Abstract
In this chapter we shall review, from a mechanistic viewpoint, the fundamental processes involved in reactions catalysed by transition metals. Particular emphasis is placed on those reactions pertaining to syn gas chemistry. More indepth treatments of particular mechanisms are given in later chapters which deal with specific reactions of syn gas.
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C. A. Tolman, P. Z. Meakin, D. L. Lindner and J. P. Jesson, J. Am. Chem. Soc., 96, 2762 (1974).
R. Ugo, Chim. Ind. (Milan), 51, 1319 (1969).
C. A. Tolman, Chem. Soc. Rev., 1, 337 (1972).
J. Halpern, in Fundamental Research in Homogeneous Catalysis, Vol. 3, ( M. Tsutsui, Ed.), Plenum Press, New York, 1979, p. 25.
J. K. Kochi, Organometallic Mechanisms and Catalysis, Academic Press, New York, 1978.
J.R. Graham and R. J. Angelici, Inorg. Chem., 6, 2082 (1967).
M. S. Wrighton and M. A. Schroeder, J. Am. Chem. Soc., 95, 5764 (1973); 98, 551 (1976).
M. Absi-Halabi and T. L. Brown, J. Am. Chem. Soc., 99, 2982 (1977).
D. J. Cox and R. Davis, Inorg. Nucl. Chem. Lett., 13, 301 (1977).
B. H. Byers and T. L. Brown, J. Am. Chem. Soc., 97, 947 (1975); 99, 2527 (1977).
R. Eisenberg and D. E. Hendriksen, Advan. Catal., 28, 78 (1979).
W. Hieber and F. Leutert, Z. Anorg. Allg. Chem., 204, 145 (1932).
P. C. Ford, Acc. Chem. Res., 14, 31 (1981).
P. C. Ford, R. G. Rinker, R. M. Laine, C. Ungerman, V. Landis and S. A. Maya, Advan. Chem. Ser., 173, 81 (1979).
R. M. Laine, R. G. Rinker and P. C. Ford, J. Am. Chem. Soc., 99, 252 (1977).
H. Kang, C. H. Mauldin, T. Cole, W. Slegeir, K. Cann and R. Pettit, J. Am. Chem. Soc., 99, 8323 (1977); R. Pettit, K. Cann, T. Cole, C. H. Mauldin and W. Slegeir, Advan. Chem. Ser., 173, 121 (1979).
A. D. King, R. B. King and D. B. Yang, J. Am. Chem. Soc., 102, 1028 (1980); C. C. Frazier, R. Hanes, A. D. King and R. B. King, Advan. Chem. Ser., 173, 94 (1979).
T. Yoshida, Y. Ueda and S. Otsuka, J. Am. Chem. Soc., 100, 3942 (1978).
D. J. Darensbourg, B. J. Baldwin and J. A. Froelich, J. Am. Chem. Soc., 102, 4688 (1980).
B. R. James, G. L. Rempel and F. T. T. Ng, J. Chem. Soc., A, 2454 (1969).
C. H. Cheng, D. E. Hendriksen and R. Eisenberg, J. Am. Chem. Soc., 99, 2791 (1977).
E. C. Baker, D. E. Hendriksen and R. Eisenberg, J. Am. Chem. Soc., 102, 1020 (1980).
T. Yoshida, T. Okano, Y. Ueda and S. Otsuka, J. Am. Chem. Soc., 103, 3411 (1981).
D. F. Shriver, J. Organometal. Chem., 94, 259 (1975); Chem. Brit., 8, 419 (1972).
J. S. Kristoff and D. F. Shriver, Inorg. Chem., 13, 499 (1974).
N. E. Kim, N. J. Nelson and D. F. Shriver, Inorg. Chim. Acta, 7, 393 (1973);
N. J. Nelson, N. E. Kim and D. F. Shriver, J. Am. Chem. Soc., 91, 5173 (1969).
R. B. Peterson, J. J. Stezowski, C. Wan, J. M. Burlitch and R. E. Hughes, J. Am. Chem. Soc., 93, 3532 (1971).
J. M. Burlitch and R. B. Peterson, J. Organometal. Chem., 24, C65 (1970).
J. C. Kotz and C. D. Turnipseed, J. Chem. Soc., Chem. Commun., 41 (1970).
G. Broden, T. N. Rhodin, C. Bruckner, R. Benbow and Z. Hutych, Surf Sci., 59, 593 (1976).
G. R. Eady, B. F. G. Johnson and J. Lewis, J. Chem. Soc. Dalton, 2606 (1975).
J. Halpern, Disc. Faraday Soc., 46, 7 (1968);Advan. Chem. Ser., 70, 1 (1968).
B. R. James, in Homogeneous Hydrogenation,Wiley, New York, 1973 and references therein.
R. A. Sheldon and J. K. Kochi, Metal Catalysed Oxidations in Organic Chemistry, Academic Press, New York, 1981, p. 73.
T. A. Weil, S. Metlin and I. Wender, J. Organometal. Chem., 49, 227 (1973).
N. W. Hoffman and T. L. Brown, Inorg. Chem., 17, 613 (1978).
B. H. Byers and T. L. Brown, J. Am. Chem. Soc., 97, 3260 (1975).
M. Orchin and W. Rupilius, Catal. Rev., 6, 85 (1972).
R. F. Heck, Organotransition Metal Chemistry, Academic Press, New York, 1974, p. 201.
W. Hieber and W. Hybel, Z. Elektrochem., 57, 235 (1953).
I. Wender, Catal. Rev., 14, 97 (1976).
B. L. Booth and B. L. Shaw, J. Organometal. Chem., 36, 363 (1972).
H. G. Kuivila, Acc. Chem. Res., 1, 299 (1968); Advan. Organometal. Chem., 1, 47 (1964).
J. P. Collman, Acc. Chem. Res., 8, 342 (1975).
J. P. Collman, Acc. Chem. Res., 1, 136 (1968).
J. P. Collman and W. R. Roper, Advan. Organometal. Chem., 7, 54 (1968).
J. Halpern, Acc. Chem. Res., 3, 386 (1970).
J. K. Stille and K. S. Y. Lau, Acc. Chem. Res., 10, 434 (1977).
L. Vaska,Acc. Chem. Res., 1, 335 (1968).
See for example, R. G. Pearson and W. R. Muir, J. Am. Chem. Soc., 92, 5519 (1970).
J. S. Bradley, D. E. Connor, D. Dolphin, J. A. Labinger and J. A. Osborn, J. Am. Chem. Soc., 94, 4043 (1972).
J. A. Labinger, A. V. Kramer and J. A. Osborn, J. Am. Chem. Soc., 95, 7908 (1973).
A. V. Kramer, J. A. Labinger, J. S. Bradley and J. A. Osborn, J. Am. Chem, Soc., 96, 7145 (1974).
A. V. Kramer and J. A. Osborn, J. Am. Chem. Soc., 96, 7832 (1974).
See for example, P. J. Krusic, P. J. Fagan and J. San Filippo, J. Am. Chem. Soc., 99, 250 (1977); R. J. Kinney, W. D. Jones and R. G. Bergman, J. Am. Chem. Soc., 100, 635 (1978).
A. S. Nesmeyanov, R. Kh. Freidlina, E. Ts. Chukovskaya, R. G. Petrova and A. B. Belyaysky, Tetrahedron, 17, 61 (1962).
B. J. Schaart, H. W. H. J. Bodewitz, C. Blomberg and F. Bickelhaupt, J. Am. Chem. Soc., 98 3712 (1976) and references cited therein.
J. F. Bunnett, Acc. Chem. Res., 11, 413 (1978).
N. Kornblum, Angew. Chem. Int. Ed. Engl., 14, 734 (1975).
R. W. Alder, J. Chem. Soc. Chem. Commun., 1184 (1980).
J. K. Kochi, Pure Appl. Chem., 52, 571 (3980).
F. Calderazzo, Angew. Chem. Int. Ed. Engl.,16 299 (1977) and references therein.
R. R. Schrock and G. W. Parshall, Chem. Rev., 76, 243 (1976).
G. M. Whitesides, J. F. Gaasch and E. R. Stedronsky, J. Am. Chem. Soc., 94, 5258 (1972).
R. L. Sweany and J. Halpern, J. Am. Chem. Soc., 99, 8335 (1977).
P. Biloen, J. N. Helle and W. M. H. Sachtler, J. Catal., 58, 95 (1979).
P. Biloen, Reel. Tray. Chim. Pays-Bas, 99, 33 (1980).
M. Araki and V. Ponec, J. Catal., 44, 439 (1976).
P. R. Wentrcek, B. J. Wood and H. Wise, J. Catal., 43, 363 (1976).
J. G. Ekerdt and A. T. Bell, J. Catal., 58, 170 (1979).
R. C. Brady and R. Pettit, J. Am. Chem. Soc., 102, 6181 (1980); 103, 1287 (1981); see also J. C. Hayes, G. D. N. Pearson and J. N. Cooper, J. Am. Chem. Soc., 103, 4648 (1981).
J. A. Rabo, A. P. Rissh and M. L. Poutsma, J. Catal., 53, 295 (1978).
C. P. Casey and S. M. Neumann, J. Am. Chem. Soc., 98, 5395 (1976); 100, 2544 (1978).
C. P. Casey, S. M. Neumann, M. A. Andrews and D. R. McAlister, Pure Appl. Chem., 52, 625 (1980).
J. A. Gladysz and W. Tam, J. Am. Chem. Soc., 100, 2545 (1978);
J. A. Galdysz and J. C. Selover, Tetrahedron Letters, 319 (1978).
C. P. Casey, M. A. Andrews and J. E. Rinz, J. Am. Chem. Soc., 101, 741 (1979).
J. R. Sweet and W. A. G. Graham, J. Organometal. Chem., 173, C9 (1979).
W. K. Wong, W. Tam, C. E. Strouse and J. Gladysz, J. Chem. Soc. Chem. Commun., 530 (1979).
J. P. Collman and S. R. Winter, J. Am. Chem. Soc., 95, 4089 (1973).
R. L. Pruett, R. C. Schoening, J. L. Vidal and R. A. Fiato, J. Organometal. Chem., 182, C57 (1979).
B. B. Wayland and B. A. Woods, J. Chem, Soc. Chem. Commun., 700 (1981).
D. R. Fahey, J. Am. Chem. Soc., 103, 136 (1981).
J. W. Rathke and H. M. Feder, J. Am. Chem. Soc., 100, 3263 (1978).
H. M. Feder and J. W. Rathke, Ann. N. Y. Acad. Sci., 333, 45 (1980); H. M. Feder, J. W. Rathke, M. J. Chen and L. A. Curtis, ACS Symp. Series, 152, 19 (1981).
R. L. Pruett, Ann. N. Y. Acad. Sci., 295, 239 (1977).
A. Deluzarche, R. Fonseca, G. Jenner and A. Kiennemann, Erdoel Kohle Erdgas Petrochem. Brennst. Chem., 32, 313 (1979).
B. D. Dombek, J. Am. Chem. Soc., 102, 6855 (1980).
J. F. Knifton, J. Chem. Soc. Chem. Commun., 188 (1981); J. Am. Chem. Soc., 103, 3959 (1981).
R. C. Williamson and T. P. Kobylinski, US Patent 4, 170, 605 (1979).
J. S. Bradley, J. Am. Chem. Soc., 101, 7419 (1979).
US Patent 3,920,753 (1975) to Ajinomoto.
A. Spencer, J. Organometal. Chem., 194, 113 (1980).
J. A. Roth and M. Orchin, J. Organometal. Chem., 172, C27 (1979).
H. Hachenberg, F. Wunder, E. I. Leupold and H. J. Schmidt, Eur. Pat. Appl. 21,330 (1981) to Hoechst; CA 94, 174317g (1981).
J. E. Bozik, T. P. Kobylinski and W. R. Pretzer, US Patent 4,239,705 (1980) to Gulf Research and Development.
K. L. Brown, G. R. Clark, C. E. L. Headford, K. Marsden and W. R. Roper, J. Am. Chem. Soc., 101, 503 (1979).
J. M. Manriquez, D. R. McAlister, R. D. Sanner and J. E. Bercaw, J. Am. Chem. Soc., 98, 6733 (1976).
R. B. King, A. D. King and K. Tanaka, J. Mol. Catal., 10, 75 (1980); see also G. Jenner, A. Kiennemann, E. Bagherzadah and A. Deluzarche, React. Kinet. Catal. Letters, 15, 103 (1980).
M. J. Doyle, A.P. Kouwenhoven, C. A. Schaap and B. van Oort, J. Organometal. Chem., 174, C55 (1979).
E. L. Muetterties, Bull. Soc. Chim. Belg., 84, 959 (1975); 85, 451 (1976).
M. Moskovits, Acc. Chem. Res., 12, 229 (1979);
H. F. Schaefer, Acc. Chem. Res., 10, 287 (1977).
C. Demitras and E. L. Muetterties, J. Am. Chem. Soc., 99, 2796 1977;
H. K. Wang, H. W. Choi and E. L. Muetterties, Inorg. Chem., 20, 2661 (1981);
H. W. Choi and E. L. Muetterties, Inorg. Chem., 20, 2664 (1981).
M. G. Thomas, B. F. Beier and E. L. Muetterties, J. Am. Chem. Soc., 98, 1296 (1976).
G. R. Steinmetz and G. L. Geoffroy, J. Am. Chem. Soc., 103, 1278 (1981).
C. van der Woude, J. A. van Doom and C. Masters, J. Am. Chem. Soc., 101, 1633 (1979).
K. S. Wong and J. A. Labinger, J. Am. Chem. Soc., 102, 3652 (1980).
J. A. Labinger and K. S. Wong, ACS Symp. Series, 152, 253 (1981).
J. A. Gladysz, W. A. Kiel, G. Y. Lin, W. K. Wong and W. Tam, ACS Symp. Series, 152, 147 (1981).
W. Reppe and H. Vetter, Justus Liebig’s Ann. Chem., 582, 133 (1953).
R. Pettit, C. Mauldin, T. Cole and H. Kang, Ann. N. Y. Acad. Sci., 295, 151 (1977).
R. M. Laine, Ann. N. Y. Acad. Sci., 333, 124 (1980).
R. M. Laine, J. Am. Chem. Soc., 100, 6451 (1978);J. Org. Chem., 45, 3370 (1980).
W. J. Thomson and R. M. Laine, ACS Symp. Series, 152, 133 (1981).
Additional Reading
P. C. Ford, Ed., Catalytic Activation of Carbon Monoxide, ACS Symposium Series, No. 152, 1981.
E. L. Muetterties and J. Stein, `Mechanistic Features of Carbon Monoxide Hydrogenation Reactions’, Chem. Rev., 79, 479 (1979).
E. L. Kugler and F. W. Steffgen, Eds., Hydrocarbon Synthesis from Carbon Monoxide and Hydrogen, Advan. Chem. Ser., No. 178 (1979).
G. P. Chiusoli, `New Aspects of Organic Syntheses Catalysed by Group VIII Metal Complexes’, Pure Appl. Chem., 52, 635 (1980).
P. T. Wolczanski and J. E. Bercaw, `On the Mechanisms of Carbon Monoxide Reduction with Zirconium Hydrides’, Acc. Chem. Res., 13, 121 (1980).
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Sheldon, R.A. (1983). Mechanistic Principles. In: Chemicals from Synthesis Gas. Catalysis by Metal Complexes, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-1019-0_2
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DOI: https://doi.org/10.1007/978-94-017-1019-0_2
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