin, A. Martin, and R. Olson,J. Metals 9, 936 (1957).
W. Gust, M. B. Hints, A. Lodding, H. Odelius, and B. Predel,Phys. State. Sol. 64, 187 (1981).
P. Neuhaus and C. Herzig,Z. Metallk. 79, 595 (1988).
F. H. Stott and G. C. Wood,Mater. Sci. Technol. 4, 1072 (1988).
S. Guruswamy, S. M. Park, J. P. Hirth, and R. A. Rapp,Oxid. Met. 26, 77 (1986).
J. R. Machert, R. D. Ringle, and C. W. Fairhurst,J. Dent. Res. 62, 1229 (1983).
R. P. Rubly and D. L. Douglass, inHigh Temperature Corrosion of Advanced Materials and Protective Coatings, Y. Saito, B. Önay, and T. Maruyama, eds. (Elsevier, Amsterdam, 1992), p. 133.
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Guan, S.W., Yi, H.C. & Smeltzer, W.W. Internal oxidation of ternary alloys. Part I: Kinetics in the absence of an external scale. Oxid Met 41, 377–387 (1994). https://doi.org/10.1007/BF01113372
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DOI: https://doi.org/10.1007/BF01113372