Abstract
A combination of photochromism and other molecular functionalities is an efficient way to constructnovel multi-mode photofunctional molecules. From this perspective, a considerable number of photochromicmetal complexes involving photochromic moieties and coordination compounds with unique electronic, magneticand optical properties have been investigated. One research point of interest in the photochromic complexesfocuses on how metal coordination affects the isomerization behavior of the photochromic moiety. Propermolecular structural design can more strongly stabilize a metastable state in support of feasible metal–ligandinteractions, improving the thermal durability of the molecular photomemory. Moreover, isomerization canbe caused not only by the excitation at the photochromic moiety, but also by the stimulation (light or electron)at the metal complex moiety. The multi-moiety combined response may be able to construct an integratedmemory or a logic gate in a single molecule. Another research point of interest focuses on howstructural conversion at the photochromic moiety affects electromagnetic properties at the complex moiety.Several studies have shown how photon information/energy is converted to luminescence, an electronic signal,or a magnetic response at the complex moiety. Interactions between multiple complex moieties can alsobe reversibly tuned with light when the photochromic moiety is used as a spacer between them. Herewe review recent studies on the combination of photochromic moieties with coordination compounds, categorizingthe research findings according to the structure of the photochromic moieties.
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Irie M (ed) (2000) Chem Rev 100:1683
Joachim C, Gimzewski JK, Aviram A (2000) Nature 408:541
Phillips JP, Mueller A, Przystal F (1965) J Am Chem Soc 87:4020
Wojtyk JTC, Kazmaier PM, Buncel E (2001) Chem Mater 13:2547
Wojtyk JTC, Kazmaier PM, Buncel E (1998) Chem Commun, p 1703
Chibisov AK, Görner H (1998) Chem Phys 237:435
Atabekyan LS (2002) High Energy Chemistry 36:397
Collins GE, Choi L-S, Ewing KJ, Michelet V, Bowen CM, Winkler JD (1999) Chem Commun 321
Evans L, Collins GE, Shaffer RE, Michelet V, Winkler JD (1999) Anal Chem 71:5322
Tanaka M, Nakamura M, Salhin MAA, Ikeda T, Kamada K, Ando H, Shibutani Y, Kimura K (2001) J Org Chem 66:1533
Keiichi K, Sakamoto H, Kado S, Arakawa R, Yokoyama M (2000) Analyst 125:1091
Kimura K, Sakamoto H, Uda RM (2004) Macromolecules 37:1871
Nagashima S, Murata M, Nishihara H (2006) Angew Chem Int Ed 45:4298
Strokach YP, Fedorova OA, Gromov SP, Koshkin AV, Valova TM, Barachevsky VA, Alfimov MV, Lokshin VA, Samat A, Guglielmetti R (2002) Russ Chem Bull 51:58
Jeliazkova BG, Minkovska S, Deligeorgiev T (2005) J Photochem Photobiol A: Chem 171:153
Minkovska S, Fedieva M, Jeliazkova B, Deligeorgiev T (2004) Polyhedron 23:3147
Bulanov AO, Luk'yanov BS, Kogan VA, Stankevich NV, Lukov VV (2002) Russ J Coord Chem 28:46
Ushakov EN, Nazarov VB, Fedorova OA, Gromov SP, Chebun'kova AV, Alfimov MV, Barigelletti F (2003) J Phys Org Chem 16:306
Ahmed SA, Tanaka M, Ando H, Iwamoto H, Kimura K (2004) Tetrahedron 60:3211
Yam VW-W, Ko C-C, Wu L-X, Wong KM-C, Cheung K-K (2000) Organometallics 19:1820
Ko C-C, Wu L-X, Wong KM-C, Zhu N, Yam VW-W (2004) Chem Eur J 10:766
Yuan W, Sun L, Tang H, Wen Y, Jiang G, Huang W, Jiang L, Song Y, Zhu D (2005) Adv Mater 17:156
Irie M, Mohri M (1988) J Org Chem 53:803
Irie M (2000) Chem Rev 100:1685
Fernández-Acebes A, Lehn J-M (1998) Adv Mater 10:1519
Fernández-Acebes A, Lehn J-M (1999) Chem Eur J 5:3285
Fraysse S, Coudret C, Launay J-P (2000) Eur J Inorg Chem 1581
Jukes RTF, Adamo V, Hartl F, Belser P, De Cola L (2004) Inorg Chem 43:2779
Yam VW-W, Ko C-C, Zhu N (2004) J Am Chem Soc 126:12734
Ko C-C, Kwok W-M, Yam VW-W, Phillips DL (2006) Chem Eur J 12:5840
Konaka H, Wu LP, Munakata M, Kuroda-Sowa T, Maekawa M, Suenaga Y (2003) Inorg Chem 42:1928
Takayama K, Matsuda K, Irie M (2003) Chem A Eur J 9:5605
Matsuda K, Takayama K, Irie M (2004) Inorg Chem 43:482
Matsuda K, Shinkai Y, Irie M (2004) Inorg Chem 43:3774
Qin B, Yao R, Zhao X, Tian H (2003) Org Biomol Chem 1:2187
Tian H, Qin B, Yao R, Zhao X, Yang S (2003) Adv Mater 15:2104
Zarnegar PP, Whitten DG (1971) J Am Chem Soc 93:3776
Zarnegar PP, Bock CR, Whitten DG (1973) J Am Chem Soc 95:4367
Boillot M-L, Roux C, Audière J-P, Dausse A, Zarembowitch J (1996) Inorg Chem 35:3975
Yam VW-W, Lau VC-Y, Cheung K-K (1995) J Chem Soc Chem Commun, p 259
Yam VW-W, Lau VC-Y, Cheung K-K (1995) J Chem Soc Chem Commun, p 1195
Yam VW-W, Lau V C-Y, Wu L-X (1998) Dalton Trans 1461
Wenger OS, Henling LM, Day MW, Winkler JR, Gray HB (2004) Inorg Chem 43:2043
Busby M, Matousek P, Towrie M, Vlček A Jr (2005) J Phys Chem A 109:3000
Yam VW-W, Yang Y, Zhang J, Chu BW-K, Zhu N (2001) Organometallics 20:4911
Tsuchiya S (1999) J Am Chem Soc 121:48
Kurihara M, Nishihara H (2002) Coord Chem Rev 226:125
Nishihara H (2004) Bull Chem Soc Jpn 77:407
Nishihara H (2005) Coord Chem Rev 249:1468
Yutaka T, Kurihara M, Nishihara H (2000) Mol Cryst Liq Cryst 343:193
Yutaka T, Kurihara M, Kubo K, Nishihara H (2000) Inorg Chem 39:3438
Yutaka T, Mori I, Kurihara M, Mizutani J, Kubo K, Furusho S, Matsumura K, Tamai N, Nishihara H (2001) Inorg Chem 40:4986
Yutaka T, Mori I, Kurihara M, Tamai N, Nishihara N (2003) Inorg Chem 42:6306
Otsuki J, Omokawa N, Yoshiba K, Yoshikawa I, Akasaka T, Suenobu T, Takido T, Araki K, Fukuzumi S (2003) Inorg Chem 42:3057
Yutaka T, Mori I, Kurihara M, Mizutani J, Tamai N, Kawai T, Irie M, Nishihara H (2002) Inorg Chem 41:7143
Kume S, Kurihara M, Nishihara H (2001) Chem Commun 1656
Kume S, Kurihara M, Nishihara H (2002) J Korean Electrochem Soc 5:189
Yamaguchi K, Kume S, Namiki K, Murata M, Tamai N, Nishihara H (2005) Inorg Chem 44:9056
Kume S, Kurihara M, Nishihara H (2003) Inorg Chem 42:2194
Kume S, Murata M, Ozeki T, Nishihara H (2005) J Am Chem Soc 127:490
Kunkely H, Vogler A (2001) J Organomet Chem 637–639:777
Kurihara M, Matsuda M, Hirooka A, Yutaka T, Nishihara H (2000) J Am Chem Soc 122:12373
Kurihara M, Matsuda T, Hirooka A, Yutaka T, Nishihara H (2004) J Am Chem Soc 126:4740
Men Y, Korupoju SR, Kurihara M, Mizutani J, Nishihara H (2005) Chem Eur J 11:7322
Kurihara M, Hirooka A, Kume S, Sugimoto M, Nishihara H (2002) J Am Chem Soc 124:8800
Sakamoto A, Hirooka A, Namiki K, Kurihara M, Murata M, Sugimoto M, Nishihara H (2005) Inorg Chem 44:7547
Daniel M-C, Sakamoto A, Ruiz J, Astruc D, Nishihara H (2006) Chem Lett 35:38
Nihei M, Kurihara M, Mizutani J, Nishihara H (2001) Chem Lett 852
Nihei M, Kurihara M, Mizutani J, Nishihara H (2003) J Am Chem Soc 125:2964
Sakamoto R, Murata M, Kume S, Sampei H, Sugimoto M, Nishihara H (2005) Chem Commun, p 1215
Nagashima S, Nihei M, Yamada T, Murata M, Kurihara M, Nishihara H (2003) Macromol Symp 204:93
Fedorova OA, Fedorov YV, Vedernikov AI, Gromov SP, Yescheulova OV, Alfimov MV, Woerner M, Bossmann S, Braun A, Saltiel J (2002) J Phys Chem A 106:6213
Fedorova OA, Fedorov YV, Vedernikov AI, Yescheulova OV, Gromov SP, Alfimov MV, Kuz'mina LG, Churakov AV, Howard JAK, Zaitsev SY, Sergeeva TI, Moebius D (2002) New J Chem 26:543
Fedorov YV, Fedorova OA, Gromov SP, Bobrovskii MB, Andryukhina EN, Alfimov MV (2002) Russ Chem Bull 51:789
Fedorov YV, Fedorova O, Schepel N, Alfimov M, Turek AM, Saltiel J (2005) J Phys Chem A 109:8653
Einaga Y, Mikami R, Akitsu T, Li G (2005) Thin Solid Films 493:230
Tyson DS, Bignozzi CA, Castellano FN (2002) J Am Chem Soc 124:4562
Ferri V, Scoponi M, Bignozzi CA, Tyson DS, Castellano FN, Doyle H, Redmond G (2004) Nano Lett 4:835
McSkimming G, Tucker JHR, Bouas-Laurent H, Desvergne J-P, Coles SJ, Hursthouse MB, Light ME (2002) Chem A Eur J 8:3331
Miyamoto Y, Kikuchi A, Iwahori F, Abe J (2005) J Phys Chem A 109:10183
Uda RM, Oue M, Kimura K (2002) J Supramol Chem 2:311
Sakamoto R, Murata M, Nishihara H (2006) Angew Chem Int Ed 45:4793
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Kume, S., Nishihara, H. (2006). Metal-based Photoswitches Derived from Photoisomerization. In: Yam, V.W.W. (eds) Photofunctional Transition Metal Complexes. Structure and Bonding, vol 123. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2006_038
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DOI: https://doi.org/10.1007/430_2006_038
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