Summary
The title head-functionalized block copolymer was synthesized by first preparing a polyisobutylene carrying a (CH3)2C=CH2-head-group and -Cl end-group, and subsequently starting the block copolymerization of α-methylstyrene from the -Cl terminus.
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7th in the series: Cationic Polymerization with Boron Halides.
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Kennedy, J.P., Huang, S.Y. & Smith, R.A. The synthesis of an isobutylene-α-methylstyrene block copolymer with olefinic head-group: (CH3)2C=CHCH2-PIB-b-PαMeSt. Polymer Bulletin 1, 371–376 (1979). https://doi.org/10.1007/BF00284405
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DOI: https://doi.org/10.1007/BF00284405