Abstract
Results are given on the angular dependence of these effects for radicals stabilized in a γ-irradiated single crystal of malonic acid. The modulation is ascribed to anisotropic hyperfine interaction with the α proton of CH(COOH)2. The results allow electron spin echo to be used in certain cases to measure small splittings in the ESR spectra of free radicals.
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References
E. L. Hahn and D. E. Maxwell, Phys. Rev., 88, 1070, 1952.
L. G. Rowan, E. L. Hahn, and W. B. Mims, Phys. Rev., 137A, 61, 1962.
A. M. Raitsimring, Yu. D. Tsvetkov, G. M. Zhiromirov, V. E. Khmelinskii, and A. G. Semenov, DAN SSSR, 172, 895, 1962.
E. L. Hahn, Phys. Rev., 80, 580, 1950.
J. A. Goedhoop and C. H. MacGillary, Acta Cryst., 10, 195, 1957.
H. M. McConnell, C. Heller, T. Cole, and R. W. Fessenden, Chem. Phys., 82, 766, 1959.
G. M. Zhidomirov and K. M. Salikhov, TEKh [Theoretical and Experimental Physics], 4, 514, 1968.
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We are indebted to G. M. Zhidomirov, K. M. Salikhov, and A. I. Burshtein for discussions, and to V. E. Khmelinskii and M. D. Shchirov for assistance with the experiments.
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Yudanov, V.F., Raitsimring, A.M. & Tsvetkov, Y.D. Modulation effects in the spin-echo signals of CH(COOH)2 radicals. Theor Exp Chem 4, 335–338 (1971). https://doi.org/10.1007/BF00524128
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DOI: https://doi.org/10.1007/BF00524128