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Anionic Polymerizations with Complex Bases and Their Derivatives

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Crown Ethers and Phase Transfer Catalysis in Polymer Science

Part of the book series: Polymer Science and Technology ((POLS))

Abstract

Organometallics as well as metals such as sodium or potassium are well known as initiators for anionic polymerizations. Moreover, in order to increase or modulate the reactivity of these classical initiators, the influence of additives (such as tertiary amines, linear and macrocyclic polyethers, cryptands, alcohols and alkoxides) has been the subject of many works1–11.

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References

  1. N. Szwarc, “Carbanions living polymers and electron transfer processes”, Interscience, New York (1968)

    Google Scholar 

  2. A.W. Langer, Jr., Trans. N.Y. Acad. Sci., 27: 741 (1965)

    Article  CAS  Google Scholar 

  3. N. Shinohara, J. Smid, N. Szwarc, J. Amer. Chem. Soc., 90: 2175 (1968)

    Article  CAS  Google Scholar 

  4. S. Kopolow, T.E. Hogen-Esch, J. Smid, Nacromolecules, 66: 133 (1973)

    Article  Google Scholar 

  5. S. Boileau, B. Kaempf, J.N. Lehn, F. Schue, J. Polym. Sci. B, 12: 203 (1974)

    CAS  Google Scholar 

  6. N. Namhashi, H. Takida, Makromol. Chem., 124: 172 (1969)

    Article  Google Scholar 

  7. D.N. Wiles, S. Bywater, J. Phys. Chem., 68: 1983 (1964)

    Google Scholar 

  8. H.L. Hsich, C.F. Wofford, J. Polym. Sci. A, 1: 449 (1969)

    Google Scholar 

  9. T. Narita, T. Yasumara, T. Tsunita, Polym. J., 4: 421 (1973)

    Article  CAS  Google Scholar 

  10. T.C. Cheng, A.F. Halasa, D.P. Tate, J. Polym. Sci. Polym. Chem. Ed. 11:253 (1973); ibid 14:573 (1976)

    Google Scholar 

  11. L. Lochmann, D. Doskocilova, J. Trekoval, Coll. Czech. Chem. Commun., 42:1355 (1977) and references cited therein

    Google Scholar 

  12. For reviews see: P. Caubere, Acc. Chem. Res., 7:301 (1974) and references cited therein; P. Caubere, Topics in Current Chemistry, 73:50 (1978) and references cited therein

    Google Scholar 

  13. G. Ndebeka, P. Caubere, S. Raynal, S. Lecolier, Polymer, 22:347 (1981) and references cited therein

    Google Scholar 

  14. G. Ndebeka, Thesis, Nancy (1979)

    Google Scholar 

  15. S. Raynal, S. Lecolier, G. Ndebeka, P. Caubere, J. Polym. Sci. Polym. Lett. Ed., 18:13 (1980)

    Article  CAS  Google Scholar 

  16. S. Raynal, Thesis, Nancy (1979)

    Google Scholar 

  17. S. Raynal, S. Lecolier, G. Ndebeka, P. Caubere, Polymer, 22: 356 (1981)

    Article  CAS  Google Scholar 

  18. S. Raynal, S. Lecolier, G. Ndebeka, P. Caubere, Polymer, 23: 283 (1982)

    Article  CAS  Google Scholar 

  19. E.R. Biehl, E. Nieh, K.C. Hsu, J. Org. Chem., 34:3595 (1969); E.R. Biehl, K. Hsu, E. Nieh, J. Org. Chem., 35: 2454 (1970)

    Google Scholar 

  20. S. Raynal, G. Ndebeka, P. Caubere, S. Suparno, J. Sledz, F.Schue J. Macromol. Sci. Chem. A, 17: 667 (1982)

    Article  Google Scholar 

  21. S. Raynal, S. Lecolier, G. Ndebeka, P. Caubere, Polymer, 22: 1425 (1981)

    Article  CAS  Google Scholar 

  22. D.N. French, Rubber Chem. Technol., 42: 90 (1969)

    Article  Google Scholar 

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Author information

Authors and Affiliations

  1. Laboratoire de Chimie Organique I, Université de Nancy I, Nancy, France

    P. Caubere

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  1. P. Caubere
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Editor information

Editors and Affiliations

  1. University of Southern Mississippi, Southern Station, Mississippi, USA

    Lon J. Mathias

  2. Wright State University, Dayton, Ohio, USA

    Charles E. Carraher Jr.

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© 1984 Plenum Press, New York

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Caubere, P. (1984). Anionic Polymerizations with Complex Bases and Their Derivatives. In: Mathias, L.J., Carraher, C.E. (eds) Crown Ethers and Phase Transfer Catalysis in Polymer Science. Polymer Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9349-2_12

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  • DOI: https://doi.org/10.1007/978-1-4615-9349-2_12

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-9351-5

  • Online ISBN: 978-1-4615-9349-2

  • eBook Packages: Springer Book Archive

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