Abstract
The oxidation of a number of lignin species by molecular oxygen was studied. The selectivity of the process was found to be close to that of the oxidation with nitrobenzene. The influence of lignin origin on the yields of vanillin and syringaldehyde as well as the correlation between the rates of wood delignification and the aldehydes formation are discussed.
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K. Kyurshner,Zh. Prikl. Khim., 1955,28, 956 [J. Appl. Chem. USSR, 1955,28 (Engl. Transl.)]
M. I. Chudakov,Promyshlennoe ispol'zovanie lignina [Industrial Use of Lignin], Lesn. Prom., Moscow, 1983, 42 (in Russian).
O. P. Grushnikov and V. V. Jolkin,Dostizheniya i problemy khimii lignina [Progress and Problems of the Chemistry of Lignin], Nauka, Moscow, 1973, 189 (in Russian).
J. M. Pepper and B. W. Casselman,Can. J. Chem, 1967,45, 3009.
B. Leopold and I. L. Malmstrom,Acta Chem. Scand., 1952,6, 49.
H. Hibbert,J. Am. Chem. Soc., 1941,63, 3049.
W. G. Simson and E. Sondhimer,TAPPI Journal, 1960,43, 1025.
J. Wozniak and D. R. Dimmel,J. Wood Chem. and Techn., 1989,9, 491.
N. G. Moskovtsev and S. A. Strel'skaya,Khimiya drevesiny [Wood Chemistry], 1986, N 1, 63 (in Russian).
B. Leopold,Svensk Kem. Tidskr., 1951,63, 260.
Z. N. Kreitsberg,Tr. In-ta lesokhosjaistvennykh problem AN Latv. SSR [Proceedings of the Institute of Forestry Problems of the Academy of Sciences of Latv. SSR], 1955,8, 55 (in Russian).
G. A. Chirkin and D. V. Tishchenko,Zh. Prikl. Khim., 1962,1, 153 [J. Appl. Chem. USSR], 1962,1 (Engl. Transl.)].
R. B. Epshtein,Tr. Ukr. NII pishchevoi promyshlennosti [Proceedings of the Ukrainian Institute of the Food Industry], 1959,2, 201 (in Russian).
V. E. Taraban'ko, A. V. Kudrjashev, G. R. Gul'bis, and N. V. Koropachinskaya, inProblemy okislit'el'no-vosstanovitel'nykh prevrashchenii komponentov drevesiny. Tez. dokl. mezhdunar. konf. [Problems of Oxidative-Reductive Transformations of Components of Wood, Abstr. of Papers of Int. Conf.], Arkhangel'sk, 1992, 85 (in Russian).
O. D. Kamaldina and Ya. A. Massov,Poluchenie vanilina iz lignosulfonatov [Production of Vanillin from Lignosulfonates], TsBTI TsINIS, Moscow, 1959 (in Russian).
F. E. Brauns and D. A. Brauns,Khimiya lignina [Chemistry of Lignin], Lesn. Prom., Moscow, 1964 (in Russian).
V. Ripachek,Biologiya derevorazrushayushchikh gribov [Biology of Wood-destroying Fungi], Lesn. Prom., Moscow, 1967 (in Russian).
K. A. Kalun'yants, E. F. Shanenko, and L. V. Zaitseva,Itogy nauki i tekhniki, Ser. khimiya i tekhnologiya pishchevykh produktov [Results of Sciense and Industry, Div. of Chemistry and Technology of Foods], Moscow, 1988,1, 3 (in Russian).
T. N. Kleinert,TAPPI Journal, 1966,49, 53.
K. Forss, R. Kokkonen, and P. E. Sagfors, inInt. Symp. Wood and Pulp Chem, Raleigh, N. C., Atlanta, 1989, 411.
V. E. Taraban'ko, A. V. Kudrjashev, G. R. Gul'bis, and N. V. Koropachinskaya, inProblemy okislit'el'no-vosstanovitel'nykh prevrashchenii komponentov drevesiny. Tez. dokl. mezhdunar. konf. [Problems of Oxidative-Reductive Transformations of Components of Wood, Abstr. of Papers of Int. Conf.], Arkhangelsk, 1992, 64 (in Russian).
Pat. USA 2434626, 1948;Chem. Abstr., 2403h,42, 1948.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 375–379, February, 1995.
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Taraban'ko, V.E., Koropatchinskaya, N.V., Kudryashev, A.V. et al. Influence of lignin origin on the efficiency of the catalytic oxidation of lignin into vanillin and syringaldehyde. Russ Chem Bull 44, 367–371 (1995). https://doi.org/10.1007/BF00702154
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DOI: https://doi.org/10.1007/BF00702154