As an apparent trend, more and more firms are adopting cause-related marketing to promote a green corporate image (Leonidou et al. 2011) in an effort to improve market share and performance. Although consumers consider a product’s environmental attributes as “structurally important features” (Gershoff and Frels 2015, p. 101), this study provides additional evidence that marketing efforts in the financial industry can also target peripheral rather than central attributes to maximize greenness perceptions by establishing the connection between consumer values and the choice of environmental cause. The existing literature highlights the importance of brand-cause fit by arguing that “a perceived match between the product’s brand and the cause it supported” could greatly improve consumer perceptions toward cause-marketing campaigns and brand image (e.g., Chéron et al. 2012, p. 362). In our research, however, the brand-cause fit is moderated by the individuals’ previous philanthropic experiences and biospheric values. Therefore, marketers should understand the environmental concerns of targeted audiences to effectively communicate with consumers. More importantly, marketers should clearly indicate the benefits of environmental consumption if they hope to convince ambivalent consumers (Burke et al. 2014).