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Supramolecular Chemistry within Dendritic Structures

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Dendrimers

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 197))

Abstract

This chapter describes reports on supramolecular interactions, i.e., molecular recognition, between dendritic hosts and guest molecules, and non-covalent self assembly of branched monomers. The emphases are associated with the chemistry within dendrimers rather than on the periphery. A brief introduction to the field of supramolecular chemistry is accompanied by a short overview of dendrimers as well as a brief analysis of the syntheses of these macromolecules. Initially, accounts of random molecular inclusion or preliminary non-specific, hydrophilic/hydrophobic-based binding interactions between small guests and dendritic molecules are described, followed by examples of physical encapsulation of guest(s) molecules and their shape selective release. Molecular recognition processes via site-specific interactions including H-bonding host-guest complexations are discussed. Reports dealing with electro- and photo-active dendrimers will be considered. The self-assembly processes involving dendrimers or dendritic building-blocks assisted by forces such as those associated with hydrophilic and lipophilic behavior of amphiphilic species, π-π interactions, and liquid crystalline behavior are reviewed. This is supplemented by a section based on self-assembly processes of dendrons, mediated by intermolecular H-bonding, and mono- and multi-layer aggregation processes of dendritic structures. Lastly the construction and supramolecular chemistry of metallo-dendrimers are considered.

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  1. Center for Molecular Design and Recognition, Department of Chemistry, University of South Florida, Tampa, FL, 33613, USA

    Venkatraj V. Narayanan & George R. Newkome

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  1. Venkatraj V. Narayanan
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Narayanan, V.V., Newkome, G.R. (1998). Supramolecular Chemistry within Dendritic Structures. In: Dendrimers. Topics in Current Chemistry, vol 197. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69779-9_2

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  • DOI: https://doi.org/10.1007/3-540-69779-9_2

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