Abstract
Metal-containing poly(disalicylidenediamines) exhibiting semiconductor properties were prepared by polycondensation of salicylidene derivatives of aromatic diamines with metal (Fe, Co, Ni, Cu) acetates. The data obtained confirm that the transfer of charge carriers in these polymers occurs along the chain through “nonclassical” polyconjugation zones formed via multiple intramolecular donor-acceptor interactions of lone electron pairs of the azomethine groups with the unoccupied d orbitals of the metal ions.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Entsiklopediya polimerov (Polymer Encyclopedia), Moscow: Sov. Entsiklopediya, 1972, vol. 1, pp. 1100–1118.
Korshak, V.V., Vinogradova, S.V., Vinogradova, O.V., et al., Uspekhi v oblasti sinteza elementoorganicheskikh polimerov (Advances in Synthesis of Organoelement Polymers), Korshak, V.V., Ed., Moscow: Nauka, 1980.
Organometallic Polymers, Carraher, C.E., Jr., Sheats, G.E., and Pittman, C.U., Jr., Eds., New York: Academic, 1978.
Pomogailo, A.D. and Savost’yanov, V.S., Metallsoderzhashchie monomery i polimery na ikh osnove (Metal-Containing Monomers and Polymers Based on Them), Moscow: Khimiya, 1988.
Pomogailo, A.D., Immobilizovannye polimernye metallokompleksnye katalizatory (Immobilized Polymeric Metal Complex Catalysts), Moscow: Nauka, 1988.
Pomogailo, A.D. and Savost’yanov, V.S., Russ. Chem. Rev., 1991, vol. 60, no. 7, pp. 762–772.
Dobrawa, R. and Wuethner, F., J. Polym. Sci., Part A. Polym. Chem., 2005, vol. 43, pp. 4981–4995.
Acikgoz, C., Hempenius, M.A., Vancso, G.J., and Huskens, J., Nanotechnol., 2009, vol. 20, no. 13, pp. 135304–135311.
Liu, D., Huxford, R.C., and Lin, W., Angew. Chem. Int. Ed., 2011, vol. 50, no. 16, pp. 3696–3700.
Ivanov, A.G., Geller, N.M., Aleksandrova, E.L., et al., Polym. Sci., Ser. B, 2008, vol. 50, nos.. 9–10, pp. 232–237.
Alexandrova, E.L., Ivanov, A.G., Geller, N.M., et al., Semiconductors, 2008, vol. 42, no. 10, pp. 1214–1218.
Geller, N.M., Ivanov, A.G., and Shamanin, V.V., Russ. J. Appl. Chem., 2009, vol. 82, no. 8, pp. 1442–1446.
Gradinaru, J., Forni, A., Simonov, Y., et al., Inorg. Chim. Acta, 2004, vol. 357, pp. 2728–2736.
Amirnasr, M., Mahmoudkhani, H., Gorji, A., and Dehghanpour, S., Polyhedron, 2002, vol. 21, pp. 2733–2742.
Watkinson, B.M., Fondo, M., Bermejo, M.R., et al., J. Chem. Soc., Dalton Trans., 1999, pp. 31–41.
Haikarainen, D.A., Sipilä, J., Pietikäinen, P., et al., J. Chem. Soc., Dalton Trans., 2001, pp. 991–995.
Langer, V., Popkov, A., Nadvornik, M., and Lycka, A., Polyhedron, 2007, vol. 26, pp. 911–917.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.G. Ivanov, B.V. Chernitsa, V.V. Shamanin, L.V. Vinogradova, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 11, pp. 1656–1663.
Rights and permissions
About this article
Cite this article
Ivanov, A.G., Chernitsa, B.V., Shamanin, V.V. et al. Metal-containing polymers based on disalicylidenediamines and their electrophysical properties. Russ J Appl Chem 87, 1693–1699 (2014). https://doi.org/10.1134/S1070427214110202
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427214110202