Abstract
Micro-organic compounds are ubiquitous in aquatic environments, occurring both in solution and in association with particles and colloids. Many of the compounds are of anthropogenic origin and are classed as pollutants although not toxic at the concentrations that are commonly encountered. Their transport and persistence in the environment are complex topics needing detailed information about the compound’s specific chemical structure, biochemistry and properties, as well as the solution composition. In general, the fate of the compounds is determined by a combination of parameters including vapour pressure, volatility, aqueous solubility, chemical/biochemical degradation and interaction with solid surfaces. It has been known for some time that organic compounds can interact with clay minerals, and be involved in both ion-exchange reactions and also penetration of the interlayer space of expandable clays (Rausell-Colom and Serretosa 1978).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Bailey GW, White JL, Rothberg T (1968) Adsorption of organic herbicides by montmorillonite: role of pH and chemical character of adsorbate. Soil Sci Soc Am Proc 32: 222–234
Bernstein F (1960) Distribution of water and electrolyte between homoionic clays and saturated NaCl solution. Clays Clay Miner 8: 122–149
Calvet R (1989) Adsorption of organic chemicals in soils. Environ Health Perspect 83: 145–177
Calvet R, Terce M (1975) Adsorption de l’atrazine par des montmorillonites-Al. Ann Agron 26: 693–707
Charalambos P, Hayes KF (1966) Distinguishing between interlayer and external sorption sites of clay minerals using X-ray absorption spectroscopy. Colloids 107: 89–96
Clarke CD (1972) Influence of pH on the adsorption of benzoic acid by kaolin. Pharm J 209: 44–45
Costerton JW, Lewandowski Z, deBeer D, Caldwell D, Korber D, James G (1994) Biofilms, the customized microniche. J Bacteriol 176: 2137–2142
Cruz M, White JL, Russell JD (1968) Montmorillonite-s-triazine interaction. Isr J Chem 6: 315–323
ECETOC (1993) DHTDMAC: Aquatic and terrestrial hazard assessment. European centre for Ecotoxicology and Toxicology of Chemicals, Technical Repaort No 53, Brussels
Everett DH (1992) Basic principles in colloid science. Royal Society of Chemistry, London
Farmer VC, Mortland MM (1966) Infrared study of the coordination of pyridine and water to exchangeable cations in montmorillonite and saponite. J Chem Soc (A): 344–351
Fox LE (1991) Phosphorus chemistry in the tidal Hudson river. Geochim Cosmochim Acta 55: 1529–1538
Francioso O, Bak E, Rossi N, Sequi P (1992) Sorption of atrazine and trifluralin in relation to the physico-chemical characteristics of selected soils. Sci Total Environ 123 /124: 503–512
Fruhstorfer P, Schneider RJ, Weil L, Niessner R (1993) Factors influencing the adsorption of atrazine on montmorillonitic and kaolinitic clays. Sci Total Environ 138: 317–328
Gilchrist GFR, Gamble DS, Kodama H, Khan SU (1993) Atrazine interactions with clay minerals: kinetics and equilibria of sorption. J Agric Food Chem 41: 1748–1755
Goswami KP, Green RE (1971) Microbial degradation of the herbicide atrazine and its 2-hydroxy analog in submerged soils. Environ Sci Technol 5: 426–429
Grim RE, Allaway WH, Cuthbert FL (1947) Reaction of different clay minerals with some organic cations. J Am Ceram Soc 30: 137–142
Grundl T, Small G (1993) Mineral contributions to atrazine and alachlor sorption in soil mixtures of variable organic carbon and clay content. J Contam Hydrol 14: 117–128
Hedges JI, Hare PE (1987) Amino acid adsorption by clay minerals in distilled water. Geochim Cosmochim Acta 51: 255–259
Hendricks SB (1941) Base exchange of clay mineral montmorillonite for organic cations and its dependence upon adsorption due to van der Waals’ forces. J Phys Chem Ithaca 45: 65–81
Hermosin MC, Cornejo J, White JL, Hess FD (1982) Bioavailability of s-triazines adsorbed on montmorillonite. J Agric Food Chem 30: 728–733
Hiemstra T, van Riemsdijk WH, Bruggenwert MGM (1987) Proton adsorption mechanism at the gibbsite and aluminium oxide solid/solution interface. Neth J Agric Sci 35: 281–293
House WA (1994) The role of surface complexation in the dissolution kinetics of silica: effects of monovalent and divalent ions at 25°C. J Colloid Interface Sci 163: 379–390
House WA, Farr IS (1989) Adsorption of sulphonates from detergent mixtures on potassium kaolinite. Colloids Surf 40: 167–180
House WA, Orr DR (1992) Investigation of the pH dependence of the kinetics of quartz dissolution at 25°C. J Chem Soc Faraday Trans 88: 233–241
House WA, Ou Z (1992) Determination of pesticides on suspended solids and sediments: investigation of the handling and separation. Chemosphere 24: 819–832
House WA, Rae JE, Kimblin RT (1992) Source-sediment controls on the riverine transport of pesticides. Brighton Crop Protection Conference-Pests and Diseases, 1992, pp 865–870
Khan SU (1974) Adsorption of linuron by montmorillonite. Can J Soil Sci 54 235–237
Knight BAG, Denny PJ (1970) The interaction of paraquat with soil: adsorption by an expanding lattice clay mineral. Weed Res 10: 40–48
Kookana RS, Aylmore AG, Gerritse RG (1992) Time-dependent sorption of pesticides during transport in soils. Soil Sci 154: 214–225
Kuchler-Krischun J, Kleiner J (1990) Heterogenously nucleated calcite precipitation in Lake Constance. A short time resolution study. Aquat Sci 52: 176–197
Kummert R, Stumm W (1980) Surface complexation of organic acids on hydrous g-Al203. J Colloid Interface Sci 75: 373–385
Laird DA, Barriuso E, Dowdy RH, Koskinen WC (1992) Adsorption of atrazine on smectites. Soil Sci Soc Am J 56: 62–67
Marchesi JR, House WA, White GF, Russell NJ (1991a) A comparative study of the adsorption of linear alkyl sulphates and alkylbenzene sulphonates on river sediment. Colloids Surf 53: 63–78
Marchesi JR, Russell NJ, White GF, House W (1991b) Effects of surfactant adsorption and biodegradability on the distribution of bacteria between sediments and water in a freshwater microcosm. Appl Environ Microbiol 57: 2507–2513
Monticone V, Treiner C (1995) Effect of pH and ionic strength on the adsorption of cetylpyridinium chloride and the co-adsorption of phenoxypropanol at a silica/ water interface. Colloids Surf 104: 285–293
Morillo E, Perez-Rodriguez JL, Maqueda C (1991) Mechanisms of the interaction between montmorillonite and 3-aminotriazole. Clay Miner 26: 269–279
Newman ACD, Brown G (1987) The chemical constitution of clays. In: Newman ACD (ed) Chemistry of clays and clay minerals. Mineralogical Soc Mon No 6. Longman Harlow, New York, pp 1–129
Papelis C, Hayes KF (1996) Distinguishing between interlayer and external sorption sites of clay minerals using X-ray absorption spectroscopy. Colloids Surf 107: 89–96
Peker S, Yaper S, Besun N (1995) Sorption behaviour of a cationic surfactant on montmorillonite. Colloids Surf 104: 249–257
Poirier JE, Cases JM (1991) Anionic surfactant adsorption onto silicate minerals. The role of cations. Colloids Surf 55: 333–344
Rausell-Colom JA, Serretosa JM (1978) Reactions of clays with organic substances. In: Newman ACD (ed) Chemistry of clays and clay minerals. Mineralogical Soc Mon No 6. Longman Harlow, New York, pp 371–422
Rennie AR, Lee EM, Simister EA, Thomas RK (1990) Structure of cationic surfactant layer at the silica-water interface. Langmuir 6: 1031–1034
Rupprecht H, Gu T (1991) Structure of adsorption of layers of ionic surfactants at the solid/liquid interface. Colloid Polymer Sci 269: 506–522
Russell JD, Cruz MI, White JL (1968) The adsorption of 3-aminotriazole by montmorillonite. J Agric Food Chem 16: 21–24
Schindler PW, Stumm W (1987) The surface chemistry of oxides, hydroxides and oxide minerals. In: Stumm W (ed) Aquatic surface chemistry. Wiley-Interscience, New York, pp 83–100
Sims GK, O’Loughlin EJ (1989) Degradation of pyridines in the environment. Crit Rev Environ Control 19:3o9–34o
Skipper HD, Volk VV (1972) Biological and chemical degradation of atrazine in three Oregon soils. Weed Sci 20: 344–347
Tipping E (1990) Interactions of organic acids with inorganic and organic surfaces. In: Perdue EM, Gjessing GT (eds) Organic acids in aquatic ecosystems. Wiley, New York, pp 209–221
Van Bladel R, Moreale A (1974) Adsorption of fenuron and monuron (substituted ureas) by two montmorillonite clays. Soil Sci Soc Am Proc 38: 244–249
Velde B (1992) Introduction to clay minerals. Chapman and Hall, London
Wayman CH (1963) Surfactant sorption on heteroionic clay minerals. In: Rosenquist IT (ed) International clay conference proceedings. Macmillan, New York, 376 pp
Weber JB (1970) Adsorption of s-triazines by montmorillonite as a function of pH and molecular structure. Soil Sci Soc Am Proc 34: 401–404
Wehrli B, Wieland E, Furrer G (1990) Chemical mechanisms in the dissolution kinetics of minerals; the aspects of active sites. Aquat Sci 52: 1–31
Wieland E, Wehrli B, Stumm W (1988) The coordination chemistry of weathering. I. A generalisation on the dissolution rates of minerals. Geochim Cosmochim Acta 52: 1969–1981
Wu S, Gschwend PM (1986) Sorption kinetics of hydrophobic organic compounds to natural sediments. Environ Sci Technol 20: 717–7725
Zachara JM, Ainsworth CCD, Cowan CE, Thomas BL (1987) Sorption of binary mixtures of aromatic heterocyclic compounds on subsurface materials. Environ Sci Technol 21: 397–405
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
House, W.A. (1998). Interactions of Non-Volatile Micro-organic Pollutants and Clay Minerals in Surficial Environments. In: Parker, A., Rae, J.E. (eds) Environmental Interactions of Clays. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03651-8_4
Download citation
DOI: https://doi.org/10.1007/978-3-662-03651-8_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-08208-5
Online ISBN: 978-3-662-03651-8
eBook Packages: Springer Book Archive