Abstract
Current energy and emission regulations set the requirements to increase the use of natural gas in engines for transportation and power generation. The characteristics of natural gas are high octane number, less amount of carbon in the molecule, suitable to lean combustion, less ignitibility, etc. There are some advantages of using natural gas for engine combustion. First, less carbon dioxide is emitted due to its molecular characteristics. Second, higher thermal efficiency is achieved owing to the high compression ratio compared to that of gasoline engines. Natural gas has higher octane number so that knock is hard to occur even at high compression ratios. However, this becomes a disadvantage in homogeneous charge compression ignition (HCCI) engines or compression ignition engines because the initial auto-ignition is difficult to be achieved. When natural gas is used in a diesel engine, primary natural gas–air mixture is ignited with small amount of diesel fuel. It was found that under high pressure, lean conditions, and with the control of certain parameters, the end gas is auto-ignited without knock and improves the engine combustion efficiency. Recently, some new fuel ignition technologies have been developed to be applied to natural gas engines. These are the laser-assisted and plasma-assisted ignition systems with high energy and compact size.
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8.1 Introduction
Internal combustion (IC) engines can perform more efficiently and with a lower level of toxic emissions if natural gas (NG) is used as a fuel. NG is a naturally occurring gas mixture, which consists of primarily methane and some amount of higher hydrocarbons, nitrogen, and carbon dioxide. Typical composition of a commercial NG product is shown in Fig. 8.1.
Due to the lowest carbon-to-hydrogen ratio, compared to other fossil fuels, NG emits the least amount of CO2 during its combustion. Plentiful resources, lower price, and cleaner burning compared to conventional liquid fuels have made NG a very economic fuel to be used in IC engines. Another important feature of NG, its high octane number, makes it suitable to be used in engines with high compression ratios (Zheng et al. 2005).
To meet low emission standards for IC engines, researchers have been extensively studying the low-temperature combustion (LTC) concept (Dempsey et al. 2014; Caton 2011). These studies showed that utilizing LTC strategies in engines can result in a simultaneous reduction of nitrogen oxides (NOx) and soot emissions and also helps achieving higher thermal efficiencies (Jia et al. 2011; Asad et al. 2013; Aoyama et al. 1996).
NG can be also used in a homogeneous charge compression ignition (HCCI) engines. In the HCCI combustion mode, a mixture of air and NG is auto-ignited due to the temperature increase close to the top dead center (TDC). The combustion process is significantly faster than that in either traditional compression ignition (CI) or spark ignition (SI) engines (Reitz 2013). The challenge for HCCI engine is to control auto-ignition and combustion. A new LTC concept named reactivity controlled compression ignition (RCCI) was developed by the researchers (Kokjohn et al. 2010, 2011; Splitter et al. 2010) to overcome difficulties like combustion phasing control and very high pressure rise rate (PRR), to extend engine operating limits and avoid potential combustion instability and misfire (Imtenan et al. 2014; Gharehghani et al. 2015; Zhou et al. 2015; Benajes et al. 2015; Li et al. 2015; Laguitton et al. 2007; Molina et al. 2015; Nieman et al. 2012; Paykani et al. 2015; Kakaee et al. 2015; Christensen and Johansson 1998).
The demand for high thermal efficiency can be met through ignition of lean fuel mixtures. However, lean combustion is related to slower flame propagation speeds and decreased power output. Engine power output can be elevated through boosting the initial cylinder pressure. An increase in the cylinder pressure keeping the same spark plug electrode distance would require increased secondary coil voltage, which leads to extreme erosion of electrodes over time. Flame propagation speed in lean air–fuel mixtures can be expanded whether through optimizing the position of ignition spot in the combustion chamber or with the aid of multi-point ignition. Ignition spot always stays close to the top of the combustion chamber in a traditional spark ignition engine and cannot be varied from its location. This can be resolved by using a laser as an ignition source.
In addition to the laser ignition, the possible use of non-equilibrium plasma for ignition and combustion control has also raised the increasing interest due to the possibility of plasma-assisted approaches for ignition and flame stabilization. During the past decade, significant progress has been made toward understanding the mechanisms of plasma-chemistry interactions, power redistribution, and the non-equilibrium initiation of combustion (Starikovskii 2005). Plasma application has been shown to furnish additional combustion control, which is crucial for ultra-lean flames, high-speed flows, high-pressure conditions, and distributed ignition control in HCCI engines. In addition, a wide variety of fuels have been examined for the use of various types of discharge plasmas. The following sections will describe in more detail the above-mentioned combustion and ignition technologies and techniques applied for natural gas-fueled engines.
8.2 Combustion of Natural Gas in Dual-Fuel Engines
To meet stringent emission standards, researchers have been developing LTC solutions to improve the traditional internal combustion engines in order to develop IC engines with higher efficiencies and cleaner combustion (Agarwal et al. 2017; Musculus Mark et al. 2013; Gharehghani et al. 2016; Scott Guerry et al. 2016). Many different gaseous and liquid fuels have been evaluated in the dual-fuel combustion engine, and natural gas is believed to be one of the most suitable alternatives due to the low cost and excellent antiknock properties (Wagemakers and Leermakers 2012; Hosmath et al. 2016).
8.2.1 Experimental Research on Dual-Fuel Engines
Several experimental research efforts on dual-fuel engines were carried out by the authors of this chapter. The more detailed explanation can be found in references (Tomita et al. 2002, 2004, 2007; Roy et al. 2009). Tomita et al. (2009) investigated the combustion and exhaust emissions in supercharged dual-fuel natural gas engines. The authors documented the range of operating conditions under which the new higher efficiency PREmixed Mixture Ignition in the End-gas Region (PREMIER) combustion mode was experimentally tested in a pilot-ignited, natural gas dual-fuel engine. The heat release during the PREMIER combustion is presented in Fig. 8.2. The details of this combustion mode are presented in the reference (Tomita et al. 2009).
Figure 8.3 shows a schematic diagram of the experimental setup. The engine specifications and experimental conditions are given in Table 8.1 and explained in detail in the reference (Tomita et al. 2009).
Figure 8.4 shows the flame development of NG as a primary fuel ignited by micro-pilot-ignited diesel fuel. The flame area is gradually increasing in all four directions with the flame front finally reaching the cylinder wall. The flame speed is affected by the CO and CO2 gases produced during the combustion. The effect of these species on fuel oxidation and flame propagation is a quite complex topic and is outside of the scope of this chapter. Figure 8.5 shows the intensity of the emitted light as background-subtracted ensemble-averaged spectra at the instances the propagating flame arrives at the end-gas region where the optical sensor is installed to capture the end-gas region auto-ignition. The detailed explanations of this setup are provided in the reference (Azimov et al. 2011).
To maintain PREMIER combustion in a dual-fuel natural gas engine, the effects of several operating parameters must be identified. For example, as shown in Fig. 8.6, PREMIER combustion can be achieved by maintaining certain fixed experimental conditions (Azimov et al. 2016).
The engine experimental conditions are presented in Table 8.2.
8.2.2 Numerical Modeling of Dual-Fuel Engines
Dual-fuel combustion is one of the efficient, clean yet difficult to model phenomenon. Dual-fuel combustion has both CI and SI characteristics in addition to its own typical behavior, which increases the complexity of the combustion process. Traditionally, in the dual-fuel combustion process, a diesel spray is introduced in a nearly homogeneous air–fuel mixture. To model dual-fuel combustion, the well-established auto-ignition models can be used. As the first stage of the dual-fuel combustion is auto-ignition, these models can be applied directly without any change under the assumption that diesel auto-ignition is not affected by the presence of another fuel species such as methane, and traces of ethane, propane, and iso-butane. In reality, traces of any gaseous fuel can change ignition delay, temperature of auto-ignition process, duration of first-stage ignition, and laminar burning velocity. Hence, diesel substitution ratio is very important in order to recognize the percentage of energy delivered by diesel fuel.
One of the current challenges in the 3D CFD simulation of the dual-fuel combustion is to get the correct heat release from the chemical reactions compared with the experimental data. This is important to predict knock in the dual-fuel operation. Dual-fuel engine starts combustion using pilot fuel spray, and auto-ignition of that small fuel acts as a spark energy for the lean gaseous fuel-air mixture. This mode of combustion can be investigated experimentally as was explained in earlier section, but poses a very complicated problem for 3D CFD modeling. In SI engines, spark location is known and has precise spark energy, spark efficiency, and duration of the spark associated with it whereas dual-fuel engine heavily depends on the nature of the pilot spray to start premixed flame-type combustion.
The sequence of different types of combustion is very important for dual-fuel operation mode. For regular dual-fuel operation, the diesel pilot spray evaporates and mixes with already almost homogeneous mixture of natural gas and air. During this process, auto-ignition of diesel takes place and produces first heat release. This rate of heat release heavily depends on the quantity of diesel, compression ratio, and local equivalence ratio. First ignition starts the flame propagation and consumes most of the gaseous fuel. It is important to focus on the end-gas ignition, which follows the traditional flame propagation and has significant heat release rate compared to the first two zones, namely auto-ignition of diesel and flame front propagation in lean NG–air mixture. Hence, auto-ignition model with detailed chemistry and well-established flame propagation model hereafter mentioned as G-equation model can be used to model dual-fuel combustion in diesel engine. G-equation model is:
where Dt is turbulent diffusion, κ is curvature of the flame, ρu is unburnt density, and St is turbulent flame speed. Depending on the fuel composition and local equivalence ratio, ignition temperature is found to vary between 950 and 1100 K and hereafter it is denoted by TG. This temperature (TG) was decided using 0D auto-ignition model for homogeneous charge in CHEMKIN. TG changes per local equivalence ratio and fuel composition. El Merhubi et al. (2016) conducted high-pressure (40 bar) methane auto-ignition using shock tube and also validated GRI 3.0 mechanism for ϕ = 0.5–1.0. At 40 bar pressure, auto-ignition temperature of methane (ϕ = 0.5) is 1560 K. Though HCCI calculations assume premixed charge, it is important to note that 1% diesel quantity by energy content significantly changes auto-ignition temperature of methane. If n-heptane mass fraction is less than 0.021, then TG is on the higher side. Hence, the value of TG needs to be determined each time when the fuel composition changes. St is derived from laminar flame speed Sl, when used for RANS modeling; it includes uʹ root mean square of turbulent fluctuation velocity as shown in Eq. 8.2 (Peters 2000).
where b1 = 2.0, b3 = 1.0, a4 = 0.78, Da—Damkohler number.
Equation 8.3 derived by Pitch (2002) is used for LES cases to calculate St
where Sc is turbulent Schmidt number, Δ is the filter width, and Cs is dynamic Smagorinsky number. In G-equation model G (x, t) is a non-reactive scalar iso-surface for any fixed value of x. The flame front is described by G = 0 surface, and the flame thickness is superimposed by Gʹ on this iso-surface. G-equation depends on the closure solution for calculating turbulent flame speed and does not have a source term; hence, G-equation model can be easily coupled with detailed chemistry model (Yang and Reitz 2010; Liang et al. 2007; Long 2006; Tamagna et al. 2008). Positive value of G suggests burnt zone, and negative value is used for unburnt zone. In the current model, laminar flame speed is calculated using CHEMKIN 1D laminar flame speed calculations instead of Guilder’s equation (Gulder 1984) as it tends to overpredict the laminar flame speed for single component fuels like methane at high pressure and temperature conditions.
Figure 8.7 shows combustion progress at 4.5° BTDC after injection has occurred at 14.5° BTDC. Formaldehyde (CH2O) is a main attribute of low-temperature combustion which appears not only in the vicinity of the flame kernels but on the peripheral area of entire combustion chamber. Plotted iso-surface at G = 0.0001 shows predominantly low-temperature regions. The empty region in the middle of combustion chamber is a high-temperature zone, and in the third figure, OH concentration is highest in the same region. This shows the smaller high-temperature region near spray surrounded by cluster of low-temperature ignition sites.
Figure 8.8 shows the development of the initial kernel after the second micro-pilot injection is complete. CH2O iso-surface is created for highest concentration and colored by temperature to show the sites of preignition low-temperature chemistry. Subsequently, G iso-surface at value 1e−04, i.e., at 0.1 mm distance from mean flame front inside the burn zone is also colored by temperature which shows three major kernel formation zones around three spray lobes. It is very important to note that outside the flame zone, at low-temperature initial kernel development starts at various locations. This kernel depending on the location from the wall and from mean flame front either becomes auto-ignition sites or just contributes to small energy release. OH iso-surface is plotted at highest mass fraction of OH (1.e−03) and shows the high-temperature chemistry inside the burnt zone. The heat release in case of the split micro-pilot injection is illustrated with CH2O and G iso-surface as shown in Fig. 8.8 at 6° ATDC. The first micro-pilot injection occurs at 6° BTDC, and Fig. 8.8 shows the aftermath for flame kernel development after the second micro-pilot injection at 5° ATDC. The positive value of G suggests the burnt region, and the negative value shows the unburnt region outside the flame zone whereas G = 0 is the mean flame front brush. CH2O and G-surfaces are colored by temperature to show low-temperature flame segments. G = 1e−04 shows the 0.1 mm zone inside the burnt zone after the flame front has passed. CH2O iso-surface shows in the pre-flame chemistry occurring outside the flame front at much lower temperature of 900 K, where inside the burnt zone the temperature is 2500 K.
Figure 8.9 shows trend of local temperature, which includes single micro-pilot injection at 14.5° BTDC. The highest temperature is noted from preheat region (1 mm away from the flame front), and second highest temperature belongs to the burnt region (1–2 mm inside the flame front). It is also important to note that around 6° BTDC mean flame front (G = 0) reaches highest temperature, and at the same time in preheat region 2–5 mm away from mean flame, there is a sudden increase in temperature. This is a very clear indication of end-gas ignition provided that temperature is much less at 0.5 mm outside the flame.
Figure 8.10 shows the local temperature and pressure data for the same scenario, and there are two major heat release zones; the first one is at 1000 K range, and the second zone shows high-temperature end-gas heat release at 2100 K range. Both LES and RANS turbulent models with the same combustion model showed good agreement in terms of end-gas ignition.
Figure 8.11 shows the gradient G that represents the temperature profiles in three combustion regions. The positive values of G represent the temperature in the burnt zone where post-flame chemistry is dominant and has the highest temperature in the combustion chamber. Negative values of G show the preheat or pre-flame regime where end-gas ignition happens in PREMIER cases. This is an excellent way of predicting temperature in the end-gas region instead of just observing few locations for higher heat release.
Figure 8.12 shows the effect of split micro-pilot injection. Ignition sites for split pilot injection are less in number compared to the single pilot injection case. The graph shows the effect of methane on the first ignition temperature as well as the overall temperature trend. For this case, when methane is present, first-stage ignition temperature is lower as compared to the scenario when methane is not present. On the contrary, at the second stage ignition methane burns at higher temperature compared to diesel-only case. As the second micro-pilot starts at 5° ATDC, for non-methane case temperature suddenly drops as spray is being injected in the developed flame kernel of the first pilot injection. Start of the second micro-pilot is visible in Fig. 8.8. This effect is reduced in case of multi-pilot injection due to the presence of methane, and flame kernel grows with steady consumption of fuel. Split injection proves to be effective in controlling end-gas ignition and growth of the flame kernel. The current way of modeling proved to be very effective in detecting changes in the end-gas ignition temperature as well as its precise location and frequency.
8.3 Combustion of Natural Gas in Homogeneous Charge Compression Ignition (HCCI) Engines
NG requires little time for mixture preparation and is chemically stable, both of which make it a suitable fuel for homogeneous charge compression ignition (HCCI) engines. NG produces less greenhouse gas emissions compared to those of petroleum-based fuels. NG also brings a few challenges for HCCI engine operations. NG has a high octane number and therefore is hard to auto-ignite. In addition, NG usually has large differences in fuel composition from field to field, which adds more uncertainties for engine applications to make universal adjustments to run on different NG types. To enable the use of NG in HCCI engines, higher compression ratios, significant amount of intake heating, some types of preignition and/or internal EGR are required to be adjusted to ensure the auto-ignition.
The use of NG in HCCI engines has been studied for over a decade. The obtained results (Ando et al. 2003; Jun et al. 2003) experimentally showed the effect of different operating parameters such as intake temperature, density, equivalence ratio, and others, on natural gas auto-ignition characteristics. Yap et al. (2004) experimentally demonstrated the decrease of NOx emissions and increase of CO and UHC emissions with the addition of reformed EGR. The same group (Yap et al. 2006) also reported an increase in NOx emissions with hydrogen addition at higher loads in a natural gas HCCI engine. Other groups (Doughty et al. 1992) investigated the effect of engine loads and measured the lower NOx emissions in the exhaust gas at lower loads and at higher engine speeds.
8.3.1 Single-Zone Model
To simulate NG HCCI combustion in IC engines, a single-zone model with distinct chemical kinetics in CHEMKIN can be employed (CHEMKIN-PRO 2010). The fundamental assumption that the model imposes is that the temperature and species concentrations are viewed as homogeneous throughout the cylinder. The thermodynamic system described by the model is shown in Fig. 8.13. In the cylinder, there are four independent properties which include temperature (T), species concentration (Yk), pressure (P), and volume (V). The heat is transferred to the cylinder wall, and the work is transferred by the piston. The main equations are described below.
The species conservation for the system is (CHEMKIN-PRO 2010),
where Yk is the mass fraction, Wk is the molecular weight, ρ is the mass averaged density, and \( \dot{\omega }_{k} \) is the molar rate of production per unit volume. The energy equation for the system shown in Fig. 8.13 is the following (CHEMKIN-PRO 2010),
Elementary reactions involving Kg species can be represented in the general form,
where \( n_{\text{ki}}^{\prime} \) and \( n_{\text{ki}}^{\prime\prime} \) v indicates forward and reverse stoichiometric coefficients for the ith reaction, and xk is the chemical symbol of the kth species. Then, the expression for the production rate \( \dot{\omega }_{k} \) can be obtained,
where kfi and kri are the forward and reverse rate constants of the ith reactions, and [Xk] is the molar concentration of the kth species. The forward rate constants for the reactions are generally the inputs of the model.
Arrhenius temperature dependence:
Instantaneous spatially averaged heat transfer to the cylinder wall is calculated using a version of the Woschni correlation (Heywood 1988). This version has been adjusted for HCCI combustion (CHEMKIN-PRO 2010), as shown below,
where a = 0.035, b = 0.8, c = 0.
where the local average gas velocity w is correlated as follows,
where Vd is the displaced volume; p is the instantaneous cylinder pressure; pr, Vr, Tr are the pressure, volume, and temperature at the reference state; pm is the motored cylinder pressure at the same crank angle as p. In this study, C11 = 2.28, C12 = 0.308, C2 = 0.54, and vswirl = 0 are used. More detailed description of this heat transfer correlation can be found in (Heywood 1988).
8.3.2 Multi-zone Model
Multi-zone models typically require non-reacting (cold flow) fluid mechanics simulation to provide the initial temperature and concentration distributions in the cylinder. With these initial distributions, an appropriate number of zones can be determined and those zones can be established and initialized with different temperatures and concentrations. Figure 8.14 shows an example of the setup procedure where the continuous temperature distribution from the CFD simulation is converted to the zonal conditions in the multi-zone model. After the zonal initial conditions are set up, the detailed chemical kinetics can be applied and solved in all zones fully coupled.
The assumptions (CHEMKIN-PRO 2010) pertaining to this model formulation are as follows. First of all, all zones are assumed to have the same, uniform pressure. Second, the mass or heat transfer between zones is assumed to be negligible and the only interaction between the zones is the compression work. Third, the total volume of the zones must equal the cylinder volume computed by the slider-crank relationship used in the single-zone internal combustion engine model. This constraint is used to determine the zonal and cylinder pressure (CHEMKIN-PRO 2010).
The governing equations for the multi-zone model are similar to those for the single-zone model, except for the additional superscript “i” which represent the zone number, as shown in Eq. 8.12 (conservation of species) and Eq. 8.13 (energy equation) (CHEMKIN-PRO 2010).
The single-zone and multi-zone models have been validated against the experimental work done by Jun et al. (2003). The operating conditions at which the prediction and measurements were compared are summarized in Table 8.3. The temperatures at intake valve closure (IVC) are used to calibrate the start of combustion for both the single-zone and multi-zone simulations. Figures 8.15 and 8.16 show the measured and predicted pressure traces as a function of crank angle at various equivalence ratios. The results for multi-zone analysis have generally better agreement with the measurements than single-zone simulations and are provided in reference (Zheng 2012).
8.3.3 Engine Efficiencies for Using Natural Gas in Comparison with Gasoline
This section continues to compare natural gas with gasoline in terms of the indicated efficiency and volumetric efficiency at the best efficiency point under various operating conditions. Some of the fuel properties are shown in Table 8.4.
For all of the equivalence ratios presented here, about 3% difference in indicated efficiencies is observed between the two fuels. The efficiencies for the natural gas cases are lower largely due to the higher heat loss and lower specific heat ratio. Higher heat transfer is a direct result of higher combustion temperature. Lower specific heat ratio is caused by the higher mole fraction of the fuel species since natural gas has much lower molar stoichiometric air–fuel ratio than gasoline. A reduction of specific heat ratio reduces the amount of energy that can be extracted by the piston. At very low equivalence ratio, the chemical kinetics and combustion become slower and less complete which affects the thermal efficiency.
As the equivalence ratio increases, though combustion efficiency is improved, the heat loss as well as the fraction of heat loss out of total fuel energy is greater as a result of a higher combustion temperature. In addition, higher equivalence ratio leads to lower specific heat ratio which reduces the thermal efficiency. So the indicated efficiency reaches a peak around ϕ equal to 0.3. In terms of the volumetric efficiency, it is straightforward that the gasoline cases are higher and the differences are larger at higher equivalence ratios, since volumetric efficiency is strongly affected by the intake temperature. This observation poses another issue for using natural gas in HCCI engines which is the relatively lower torque output at the same equivalence ratio due to the low volumetric efficiency (Zheng 2012).
The indicated thermal efficiency for both natural gas and gasoline increases as the engine speed increases. This increase is again related to the amount of heat transfer. Although the temperature at the IVC is higher at higher speeds, less time is allowed for transferring heat from the gas to the walls as the real time of one cycle becomes shorter as engine speed increases. The overall effect is to reduce the fraction of heat loss out of total fuel energy and to improve the thermal efficiency. The volumetric efficiency, however, decreases with the increase of engine speeds. Again, this is directly dictated by the higher IVC temperature at higher speeds. So running HCCI engines, either with gasoline or natural gas, at higher speeds could improve thermal efficiency but at the penalty of torque output (Zheng 2012).
The indicated thermal efficiency approximately remains nearly constant as the EGR level changes for both natural gas and gasoline cases. This might be attributed to the balance between lowered combustion temperature due to the EGR dilution effect and increased IVC temperature. Volumetric efficiency slightly drops as the EGR fraction increases and IVC temperature at best efficiency increases.
Having higher intake pressure slightly increases the indicated efficiency as a result of lower IVC temperature and corresponding lower heat loss. Furthermore, increasing intake pressure greatly improves the volumetric efficiency due to the increase in the mass of air–fuel mixture. These results imply that intake boosting is an attractive option to have for HCCI engines fueled with natural gas or other high octane fuels (Zheng 2012).
Using the single-zone model, Zheng (2012) conducted the analysis on the effect of operating conditions on the ignition characteristics, engine performance, and thermal efficiency of the HCCI engine. He found that the operating conditions, including equivalence ratio, engine speed, and intake pressure, have great influences on the HCCI ignition characteristics. The minimum required temperature at IVC for auto-ignition and complete combustion decreases as the equivalence ratio increases and the intake pressure increases, and increases as the engine speed increases. In addition to the operating conditions, compression ratio has an even greater effect on the minimum required temperature at IVC. For the natural gas case, the increase in compression ratio from 18 to 22 could reduce the requirement of the minimum required temperature at IVC by 40 K. The results imply that to reduce the intake temperature requirement for using natural gas, higher compression ratio, intake boosting, and relative lower engine speed are desirable.
The operating conditions have a great effect on the HCCI engine performance and efficiencies. The volumetric efficiency increases with the increase of equivalence ratio or intake pressure or the decrease of engine speed or exhaust gas recirculation level. The indicated thermal efficiency peaks at a certain equivalence ratio, and a higher or lower equivalence ratio than this value will decrease the indicated efficiency. The increase in engine speed improves the indicated efficiency, while the change in intake pressure and EGR level does not have a strong influence on the efficiency. In terms of the volumetric efficiency, intake boosting is a very desirable option to increase the specific power output, and operating at high engine speed is not attractive as it deteriorates the volumetric efficiency. In terms of the indicated efficiency, operating with a relatively lean mixture is still a desirable option for natural gas HCCI engines.
8.4 Combustion of Natural Gas in Reactivity Controlled Compression Ignition (RCCI) Engines
Reactivity controlled compression ignition (RCCI) concept can significantly improve the combustion process in terms of efficiency and exhaust gas emissions (Reitz and Duraisamy 2015). Recent interest has been raised to investigate RCCI combustion concept with NG/diesel fuels at different engine operating conditions (Ansari et al. 2016; Nieman et al. 2012; Zoldak et al. 2014, 2015; Doosje et al. 2014; Xu et al. 2016).
8.4.1 Effect of Energy-Based Premixed Ratio
Figure 8.17 shows the effect of premixed ratio (PR) on heat release rate (HRR) and in-cylinder pressure. The NG premixed ratios were composed to provide the same amount of the total energy for combustion. The graph shows that sweeping the PR from 55 to 95% increases the ignition delay and reduces the in-cylinder pressure and HRR (Poorghasemi et al. 2017).
Figure 8.18 shows that when the pressure ratio increases, the in-cylinder temperature decreases. This can result in the increase of HC emissions. It can also be explained by the fact that the crevice regions near the walls are usually colder in higher-pressure ratios. This will lower the combustion efficiency and increase the UHC emissions.
8.4.2 Effect of Injection Timing
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The first injection timing
The effect of the first injection timing (SOI1) was once completed by changing SOI1 from 85° to 45° BTDC while maintaining SOI2 timing consistent at 20° BTDC. Seventy percentage of the total diesel fuel was injected at the first pulse and 30% at the second pulse. Advancing SOI1 timing from 85° to 45° BTDC results in delayed combustion and reduced peak in-cylinder pressure and HRR, as shown in Fig. 8.19. This happened due to the increase of the mixing time and better homogeneity of NG and diesel fuel, and as a result, less reactive mixture was prepared (Curran et al. 2012; Ma et al. 2013).
As the SOI1 timing is retarded, NOx emission increases and HC and CO emissions decrease. NOx increases due to the increase of the in-cylinder temperature. As shown in Fig. 8.20, the spray is impinged on the wall and enters the crevice cavity where due to the established lower temperature and lower volume to surface ratio zones HC and CO emissions increase. In later SOI1 at 45° BTDC, a greater amount of fuel is injected into the areas of piston bowl and squish areas with higher temperature and reactivity gradients, and consequently, lower levels of HC and CO produced.
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The second injection timing
The second fuel injection timing (SOI2) was changed from 40° to 0° BTDC, with constant SOI1 timing at 55° BTDC, as shown in Fig. 8.21. The results showed that retarding the SOI2 from 40° to 0° BTDC caused the retard of the combustion phasing, which caused the peak of in-cylinder pressure to be decreased. The second diesel injection pulse could not mix properly with in-cylinder mixture due to a very short time period, and this has caused the ignition delay to be increased.
Figure 8.22 shows the effect of SOI2 sweep on in-cylinder temperature. The simulation results showed that high local in-cylinder temperature region near TDC occurred that has caused the NOx to be increased at earlier SOI2 timings. When SOI2 was advanced, the lowest carbon monoxide and unburnt hydrocarbon emissions were achieved. When the injection SOI2 was initiated at 40° BTDC, the flame could reach the whole combustion chamber, while at SOI2 at 0° BTDC there are more regions with lower temperatures, as shown in Fig. 8.22. This causes a lower combustion efficiency and higher levels of unburnt hydrocarbons and carbon monoxide emissions at later SOI2 timings (Paykani et al. 2015).
8.5 Advanced Ignition Systems for Natural Gas Combustion
Due to high octane number, natural gas engines can be operated at relatively higher compression ratios and leaner fuel–air mixtures, thus leading to higher thermal efficiencies and lower emissions. However, this can lead to considerable reduction in power density. This can be compensated by increasing the pressure of combustible charge at the end of a compression stroke. To ignite a leaner air–fuel charge at higher pressures requires using much higher voltage ignition systems. These high voltages significantly reduce the lifetime of spark plugs (Wienrotter et al. 2006). Such ignition systems are a laser-assisted ignition and a plasma-assisted ignition, which are discussed below.
8.5.1 Laser-Assisted Ignition Control
Laser can be used as an alternative ignition source for engines. Laser pulses delivered with the aid of a laser system are targeted inside the combustion chamber with fuel–air mixture. The experimental laser ignition system was designed and constructed by Srivastava et al. (2011) and is shown in Fig. 8.23.
The obtained high-speed camera images that display the development of the early flame kernel stages with time had been recorded using shadowgraphy technique. The images were obtained at 54,000 fps. The snapshots were captured at an interval of 18.5 ms for a combustion event. From these images, we can get an idea on how the flame kernel is developed with time for selected NG–air ratios (λ = 1.2 and λ = 1.6). Figure 8.24 shows the sequential snapshots of flame kernel development at unique timescales for λ = 1.2. Timescales of the first four snapshots were kept constant; however, the timescales for the final four snapshots were different due to the fact of longer combustion duration for the leaner mixtures. The vertical and horizontal dimensions of all images have been kept constant at 1.15 and 1.45 cm, respectively.
Srivastava et al. (2011) found that the flame kernel propagation distance was consistently decreasing with leaner mixtures λ = 1.6, as shown in Fig. 8.25. These findings suggest that the volumetric growth of the flame kernel reduces substantially with the reduction of NG–air mixture strength and a practical laser ignition system applied to the engine will not be able to deal with NG–air mixtures leaner than λ = 1.6.
To observe the laser ignition process under the reciprocating engine conditions, Dumitrache et al. (2017) used rapid compression machine (RCM) shown in Fig. 8.26. Details of this setup are given in the reference (Dumitrache et al. 2017).
The approach validated in this study used to be for a laser-ignited mixture of CH4–air at an equivalence ratio of = 0.5 (Dumitrache et al. 2017), as shown in Fig. 8.27. The lean condition used to be chosen to restrain the flame propagation speed, hence allowing capturing numerous frames of the flame propagation, given the limitations of the imaging system. In these experiments, only 30% of the mixture has been consumed by the propagating flame and the chemical heat release overcomes the heat losses to the wall that causes the flame to become turbulent with cellular structure as shown in Fig. 8.27.
8.5.2 Plasma-Assisted Ignition and Combustion Control
In latest years, the plasma-assisted combustion mechanisms have been validated through experimentation under controlled conditions and by the way of evaluating the effects with numerical simulations of discharge and combustion processes. Researchers became curious about non-equilibrium plasma for ignition and combustion control (Starikovskii 2005, 2006) thanks to the new potentialities for ignition and flame stabilization that are supplied by the plasma-assisted approach. The most important distinction between the traditional combustion and plasma-assisted combustion is the ignition initiation mechanism.
Kosarev et al. (2008) and Aleksandrov et al. (2009) have observed a correlation between the ignition delay time and the temperature for the CH4/O2/Ar mixture. The fuel discharge causes a drastic reduction in the ignition delay time and allows the mixture to ignite at notably lower temperatures. Figure 8.28 shows the ignition delay time in a CH4/O2/Ar = 3.3:6.7:90 mixture as a function of temperature for auto-ignition and (I–II) ignition with the plasma discharge. The diagram indicates the comparison of the measured ignition delay time with and without plasma at the equal initial gas densities. As viewed in Fig. 8.28, these times may vary by two or three orders of magnitude.
Michael et al. (2010) showed that the ignition in CH4–air mixtures can be performed using low energy seed laser pulses and an overlapping subcritical microwave pulse. Very susceptible ionization by a laser localized the deposition of microwave energy and caused fast heating, high temperatures, and ignition. The same research team (Michael et al. 2010) also developed a coupled one-dimensional gas-dynamic/plasma-dynamic model to follow the rapidly evolving plasma and gas properties carried out through this interaction. By growing the pulse power by a factor of 3, the ignition used to be discovered alongside the seed laser path. In this case, a much larger area of strong coupling with the microwave (MW) energy was discovered in the shadowgraph snapshots as shown in Fig. 8.29 (Michael et al. 2010). For a large number of combustion-driven engines, transient plasma ignition involving quick ignition pulses (typically 10–50 ns) has been shown to efficiently minimize ignition delays and enhance engine performance compared to the conventional spark ignition.
8.6 Conclusion
The chapter summarizes the advanced combustion and ignition technologies with natural gas as a fuel for application in internal combustion engines. Natural gas is considered the direct alternative to replace the crude oil-derived liquid fuels for better energy efficiency and cleaner environment. It was demonstrated by several researchers that the novel combustion technologies such as PREMIER, HCCI, and RCCI can provide better fuel efficiency and emission reduction. However, these technologies should be further developed to become applicable and feasible to a wider range of engine design and operating conditions with natural gas.
These technologies will become even more useful during the transport electrification era. With the requirements to introduce more electric vehicles in transportation network, more challenges will appear to meet required power and mileage levels, especially for commercial heavy-duty vehicles and trucks. The analysis shows that in the near future it will not be possible to convert the entire heavy-duty vehicles fleet to run on electric batteries only, and therefore, the hybrid powertrain systems will have to be used to ensure the cost-effective and reliable operation. In this situation, hybrid powertrain systems with natural gas as a fuel for internal combustion engines will become a feasible solution.
Along with the novel combustion technologies for effective burning of fuel inside the engine cylinders, more advanced ignition initiation technologies are also being developed and applied to conventional and future internal combustion engines. Such technologies are laser-assisted and plasma-assisted ignition systems. Lasers are becoming feasible candidates as alternative ignition systems in internal combustion engines. This technology can be applied to initiate the combustion of high octane number natural gas mixtures. Plasma formation does not always imply that ignition has to take place. Only if the energy content of the plasma is excessive enough, then the mixture of NG–air is ignited by a flame kernel, which may also extend or extinguish. This plasma source can be applied as a stand-alone or additional source to initiate the combustion in internal combustion engines.
Natural gas can play an important role as an actual game changer in energy and transport sectors for energy security. For the consumer’s perspectives to make a swap from current liquid fuels to compressed natural gas will be more compelling than for other alternatives such as ethanol or electricity.
Abbreviations
- ATDC:
-
After top dead center
- AFR:
-
Air–fuel ratio
- BTDC:
-
Before top dead center
- CA:
-
Crank angle
- CAD:
-
Crank angle degree
- CFD:
-
Computational fluid dynamics
- CI:
-
Compression ignition
- CNG:
-
Compressed natural gas
- CO:
-
Carbon monoxide
- CO2:
-
Carbon dioxide
- EVC:
-
Exhaust valve closing
- EVO:
-
Exhaust valve opening
- EGR:
-
Exhaust gas recirculation
- ϕ :
-
Equivalence ratio
- IMEP:
-
Indicated mean effective pressure
- IVC:
-
Intake valve close
- IVO:
-
Intake valve open
- HC:
-
Hydrocarbon
- HCCI:
-
Homogeneous charge compression ignition
- HRR:
-
Heat release rate
- IC:
-
Internal combustion
- LES:
-
Large Eddy simulation
- LTC:
-
Low-temperature combustion
- m DF :
-
Mass of pilot-injected diesel fuel
- NG:
-
Natural gas
- NO:
-
Nitrogen monoxide
- NOx:
-
Nitrogen oxides
- P:
-
Pressure
- PCCI:
-
Premixed charge compression ignition
- rpm:
-
Revolution per minute
- RANS:
-
Reynolds-averaged Navier–Stokes
- RCCI:
-
Reactivity controlled compression ignition
- SI:
-
Spark ignition
- SOC:
-
Start of combustion
- SOI:
-
Start of injection
- T:
-
Temperature
- T G :
-
Ignition temperature
- TDC:
-
Top dead center
- UHC:
-
Unburned hydrocarbon
- V:
-
Volume
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Azimov, U., Kawahara, N., Tsuboi, K., Tomita, E. (2019). Advanced Combustion in Natural Gas-Fueled Engines. In: Srinivasan, K., Agarwal, A., Krishnan, S., Mulone, V. (eds) Natural Gas Engines . Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-13-3307-1_8
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