Abstract
In recent years linear polymers containing transition metals have attracted much interest. There are two types of organometallic polymers in which the metal-containing portion is either a part of the polymer main chain or bound to the polymer as a pendant group. In this article the recent studies on the former type of linear polymers are reviewed on the basis of the following three parts: 1 metallocene-containing polymers; 2 linear “Werner-type” coordination polymers; 3 polymers containing sigma-bonded transition metals in the main chain. The main part of this review is devoted to a new class of soluble metal-poly-yne polymers in which transition metal atoms are joined in the main chain by a metal-carbon σ-bond.
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Hagihara, N., Sonogashira, K., Takahashi, S. (1981). Linear polymers containing transition metals in the main chain. In: Speciality Polymers. Advances in Polymer Science, vol 41. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10554-9_12
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DOI: https://doi.org/10.1007/3-540-10554-9_12
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