Abstract
Pectin was extracted from guava peels using the environmentally friendly deep eutectic solvent (DES) and citric acid solution. The chemical characteristics of guava peel pectin were investigated and compared to assess the potential of two different DES as an alternative to the conventional solvent. In this study, two different DES, 10% ChCl:Urea (1:2) and 10% ChCl:EG (1:2), were prepared to extract pectin from guava peels. The extracted pectin was calculated, characterized and compared to the pectin extracted with the conventional method using 10% citric acid. DES of 10% ChCl:EG is able to extract the highest pectin content (37.1%) compared to 10% citric acid (29.2%) and 10% ChCl:Urea (16.4%). The results showed that the pectin extracted using 10% ChCl:EG produced pectin with high ability to form gel as the ash content was lower (2.02%), and both methoxyl content (15.6%) and degree of esterification (98.47%) are high, which are compared with the pectin extracted from 10% citric acid. The pectin extracted from 10% ChCl:EG has a stable foam; even their foaming capacity is low compared to pectin extracted with 10% citric acid. To sum up, the DES of 10% ChCl:EG shows high potential to extract pectin as the percentage yield is high and the extracted pectin can form gel rapidly, which will be an advantage in food processing as a gelling agent.
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References
Abbott AP, Capper G, Davies DL, Rasheed RK, Tambyrajah V (2003) Novel solvent properties of choline chloride/urea mixtures. Chem Commun 70–71
Begum R, Aziz MG, Yusof YA, Burhan M (2017) Extraction and characterization of pectin from jackfruit (Artocarpus heterophyllus Lam) waste. IOSR J Pharm Biol Sci (IOSR-JPBS) 12(6):42–49
Bhat SA, Singh ER (2014) Extraction and characterization of pectin from guava fruit peel. Int J Res Eng Adv Technol 2(3):1–7
Cano-Medina A, Jiménez-Islas H, Dendooven L, Herrera RP, González-Alatorre G, Escamilla-Silva EM (2011) Emulsifying and foaming capacity and emulsion and foam stability of sesame protein concentrates. Food Res Int 44(3):684–692
Castillo-Israel KAT, Baguio SF, Diasanta MDB, Lizardo RCM, Dizon EI, Mejico MIF (2015) Extraction and characterization of pectin from Saba banana [Musa’saba’(Musa acuminata x Musa balbisiana)] peel wastes: a preliminary study. Int Food Res J 22(1):202–207
Cui S, Yao B, Gao M, Sun X, Gou D, Hu J, Liu Y (2017) Effects of pectin structure and crosslinking method on the properties of crosslinked pectin nanofibers. Carbohyd Polym 157:766–774
Das AK, Sharma M, Mondal D, Prasad K (2016) Deep eutectic solvents as efficient solvent system for the extraction of κ-carrageenan from Kappaphycus alvarezii. Carbohyd Polym 136:930–935
Devi WE, Shukla RN, Abraham A, Jarpula S, Kaushik U (2014) Optimized extraction condition and characterization of pectin from from orange peel. Int J Res Eng Adv Technol 2(2):1–9
Dranca F, Oroian M (2018) Extraction, purification and characterization of pectin from alternative sources with potential technological applications. Food Res Int 113:327–350
Gan CY, Abdul Manaf NH, Latiff AA (2010) Physico-chemical properties of alcohol precipitate pectin-like polysaccharides from Parkia speciosa pod. Food Hydrocoll 24(5):471–478
García-Argüelles S, Serrano MC, Gutiérrez MC, Ferrer ML, Yuste L, Rojo F, Del Monte F (2013) Deep eutectic solvent-assisted synthesis of biodegradable polyesters with antibacterial properties. Langmuir 29(30):9525–9534
Girma E, Worku T (2016) Extraction and Characterization of pectin from selected fruit peel waste. Int J Sci Res Publ 6(2):447–454
Ismail NS, Ramli NM, Hani N, Zainuddin (2012) Extraction and characterization of pectin from dragon fruit (Hylocereus polyrhizus) using various extraction conditions. Sains Malays 41(1):41–45
Liew SQ, Ngoh GC, Yusoff R, Teoh WH (2017) Acid and deep eutectic solvent (des) extraction of pectin from pomelo (Citrus grandis (L.) Osbeck) peels. Biocatal Agric Biotechnol 17:26
Maria B, Gama V, Eduardo C, Silva DFOLM, Karla A, Abud DS (2015) Extraction and characterization of pectin from citric waste. Ital Assoc Chem Eng 44:259–264
Meng X, Ballerat-Busserolles K, Pascale H, Jean-Michel A (2016) Impact of water on the melting temperature of urea + choline chloride deep eutectic solvent. New J Chem 1–19
Naghshineh M, Olsen K, Georgiou CA (2013) Sustainable production of pectin from lime peel by high hydrostatic pressure treatment. Food Chem 136(2):472–478
Omar N, Ku Abdullah KH (2000) Pectin content of selected local fruit by-products. J Trop Agric Food Sci 28(2):195–201
Sayah MY, Chabir R, Benyahia H, Kandri YR, Chahdi FO, Touzani H, Errachidi F (2016) Yield, esterification degree and molecular weight evaluation of pectins isolated from orange and grapefruit peels under different conditions. Public Libr Sci (PLOS) 11(9):1–16
Shafie MH, Yusof R, Gan CY (2019) Deep eutectic solvents (DES) mediated extraction of pectin from Averrhoa bilimbi: optimization and characterization studies. Carbohyd Polym 216(January):303–311
Sharma PC, Gupta A, Kaushal P (2014) Optimization of method for extraction of pectin from apple pomace. Indian J Nat Prod Resour 5(2):184–189
Yancheva N, Markova D, Murdzheva D, Vasileva I, Slavov A (2016) Foaming and emulsifying properties of pectin isolated from different plant materials Acta Scientifica Naturalis Foaming and emulsifying properties of pectin isolated from different plant materials. Acta Sci Nat 3(1):7–12
Yang Y, Wang Z, Hu D, Xiao K, Wu JY (2018) Efficient extraction of pectin from sisal waste by combined enzymatic and ultrasonic process. Food Hydrocoll 79:189–196
Zdanowicz M, Wilpiszewska K, Spychaj T (2018) Deep eutectic solvents for polysaccharides processing. A review. Carbohydr Polym
Acknowledgements
The authors acknowledge support from the Fundamental Research Grant Scheme (FRGS/1/2018/STG01/UITM//02/17) of the Ministry of Higher Education, Malaysia. They would also like to thank Universiti Teknologi MARA Perlis for providing the facilities used in this work.
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Yusof, R., Zaini, S.Z.A., Azman, M.A. (2020). Characterization of Pectin Extracted from Guava Peels Using Deep Eutectic Solvent and Citric Acid. In: Alias, N., Yusof, R. (eds) Charting the Sustainable Future of ASEAN in Science and Technology . Springer, Singapore. https://doi.org/10.1007/978-981-15-3434-8_36
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DOI: https://doi.org/10.1007/978-981-15-3434-8_36
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